The Thermal Decomposition of Ethyl Nitrate
Title | The Thermal Decomposition of Ethyl Nitrate PDF eBook |
Author | H. S. B. Marshall |
Publisher | |
Pages | |
Release | 1952 |
Genre | |
ISBN |
A KINETIC STUDY OF THE THERMAL DECOMPOSITION OF ETHYL NITRATE.
Title | A KINETIC STUDY OF THE THERMAL DECOMPOSITION OF ETHYL NITRATE. PDF eBook |
Author | |
Publisher | |
Pages | 76 |
Release | 1952 |
Genre | |
ISBN |
The thermal decomposition of gaseous Et nitrate (I) was studied at 161 deg, 181 deg, and 201 deg C. The data (pressure of the particular component/initial pressure of I) were plotted according to a first-order reaction. The results at 161 deg and 181 deg C were divisible into 2 parts, an initial linear portion and a second linear portion of higher slope; the change in slope occurred at about 50 and 201 deg C did not permit division. The effects of NO sub-2, Et nitrite (II), and Hg on the decomposition rate are discussed. The NO sub-2 content usually did not exceed 10% of the initial amount of I; the NO sub- 2 pressure variation was attributed to NO sub-2 formation from the decomposition of I and NO sub-2 consumption by EtOH, a dissociation product of II. No formed directly from the decomposition of II. The presence of Me nitrite and MeNO sub-2 was established at the end of the reaction. Peak pressures of II occurred at 70 and 62% of the initial concentration of I at 161 deg and 181 deg C, respectively; more II was formed than could be accounted for by the NO sub-2-EtOH reaction. The decompostion mechanism of I cannot be completely explained by attributing the point of molecule fracture of the O-N bond.
The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Stand-point, Dissertation... by Edward L. Rodowskas,...
Title | The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Stand-point, Dissertation... by Edward L. Rodowskas,... PDF eBook |
Author | Edward L. Rodowskas |
Publisher | |
Pages | 7 |
Release | 1935 |
Genre | |
ISBN |
Thermal Decomposition of Organic Nitrates
Title | Thermal Decomposition of Organic Nitrates PDF eBook |
Author | |
Publisher | |
Pages | 0 |
Release | 1953 |
Genre | Decomposition (Chemistry) |
ISBN |
The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Standpoint ...
Title | The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Standpoint ... PDF eBook |
Author | Edward Laurence Rodowskas |
Publisher | |
Pages | 86 |
Release | 1935 |
Genre | Acetone |
ISBN |
The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Standpoint
Title | The Thermal Decomposition of Ethyl Nitrite and Acetone from the Free Radical Standpoint PDF eBook |
Author | Edward L.. Rodowskas |
Publisher | |
Pages | |
Release | 1935 |
Genre | |
ISBN |
The Kinetics of the Thermal Decomposition of Ethyl Bromide by Chemical Analysis
Title | The Kinetics of the Thermal Decomposition of Ethyl Bromide by Chemical Analysis PDF eBook |
Author | Arthur Edward Goldberg |
Publisher | |
Pages | 94 |
Release | 1949 |
Genre | |
ISBN |