The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals
Title | The Direct Synthesis of Optically Active Complexes of the Alkaline Earth Metals PDF eBook |
Author | Billy Thomas Upchurch |
Publisher | |
Pages | 114 |
Release | 1967 |
Genre | |
ISBN |
Synthesis of Chiral Rare Earth and Alkaline Earth Compounds
Title | Synthesis of Chiral Rare Earth and Alkaline Earth Compounds PDF eBook |
Author | Meng He |
Publisher | Cuvillier Verlag |
Pages | 134 |
Release | 2016-08-16 |
Genre | Science |
ISBN | 3736983301 |
The first chiral amidinate borohydride rare earth compounds and compounds based on (S)-HPEBA ((S,S)-N,N-bis-(1-phenylethyl)benzamidine) ligand were reported by Roesky et al. To continuing this work, the new chiral ligand (S)-HNEBA ((S,S)-N,N-bis-(1-naphthylethyl)benzamidine) were synthesized. The corresponding amidinate metal complexes were successfully obtained by amine elimination. The luminescent and magnetic properties of rare earth compounds were studied. Alkaline earth metal compounds have been extensively studied as catalysts in synthetic chemistry. However, chiral amidinate alkaline earth metal complexes have never been reported. Chiral amidinate ligand (S)-HPEBA was introduced into the coordination chemistry of the alkaline earth metal as well as divalent lanthanides, their catalytic activities in hydrophosphination have been investigated. The Ba compound showed high catalytic activities in the hydrophosphination reaction. Moreover, since rare earth metal COT complexes exhibit excellent SMM behavior, it is of great interest to study the magnetic behavior of COT amidinate complexes. Thus, amidine ligand (S)-HPEBA and (S)-HPETA are introduced into the corresponding COT amidinate complexes for magnetic properties studies. The Er Compound exhibited typical field-induced SMM behavior. Furthermore, inspired by the promising application of lanthanide SMMs and the research of SMMs based on sandwich type lanthanide complexes, a series of novel sandwich type complexes comprising of Pc and COT ligand were designed and synthesized.
Direct Synthesis of Metal Complexes
Title | Direct Synthesis of Metal Complexes PDF eBook |
Author | B.I. Kharisov |
Publisher | Elsevier |
Pages | 470 |
Release | 2018-04-19 |
Genre | Science |
ISBN | 0128110627 |
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. - Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more - Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water - Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Masters Theses and Doctoral Dissertations in the Pure and Applied Sciences Accepted by Colleges and Universities of the United States
Title | Masters Theses and Doctoral Dissertations in the Pure and Applied Sciences Accepted by Colleges and Universities of the United States PDF eBook |
Author | |
Publisher | |
Pages | 536 |
Release | 1968 |
Genre | Chemistry |
ISBN |
Master's Theses and Doctoral Dissertations in the Pure and Applied Sciences
Title | Master's Theses and Doctoral Dissertations in the Pure and Applied Sciences PDF eBook |
Author | |
Publisher | |
Pages | 166 |
Release | 1967 |
Genre | Dissertations, Academic |
ISBN |
Clemson College Faculty Publications and Research and Abstracts of Doctoral Dissertations and Master's Theses
Title | Clemson College Faculty Publications and Research and Abstracts of Doctoral Dissertations and Master's Theses PDF eBook |
Author | Clemson University. Graduate School |
Publisher | |
Pages | 130 |
Release | 1965 |
Genre | Dissertations, Academic |
ISBN |
Synthesis of Optically Active Cobalt-complexes as Catalysts for Enantioselective Reactions
Title | Synthesis of Optically Active Cobalt-complexes as Catalysts for Enantioselective Reactions PDF eBook |
Author | Sherine A. N. Khattab |
Publisher | |
Pages | 174 |
Release | 1990 |
Genre | |
ISBN |