The growing need to find a sustainable, environmentally-friendly replacement for petroleum-based materials is fuelling the development of bio-based polymers from renewable resources. Amongst the most promising of these are vegetable oil-based polymeric materials. Vegetable oil-based polymers provides a comprehensive review of the research in this important field.After an introduction to classification and polymerization, Vegetable oil-based polymers goes on to review the factors involved in polymer biodegradation. The extraction, purification and application of vegetable oils are then explored, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies. The book then reviews polyamides, polyolefins and vegetable oil-based hyperbranched polymers. It concludes with an analysis of vegetable oil-based polymer composites and polymer nanocomposites.Vegetable oil-based polymers is an indispensable guide for all those involved in the research and development of biopolymers as well as the wide range of industries looking for more sustainable polymer materials. - Provides a comprehensive review of recent research in the area of vegetable oil-based polymeric materials - Discusses vegetable oils and their derivatives, biodegradable polymers and the fundamentals of polymers - Explores the extraction, purification and application of vegetable oils, along with vegetable oil-based polyesters and poly(ester amide)s, polyurethanes and epoxies

Vegetable Oil Based Polymers and Their Surface Applications presents detailed coverage of principles, preparation methods and novel surface uses of vegetable oil based polymers. This comprehensive, state-of-the-art book follows the journey of vegetable oils from seeds to surfaces in a range of advanced applications. Opening chapters discuss theory, principles and characterization techniques while other sections present concepts on the preparation of different polymer types based on vegetable oil. The final section of the book provides extensive coverage of applications, enabling the preparation of vegetable oil based polymers for a range of products and industries. This is a valuable resource for researchers, scientists, and advanced students in polymer chemistry, surfaces and coatings, natural polymers, materials chemistry, chemical engineering and plastics engineering. In an industrial setting, this book supports R&D professionals, scientists, and engineers interested in developing innovative biobased materials for a range of applications, including automotive and aerospace, packaging, cosmetics, pharmaceuticals, biomedicine and consumer goods. - Provides in-depth information on the preparation of vegetable oil-based epoxies, alkyds, polyesteramides, polyetheramides and polyurethanes - Explores cutting-edge surface applications of vegetable oil-based polymers in areas such as coatings, packaging, cosmetics and wound dressings - Includes other key considerations, including cost benefit analysis, lifecycle assessment and future developments

Bio-Based Polymers and Composites is the first book systematically describing the green engineering, chemistry and manufacture of biobased polymers and composites derived from plants. This book gives a thorough introduction to bio-based material resources, availability, sustainability, biobased polymer formation, extraction and refining technologies, and the need for integrated research and multi-disciplinary working teams. It provides an in-depth description of adhesives, resins, plastics, and composites derived from plant oils, proteins, starches, and natural fibers in terms of structures, properties, manufacturing, and product performance. This is an excellent book for scientists, engineers, graduate students and industrial researchers in the field of bio-based materials.* First book describing the utilization of crops to make high performance plastics, adhesives, and composites* Interdisciplinary approach to the subject, integrating genetic engineering, plant science, food science, chemistry, physics, nano-technology, and composite manufacturing.* Explains how to make green materials at low cost from soyoil, proteins, starch, natural fibers, recycled newspapers, chicken feathers and waste agricultural by-products.

Bio-based Plant Oil Polymers and Composites provides engineers and materials scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field—enabling them to develop and commercialize their own products quickly and more successfully. Plant oil is one of the most attractive options as a substitute for non-renewable resources in polymers and composites, and is producing materials with very promising thermomechanical properties relative to traditional, petroleum-based polymers. In addition to critical processing and characterization information, the book assists engineers in deciding whether or not they should use a plant oil-based polymer over a petroleum-based polymer, discussing sustainability concerns, biodegradability, associated costs, and recommended applications. The book details the advancements in the development of polymeric materials and composites from plant oils, and provides a critical review of current applications in various fields, including packaging, biomedical, and automotive applications. Also includes the latest progress in developing multifunctional biobased polymers—by increasing thermal conductivity or adding antibacterial properties, for example. - Essential coverage of processing, characterization, and the latest research into polymeric materials and composites derived from plant oils (thermoplastics, thermosets, nanocomposites, and fiber reinforced composites) - Critically reviews the potential applications of plant oil-based polymers, including sensors, structural parts, medical devices, and automotive interiors - Includes the latest developments in multifunctional bio-based polymer composites

The progressive dwindling of fossil resources, coupled with the drastic increase in oil prices, have sparked a feverish activity in search of alternatives based on renewable resources for the production of energy. Given the predominance of petroleum- and carbon-based chemistry for the manufacture of organic chemical commodities, a similar preoccupation has recently generated numerous initiatives aimed at replacing these fossil sources with renewable counterparts. In particular, major efforts are being conducted in the field of polymer science and technology to prepare macromolecular materials based on renewable resources. The concept of the bio-refinery, viz. the rational exploitation of the vegetable biomass in terms of the separation of its components and their utilisation as such, or after suitable chemical modifications, is thus gaining momentum and considerable financial backing from both the public and private sectors. This collection of chapters, each one written by internationally recognised experts in the corresponding field, covers in a comprehensive fashion all the major aspects related to the synthesis, characterization and properties of macromolecular materials prepared using renewable resources as such, or after appropriate modifications. Thus, monomers such as terpenes and furans, oligomers like rosin and tannins, and polymers ranging from cellulose to proteins and including macromolecules synthesized by microbes, are discussed with the purpose of showing the extraordinary variety of materials that can be prepared from their intelligent exploitation. Particular emphasis has been placed on recent advances and imminent perspectives, given the incessantly growing interest that this area is experiencing in both the scientific and technological realms. - Discusses bio-refining with explicit application to materials - Replete with examples of applications of the concept of sustainable development - Presents an impressive variety of novel macromolecular materials

Biopolymers from Renewable Resources is a compilation of information on the diverse and useful polymers derived from agricultural, animal, and microbial sources. The volume provides insight into the diversity of polymers obtained directly from, or derived from, renewable resources. The beneficial aspects of utilizing polymers from renewable resources, when considering synthesis, pro cessing, disposal, biodegradability, and overall material life-cycle issues, suggests that this will continue to be an important and growing area of interest. The individual chapters provide information on synthesis, processing and properties for a variety of polyamides, polysaccharides, polyesters and polyphenols. The reader will have a single volume that provides a resource from which to gain initial insights into this diverse field and from which key references and contacts can be drawn. Aspects of biology, biotechnology, polymer synthesis, polymer processing and engineering, mechanical properties and biophysics are addressed to varying degrees for the specific biopolymers. The volume can be used as a reference book or as a teaching text. At the more practical level, the range of important materials derived from renewable resources is both extensive and impressive. Gels, additives, fibers, coatings and films are generated from a variety of the biopolymers reviewed in this volume. These polymers are used in commodity materials in our everyday lives, as well as in specialty products.

This brief outlines the most recent advances in the production of polyols and polyurethanes from renewable resources, mainly vegetable oils, lignocellulosic biomass, starch, and protein. The typical processes for the production of polyols from each of the above mentioned feedstocks are introduced and the properties of the resultant polyols and polyurethanes are also discussed.