Tunable Far Infrared Laser Spectroscopy of Van Der Waals Bonds
Title | Tunable Far Infrared Laser Spectroscopy of Van Der Waals Bonds PDF eBook |
Author | Dz-Hung Gwo |
Publisher | |
Pages | 570 |
Release | 1989 |
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Tunable Far Infrared Laser Spectroscopy of Van Der Waals Bonds
Title | Tunable Far Infrared Laser Spectroscopy of Van Der Waals Bonds PDF eBook |
Author | |
Publisher | |
Pages | 268 |
Release | 1989 |
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ISBN |
Hyperfine resolved vibration-rotation-tunneling spectra of Ar--NH3 and (NH3)2, generated in a planar supersonic jet, have been measured with the Berkeley tunable far infrared laser spectrometer. Among the seven rotationally assigned bands, one band belongs to Ar--NH3, and the other six belong to (NH3)2. To facilitate the intermolecular vibrational assignment for Ar--NH3, a dynamics study aided by a permutation-inversion group theoretical treatment is performed on the rovibrational levels. The rovibrational quantum number correlation between the free internal rotor limit and the semi-rigid limit is established to provide a basic physical picture of the evolution of intermolecular vibrational component states. An anomalous vibronically allowed unique Q branch vibrational band structure is predicted to exist for a near prolate binary complex containing an inverting subunit. According to the model developed in this work, the observed band of Ar--NH3 centered at 26.470633(17) cm−1 can correlate only to either the fundamental dimeric stretching band for the A2 states with the NH3 inversional quantum number v{sub i} = 1, or the K{sub a} = 0 {l arrow} 0 subband of the lowest internal-rotation-inversion difference band. Although the estimated nuclear quadrupole coupling constant favors a tentative assignment in terms of the first possibility, a definitive assignment will require far infrared data and a dynamical model incorporating a potential surface.
Tunable Far Infrared Laser Spectroscopy of Van Der Waals Molecules in a Planar Supersonic Jet Expansion
Title | Tunable Far Infrared Laser Spectroscopy of Van Der Waals Molecules in a Planar Supersonic Jet Expansion PDF eBook |
Author | Kerry Lynn Busarow |
Publisher | |
Pages | 642 |
Release | 1990 |
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Tunable Far Infrared Laser Spectroscopy of Van Der Waals Molecules in a Planar Supersonic Jet Expansion
Title | Tunable Far Infrared Laser Spectroscopy of Van Der Waals Molecules in a Planar Supersonic Jet Expansion PDF eBook |
Author | |
Publisher | |
Pages | 317 |
Release | 1990 |
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The gas phase high resolution spectroscopic study of weakly bound clusters can provide the information necessary to develop an intermolecular potential energy surface. This surface can then be used to better understand condensed phases. In this work, a tunable far infrared laser spectrometer is used to study weakly bound dimers produced in the newly developed continuous planar supersonic jet expansion apparatus. The water dimer is an extensively studied hydrogen bonded dimer. It undergoes several tunneling motions which result in splittings and perturbations of the rovibrational energy levels. A review is presented of much of the experimental and theoretical work done on water dimer, including a description of the combined fit of all the high resolution spectroscopic results by Coudert and Hougen. Also included is a discussion of the measurement of the K = 1 lower --> K = 2 lower band performed using the tunable far infrared laser/planar jet apparatus. The preliminary results from the study of CH4{center dot}H2O will also be presented. CH4{center dot}H2O is unique in that unlike a strongly anisotropic complex, such as the water dimer, the monomer subunits are nearly free internal rotors. Seven bands are observed which have very similar band origins and rotational constants. Two energy level diagrams are proposed which are strongly influenced by earlier ArH2O studies. A brief qualitative discussion of the CH4{center dot}H2O binding energy compared to that of ArH2O is also included. 152 refs., 54 figs., 20 tabs.
Tunable Far-infrared Laser Spectroscopy of Clusters
Title | Tunable Far-infrared Laser Spectroscopy of Clusters PDF eBook |
Author | Charles Albert Schmuttenmaer |
Publisher | |
Pages | 532 |
Release | 1991 |
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Energy Research Abstracts
Title | Energy Research Abstracts PDF eBook |
Author | |
Publisher | |
Pages | 584 |
Release | 1990 |
Genre | Power resources |
ISBN |
Scientific and Technical Aerospace Reports
Title | Scientific and Technical Aerospace Reports PDF eBook |
Author | |
Publisher | |
Pages | 1460 |
Release | 1991 |
Genre | Aeronautics |
ISBN |
Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.