Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference

Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications, is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells. - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference.

Fluoropolymers were discovered accidentally by Plunkett in 1938. He was working on freon and accidentally polymerised tetrafluoroethylene. The result was polytetrafluoroethylene (PTFE), more commonly known as Teflon. PTFE is inert to virtually all chemicals and is considered to be the most slippery material in existence - it has the lowest coefficient of friction of any known solid material. These properties have made it one of the most valuable and versatile technologies ever invented, contributing to significant advancements in areas such as aerospace, communications, electronics, industrial.

This third edition has been updated and expanded, providing industrial chemists, technologists, environmental scientists, and engineers with an accurate, compact, and practical source of information on fluoropolymers. Highlighting existing and new industrial, military, medical, and consumer goods applications, this edition adds more detailed information on equipment and processing conditions. It explores breakthroughs in understanding property-structure relationships, new polymerization techniques, and the chemistry underlying polymers, such as melt-processable fluoroplastics. It also expands on the important properties of fluoropolymers, including heat and radiation degradation, health effects, and recycling. Features: Revised, updated, and expanded to continue to provide an accurate, compact, and practical source of information on fluoropolymers Explores the property-structure relationships, polymerization techniques, and the chemistry underlying polymers Fluoropolymers rank high on the specialty polymers group and, due to their unique properties, are naturally part of the solution to the industrial sustainability challenges of the twenty-first century Describes the technology of fluoropolymers, including thermoplastic and elastomeric products Expands upon the important characteristics of fluoropolymers and their recycling.

Fully revised and updated, this second edition continues to provide industrial chemists, technologists, and engineers with the most accurate, compact, and practical source on fluoropolymers (such as Teflon). Highlighting new industrial, military, medical, and consumer goods applications, this edition adds more detailed information on equipment and

Fluoropolymers are very unique materials. Since the middle of the twentieth century fluoropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling covers recent developments in fluoropolymers, including synthesis of new copolymers, strategies for radical polymerization of fluoromonomers (conventional or controlled; RDRP), and the modification of fluoropolymers to achieve desired material characteristics. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the synthetic strategies, properties, and recycling of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries. - Written by a global team of fluoropolymer experts - Includes conventional techniques of radical polymerization and more modern controlled polymerization techniques - Covers nanocomposites, which are of interest to researchers and industrial manufacturers of fluoropolymers

Advanced Fluoropolymer Nanocomposites: Fabrication, Processing, Characterization and Applications presents a comprehensive review on the fundamental chemistry, physics, biology and engineering of advanced fluoropolymer nanocomposites. Detailed attention is given to the synthesis, processing characterization, properties and applications of fluoropolymer nanocomposites. Morphological, thermal, electrical, mechanical, tribological and viscoelastic properties are also discussed in detail, along with the influence of synthesis methods on the formation of fluoropolymer nanocomposites, including the effect of nanofiller size and shape and the dispersion state of various nanofillers in different fluoropolymer matrices. This book will be a useful reference resource for scientists, engineers and postgraduate students working in the field of polymer science and technology, materials science and engineering, composites and nanocomposites. This resource will help them find solutions to both fundamental and applied problems associated with their research. It will also assist researchers in becoming more acquainted with the field to address key questions within a short time. - Covers the range of fluoropolymer nanocomposites and their fabrication, processing, structural, physical, thermal, electrical and mechanical properties - Discusses high-performance applications in the electronics, energy, architecture, environmental, biomedical and textile industries - Presents the latest information on disposal and recycling, safety considerations, and the environmental and health impact of fluoropolymer nanocomposites