This classic sets forth the fundamentals of thermodynamics and kinetic theory simply enough to be understood by beginners, yet with enough subtlety to appeal to more advanced readers, too.

The first objective of statistical mechanics is to explain the fundamental laws of thermodynamics from first principles based on the atomic structure of matter. This problem was attacked successfully first by MAXWELL and CLAUSIUS in studies on the kinetic theory of gases. It will be treated briefly in Sec. II-A, to gain some understanding and experience before dealing with more general problems. The second objective is then to calculate thermodynamics quantities from the microscopic laws governing the atomic motion. Whenever we try to lay the foundation of thermodynamics on an atomistic theory, we are confronted with a very strange situation. The thermodynamical state of a system is defined uniquely by only a few quantities, such as pressure, volume, energy, temperature, flow velocities, etc. In contrast, the atomistic descrip tion needs an enormous number of variables to define a state, e. g. , positions and velocities of all the atoms involved in classical mechanics or Schrodinger's wave function of the corresponding N body-problem in quantum mechanics. Classical mechanics, for instance, can predict the future development only if all the positions and velocities are known, say at time t = O. The number of values needed for this 23 purpose is of the order of 10 . Actually, only a few parameters are at our disposal from thermodynamics. Therefore, from thermodynamics we know almost nothing about the atomistic situation.

xi should hope for "first and foremost" from any historical investigation, including his own, was that "it may not be too tedious. " II That hope is generally realized in Mach's historical writings, most of which are as lively and interesting now as they were when they appeared. Mach did not follow any existing model of historical or philosophical or scientific exposition, but went at things his own way combining the various approaches as needed to reach the goals he set for himself. When he is at his best we get a sense of the Mach whom William James met on a visit to Prague, the Mach whose four hours of "unforgettable conversation" gave the forty year old, well traveled James the strongest "impression of pure intellectual genius" he had yet received, and whose "absolute simplicity of manner and winningness of smile" captivated him completely. 12 Consider, for example, the first few chapters of this book, Principles of the Theory of Heat, which Mach devotes to the notion of temperature, that most fundamental of all thermal concepts. He begins by trying to trace the path that leads from our sensations of hot and cold to a numerical temperature scale.

This text on the statistical theory of nonequilibrium phenomena grew out of lecture notes for courses on advanced statistical mechanics that were held more or less regularly at the Physics Department of the Technical University in Munich. My aim in these lectures was to incorporate various developments of many-body theory made during the last 20-30 years, in particular the correlation function approach, not just as an "extra" alongside the more "classical" results; I tried to use this approach as a unifying concept for the presentation of older as well as more recent results. I think that after so many excellent review articles and advanced treatments, correlation functions and memory kernels are as much a matter of course in nonequilibrium statistical physics as partition functions are in equilibrium theory, and should be used as such in regular courses and textbooks. The relations between correlation functions and earlier vehicles for the formulation of nonequilibrium theory such as kinetic equations, master equations, Onsager's theory, etc. , are discussed in detail in this volume. Since today there is growing interest in nonlinear phenomena I have included several chapters on related problems. There is some nonlinear response theory, some results on phenomenological nonlinear equations and some microscopic applications of the nonlinear response formalism. The main focus, however, is on the linear regime.

This classic sets forth the fundamentals of thermodynamics and kinetic theory simply enough to be understood by beginners, yet with enough subtlety to appeal to more advanced readers, too.

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