Covering both organic materials, where recent advances in the understanding of device physics is driving progress, and the newly emerging field of mixed halide perovskites, which are challenging the efficiencies of conventional thin film PV cells, this book provides a balanced overview of the experimental and theoretical aspects of these two classes of solar cell. The book explores both the experimental and theoretical aspects of these solar cell classes. Emphasis is placed on understanding the fundamental physics of the devices. The book also discusses modelling over many length scales, from nano to macro. The first book to cover perovskites, this is an important reference for industrialists and researchers working in energy technologies and materials.

"You, 0 Sun, are the eye of the world You are the soul of all embodied beings You are the source of all creatures You are the discipline of all engaged in work" - Translated from Mahabharata 3rd Century BC Today, energy is the lifeline and status symbol of "civilized" societies. All nations have therefore embarked upon Research and Development pro grams of varying magnitudes to explore and effectively utilize renewable sources of energy. Albeit a low-grade energy with large temporal and spatial variations, solar energy is abundant, cheap, clean, and renewable, and thus presents a very attractive alternative source. The direct conver sion of solar energy to electricity (photovoltaic effect) via devices called solar cells has already become an established frontier area of science and technology. Born out of necessity for remote area applications, the first commercially manufactured solar cells - single-crystal silicon and thin film CdS/Cu2S - were available well over 20 years ago. Indeed, all space vehicles today are powered by silicon solar cells. But large-scale terrestrial applications of solar cells still await major breakthroughs in terms of discovering new and radical concepts in solar cell device structures, utilizing relatively more abundant, cheap, and even exotic materials, and inventing simpler and less energy intensive fabrication processes. No doubt, this extraordinary challenge in R/D has led to a virtual explosion of activities in the field of photovoltaics in the last several years.

Thin film photovoltaic-based solar modules produce power at a low cost per watt. They are ideal candidates for large-scale solar farms as well as building-integrated photovoltaic applications. They can generate consistent power, not only at elevated temperatures but also on cloudy, overcast days and at low sun angles.Thin film photovoltaics are second-generation solar cells produced by depositing one or more thin layers, or thin films, of photosensitive material on a suitable substrate such as glass, polymer, or metal. Thin film solar cells are based on various materials such as cadmium telluride (CdTe), copper indium gallium diselenide (CIGS), and amorphous thin film silicon (a-Si, TF-Si) are commercially used in several conventional and advanced technologies.

This is an advanced book on thin film solar cell techniques. This technique uses direct-gap semiconductors such as CIGS and CdTe pose minimum manufacturing costs and is now increasing in popularity amongst industries. The field of photovoltaics has seen a large-scale manufacturing of the second genesis of thin film solar modules and has succeeded in constructing powerful solar plants in many countries across the globe. This has led to an increase in the manufacturability of thin film solar modules as compared to wafer or ribbon Si modules. Thin films like CIGS and CdTe will soon take over wafer-based silicon solar cells as the superior photovoltaic technology. This book elucidates the scientific and technological difficulties of increasing the photoelectric efficiency of thin film solar cells. It covers various aspects of thin film solar cells processing, modeling and sensitive issues, analysis of monograin layer solar cell etc. The book will be beneficial for readers interested in this subject.

This book discusses the benefits and challenges of utilizing thin film solar cells as an alternative energy source. The field of photovoltaics has seen a large-scale manufacturing of the second genesis of thin film solar modules and has succeeded in constructing powerful solar plants in many countries across the globe. Thin film techniques using direct-gap semiconductors such as CIGS and CdTe pose minimum manufacturing costs and are now increasing in popularity amongst industries. This has led to an increase in the manufacturability of thin film solar modules as compared to wafer or ribbon Si modules. Thin films like CIGS and CdTe will soon take over wafer-based silicon solar cells as the superior photovoltaic technology. This book elucidates the scientific and technological difficulties of increasing the photoelectric efficiency of thin film solar cells. It covers various aspects of thin film solar cells varying from photovoltaics as mainstream power engineering to low cost solar cell based on cuprous oxides to application of electron beam treatment. This book will be beneficial for readers interested in this subject.

This book provides recent development in thin-film solar cells (TFSC). TFSC have proven the promising approach for terrestrial and space photovoltaics. TFSC have the potential to change the device design and produce high efficiency devices on rigid/flexible substrates with significantly low manufacturing cost. TFSC have several advantages in manufacturing compared to traditional crystalline Si-solar cells like less requirement of materials, can be prepared with earth’s abundant materials, less processing steps, easy to dispose, etc. Several universities/research institutes/industry in India and abroad are involved in the research area of thin-film solar cells. The book helps the readers to find the details about different thin-film technologies and its advancement at one place. Each chapter covers properties of materials, its suitability for PV applications, simple manufacturing processes and recent and past literature survey. The issues related to the development of high efficiency TFSC devices over large area and its commercial and future prospects are discussed.

PHYSICS OF THIN-FILM PHOTOVOLTAICS Tackling one of the hottest topics in renewables, thin-film photovoltaics, the authors present the latest updates, technologies, and applications, offering the most up-to-date and thorough coverage available to the engineer, scientist, or student. It appears rather paradoxical that thin-film photovoltaics (PVs) are made of materials that seem unacceptable from the classical PV perspective, and yet they often outperform classical PV. This exciting new volume solves that paradox by switching to a new physics paradigm. Many concepts here fall beyond the classical PV scope. The differences lie in device thinness (microns instead of millimeters) and morphology (non-crystalline instead of crystalline). In such structures, the charge carriers can reach electrodes without recombination. On the other hand, thin disordered structures render a possibility of detrimental lateral nonuniformities (“recombination highways”), and their energy spectra give rise to new recombination modes. The mechanisms of thermal exchange and device degradation are correspondingly unique. The overall objective of this book is to give a self-contained in-depth discussion of the physics of thin-film systems in a manner accessible to both researchers and students. It covers most aspects of the physics of thin-film PV, including device operations, material structure and parameters, thin-film junction formation, analytical and numerical modeling, concepts of large area effects and lateral non-uniformities, physics of shunting (both shunt growth and effects), and device degradation. Also, it reviews a variety of physical diagnostic techniques proven with thin-film PV. Whether for the veteran engineer or the student, this is a must-have for any library. This outstanding new volume: Covers not only the state-of-the-art of thin-film photovoltaics, but also the basics, making this volume useful not just to the veteran engineer, but the new-hire or student as well Offers a comprehensive coverage of thin-film photovoltaics, including operations, modeling, non-uniformities, piezo-effects, and degradation Includes novel concepts and applications never presented in book format before Is an essential reference, not just for the engineer, scientist, and student, but the unassuming level of presentation also makes it accessible to readers with a limited physics background Is filled with workable examples and designs that are helpful for practical applications Is useful as a textbook for researchers, students, and faculty for understanding new ideas in this rapidly emerging field Audience: Industrial professionals in photovoltaics, such as engineers, managers, research and development staff, technicians, government and private research labs; also academic and research universities, such as physics, chemistry, and electrical engineering departments, and graduate and undergraduate students studying electronic devices, semiconductors, and energy disciplines