This book is a printed edition of the Special Issue "Thermodynamics and Statistical Mechanics of Small Systems" that was published in Entropy

This thesis presents a general theory of nonequilibrium thermodynamics for information processing. Ever since Maxwell's demon was proposed in the nineteenth century, the relationship between thermodynamics and information has attracted much attention because it concerns the foundation of the second law of thermodynamics. From the modern point of view, Maxwell's demon is formulated as an information processing device that performs measurement and feedback at the level of thermal fluctuations. By unifying information theory, measurement theory, and the recently developed theory of nonequilibrium statistical mechanics, the author has constructed a theory of "information thermodynamics," in which information contents and thermodynamic variables are treated on an equal footing. In particular, the maximum work that can be extracted by the demon and the minimum work that is needed for measurement and information erasure by the demon has been determined. Additionally, generalizations of nonequilibrium relations such as a Jarzynski equality for classical stochastic systems in the presence of feedback control have been derived. One of the generalized equalities has recently been verified experimentally by using sub-micron colloidal particles. The results obtained serve as fundamental principles for information processing in small thermodynamic systems, and are applicable to nanomachines and nanodevices.

Authoritative summary introduces basics, explores environmental variables, examines binding on macromolecules and aggregation, and includes brief summaries of electric and magnetic fields, spherical drops and bubbles, and polydisperse systems. 1963 and 1964 editions.

This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems in the range of sizes from one to 100 nm- when one cannot apply equations or traditional thermodynamic models.

Boltzmann's formula S = In(W(E) defines the microcanonical ensemble. The usual textbooks on statistical mechanics start with the microensemble but rather quickly switch to the canonical ensemble introduced by Gibbs. This has the main advantage of easier analytical calculations, but there is a price to pay -- for example, phase transitions can only be defined in the thermodynamic limit of infinite system size. The question how phase transitions show up from systems with, say, 100 particles with an increasing number towards the bulk can only be answered when one finds a way to define and classify phase transitions in small systems. This is all possible within Boltzmann's original definition of the microcanonical ensemble. Starting from Boltzmann's formula, the book formulates the microcanonical thermodynamics entirely within the frame of mechanics. This way the thermodynamic limit is avoided and the formalism applies to small as well to other nonextensive systems like gravitational ones. Phasetransitions of first order, continuous transitions, critical lines and multicritical points can be unambiguously defined by the curvature of the entropy S(E, N). Special attention is given to the fragmentation of nuclei and atomic clusters as a peculiar phase transition of small systems controlled, among others, by angular momentum. The dependence of the liquid-gas transition of small atomic clusters under prescribed pressure is treated. Thus the analogue to the bulk transition can be studied. New insights into the many facets of the many-body physics of the critical point are presented. The book also describes the microcanonical statistics of the collapse of a self-gravitating system under large angular momentum.

This book offers a comprehensive picture of nonequilibrium phenomena in nanoscale systems. Written by internationally recognized experts in the field, this book strikes a balance between theory and experiment, and includes in-depth introductions to nonequilibrium fluctuation relations, nonlinear dynamics and transport, single molecule experiments, and molecular diffusion in nanopores. The authors explore the application of these concepts to nano- and biosystems by cross-linking key methods and ideas from nonequilibrium statistical physics, thermodynamics, stochastic theory, and dynamical systems. By providing an up-to-date survey of small systems physics, the text serves as both a valuable reference for experienced researchers and as an ideal starting point for graduate-level students entering this newly emerging research field.

In this clear and concise introduction to thermodynamics and statistical mechanics the reader, who will have some previous exposure to thermodynamics, will be guided through each of the two disciplines separately initially to provide an in-depth understanding of the area and thereafter the connection between the two is presented and discussed. In addition, mathematical techniques are introduced at appropriate times, highlighting such use as: exact and inexact differentials, partial derivatives, Caratheodory's theorem, Legendre transformation, and combinatory analysis. * Emphasis is placed equally on fundamentals and applications * Several problems are included