Transition Metal Mediated Transformations of Small Molecules . Progress Report
Title | Transition Metal Mediated Transformations of Small Molecules . Progress Report PDF eBook |
Author | |
Publisher | |
Pages | 22 |
Release | 1992 |
Genre | |
ISBN |
Work on organotransition metal chemistry, homogeneous and heterogeneous catalysis is summarized. Several cationic palladium(II) complexes with bulky phosphine or pyridine ligands were discovered that are highly selective catalysts for linear dimerization of vinyl monomers and linear polymerization of p-divinylbenzene, the reactions proceeding through a carbocationic mechanism. Our studies were continued on alternating olefin-carbon monoxide copolymers. The copolymerization reaction and reactivity of copolymers were examined. New catalytic systems for alternating copolymerization of [alpha]-olefins with CO were discovered. In the case of styrene derivatives, tactic copolymers were obtained. Poly(ethylenepyrrolediyl) derivatives were synthesized from alternating ethylene-carbon monoxide copolymer and become electronic conductors when doped with iodine. A catalytic system for direct synthesis of polyureas and polyoxamides from and diamines was also discovered. Pt metal catalyzed the oxidation of ethers, esters, and amines to carboxylic acids and the oxidation of olefins to 1,2-diols. Anaerobic and aerobic decomposition of molybdenum(VI)-oxoalkyl compounds were studied for heterogeneous oxidation of alkanes and olefins on Mo(VI)-oxide surfaces. Synthesis of polymer-trapped metal, metal oxide, and metal sulfide nanoclusters (size
Transition Metal Mediated Transformations of Small Molecules
Title | Transition Metal Mediated Transformations of Small Molecules PDF eBook |
Author | |
Publisher | |
Pages | 22 |
Release | 1992 |
Genre | |
ISBN |
Work on organotransition metal chemistry, homogeneous and heterogeneous catalysis is summarized. Several cationic palladium(II) complexes with bulky phosphine or pyridine ligands were discovered that are highly selective catalysts for linear dimerization of vinyl monomers and linear polymerization of p-divinylbenzene, the reactions proceeding through a carbocationic mechanism. Our studies were continued on alternating olefin-carbon monoxide copolymers. The copolymerization reaction and reactivity of copolymers were examined. New catalytic systems for alternating copolymerization of [alpha]-olefins with CO were discovered. In the case of styrene derivatives, tactic copolymers were obtained. Poly(ethylenepyrrolediyl) derivatives were synthesized from alternating ethylene-carbon monoxide copolymer and become electronic conductors when doped with iodine. A catalytic system for direct synthesis of polyureas and polyoxamides from and diamines was also discovered. Pt metal catalyzed the oxidation of ethers, esters, and amines to carboxylic acids and the oxidation of olefins to 1,2-diols. Anaerobic and aerobic decomposition of molybdenum(VI)-oxoalkyl compounds were studied for heterogeneous oxidation of alkanes and olefins on Mo(VI)-oxide surfaces. Synthesis of polymer-trapped metal, metal oxide, and metal sulfide nanoclusters (size
Energy Research Abstracts
Title | Energy Research Abstracts PDF eBook |
Author | |
Publisher | |
Pages | 654 |
Release | 1993 |
Genre | Power resources |
ISBN |
Scientific and Technical Aerospace Reports
Title | Scientific and Technical Aerospace Reports PDF eBook |
Author | |
Publisher | |
Pages | 692 |
Release | 1995 |
Genre | Aeronautics |
ISBN |
Part 1: Progress Towards the Transition Metal Mediated Reduction of Molecular Nitrogen : Synthesis and Characterization of Possible Precursors
Title | Part 1: Progress Towards the Transition Metal Mediated Reduction of Molecular Nitrogen : Synthesis and Characterization of Possible Precursors PDF eBook |
Author | Alesia N. Parker |
Publisher | |
Pages | |
Release | 1995 |
Genre | |
ISBN |
The Reactions of Small Molecules with Transition Metal Complexes
Title | The Reactions of Small Molecules with Transition Metal Complexes PDF eBook |
Author | D. Kelly |
Publisher | |
Pages | |
Release | 1990 |
Genre | |
ISBN |
Application of Transition Metal Catalysis to Small Molecule Synthesis
Title | Application of Transition Metal Catalysis to Small Molecule Synthesis PDF eBook |
Author | Christie Morrill |
Publisher | |
Pages | 476 |
Release | 2006 |
Genre | Electronic dissertations |
ISBN |