This book introduces key concepts in modeling and risk assessments of vapor intrusion, a process by which the subsurface volatile contaminants migrate into the building of concern. Soil vapor intrusion is the major exposure pathway for building occupants to chemicals from the subsurface, and its risk assessments determine the criteria of volatile contaminants in soil/groundwater in brownfield redevelopment. The chapters feature the recent advances in vapor intrusion studies and practices, including analytical and numerical modeling of vapor intrusion, statistical findings of United States Environmental Protection Agency’s Vapor Intrusion Database and Petroleum Vapor Intrusion Databases, the challenges of preferential pathways, and the application of building pressure cycling methods, and field practices of vapor intrusion risk assessments at developed contaminated sites and in brownfield redevelopment. This volume also summarizes the advantages and limits of current applications in vapor intrusion risk assessment, laying the groundwork for future research of better understanding in risk characterization of soil vapor intrusion using models. Written by experts in this field, Vapor Intrusion Simulations and Risk Assessments will serve as an invaluable reference for researchers, regulators, and practitioners, who are interested in perceiving the basic knowledge and current advances in risk assessments of soil vapor intrusion.

Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be used to predict the concentration of VOCs in the indoor air of a building based on a measured subsurface soil gas concentration or contaminant source concentrations, either in non-aqueous phase liquid (NAPL), groundwater, or soil. An analysis of two of the EPA-implemented J&E spreadsheet models, one that considers subsurface soil gas data and one that considers groundwater data, was conducted. The governing equations, assumptions, and limitations of these spreadsheet models were investigated. A value of information (Vol) worksheet was developed that can assist practitioners in deciding what additional data to collect as part of a remedial investigation. The Vol worksheet calculates how varying values of model input parameters affect the model-predicted indoor air carcinogenic risk. The worksheet then compares the user-defined target risk to the range of potential risk values for different combinations of varying parameters. The results of this analysis allow the user to determine which groups of parameters have the most impact on the model results. This information can assist the practitioner in deciding whether or not to collect additional data to reduce the uncertainty in the input parameters. The EPA J&E soil gas and groundwater spreadsheet models, as well as the Vol worksheet developed for each model, were applied to case study data for a trichloroethylene-impacted site in Rhode Island. The results of the J&E model and Vol worksheet analyses for this case study predicted incremental carcinogenic risk values for trichloroethylene (TCE) below the risk value calculated based on measured indoor air data. This comparison suggests the potential for other sources of TCE within the building. Groups of parameters were identified for each model that impacted the model-predicted carcinogenic risk. The development of a cost-benefit analysis, which would be used to quantify the value of obtaining additional data for these critical parameters, is recommended for future research.

Since the International Institute for Applied Systems Analysis began its study of water quality modeling and management in 1977, it has been interested in the relations between uncertainty and the problems of model calibration and prediction. The work has focused on the theme of modeling poorly defined environmental systems, a principal topic of the effort devoted to environmental quality control and management. Accounting for the effects of uncertainty was also of central concern to our two case studies of lake eutrophication management, one dealing with Lake Balaton in Hungary and the other with several Austrian lake systems. Thus, in November 1979 we held a meeting at Laxenburg to discuss recent method ological developments in addressing problems associated with uncertainty and forecasting of water quality. This book is based on the proceedings of that meeting. The last few years have seen an increase in awareness of the issue of uncertainty in water quality and ecological modeling. This book is relevant not only to contemporary issues but also to those of the future. A lack of field data will not always be the dominant problem for water quality modeling and management; more sophisticated measuring techniques and more comprehensive monitoring networks will come to be more widely applied. Rather, the important problems of the future are much more likely to emerge from the enhanced facility of data processing and to concern the meaningful interpretation, assimilation., and use of the information thus obtained.

Safety in the process industries is critical for those who work with chemicals and hazardous substances or processes. The field of loss prevention is, and continues to be, of supreme importance to countless companies, municipalities and governments around the world, and Lees’ is a detailed reference to defending against hazards. Recognized as the standard work for chemical and process engineering safety professionals, it provides the most complete collection of information on the theory, practice, design elements, equipment, regulations and laws covering the field of process safety. An entire library of alternative books (and cross-referencing systems) would be needed to replace or improve upon it, but everything of importance to safety professionals, engineers and managers can be found in this all-encompassing three volume reference instead. The process safety encyclopedia, trusted worldwide for over 30 years Now available in print and online, to aid searchability and portability Over 3,600 print pages cover the full scope of process safety and loss prevention, compiling theory, practice, standards, legislation, case studies and lessons learned in one resource as opposed to multiple sources