This book addresses structural material corrosion in coolant circuits, simulation of erosion corrosion of carbon and low-alloy steels, and simulation of stress corrosion. It also discusses corrosion of copper alloys, zirconium corrosion, optimization of water chemistry at operating nuclear power plants, coolant tendency to deposit hardness salts on heat-transfer surfaces, and inspection of metallic components. In addition, there are two appendixes, the first showing the chemical composition of steels, the second discussing solubility of iron, cobalt, zinc and copper corrosion products under conditions simulating power unit water chemistry.

Corrosion of nuclear materials, i.e. the interaction between these materials and their environments, is a major issue for plant safety as well as for operation and economic competitiveness. Understanding these corrosion mechanisms, the systems and materials they affect, and the methods to accurately measure their incidence is of critical importance to the nuclear industry. Combining assessment techniques and analytical models into this understanding allows operators to predict the service life of corrosion-affected nuclear plant materials, and to apply the most appropriate maintenance and mitigation options to ensure safe long term operation.This book critically reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities. Initial sections introduce the complex field of nuclear corrosion science, with detailed chapters on the different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them. This is complemented by reviews of monitoring and control methodologies, as well as modelling and lifetime prediction approaches. Given that corrosion is an applied science, the final sections review corrosion issues across the range of current and next-generation nuclear reactors, and across such nuclear applications as fuel reprocessing facilities, radioactive waste storage and geological disposal systems.With its distinguished editor and international team of expert contributors, Nuclear corrosion science and engineering is an invaluable reference for nuclear metallurgists, materials scientists and engineers, as well as nuclear facility operators, regulators and consultants, and researchers and academics in this field. - Comprehensively reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities - Chapters assess different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them - Considers monitoring and control methodologies, as well as modelling and lifetime prediction approaches

Corrosion remains one of the key issues affecting the performance and availability of nuclear power plants. Therefore, reliable in-plant corrosion monitoring methods are essential both for the future operation of existing plants and to ensure the safety of future nuclear waste disposal systems. In two parts, this book was stimulated by a workshop organised by EFC Working Party 4 on Nuclear Corrosion and the European Cooperative Group on Corrosion Monitoring of Nuclear Materials (EGC-COMON). The first part deals mainly with research into the detection of stress corrosion crack initiation in nuclear power plant environments (essentially high temperature water at around 300 °C) by various methods, particularly the electrochemical noise technique but also including the electrochemical impedance, acoustic emission and direct current potential drop methods. The second part addresses the goal to develop in-situ techniques and includes examples of the application of electrochemical corrosion potential monitoring. This book will be of particular interest to scientists and engineers concerned with the mitigation of corrosion in nuclear systems.