Für das Verständnis der organischen Chemie muss man wissen, worum es sich bei funktionalen Gruppen handelt. Dieses Fachbuch steht ganz in der Tradition der Reihe Patai's Chemistry of Functional Groups. Jeder Band deckt sämtliche Aspekte funktionaler Gruppen ab und behandelt dabei theoretische, analytische, synthetische, biologische Aspekte sowie Belange der Industrie. Hypervalente Halogenverbindungen, insbesondere Jodverbindungen, sind überaus effiziente und selektive Oxidantien für eine Vielzahl funktionaler Gruppen. Die elektrophilen Eigenschaften dieser Reagenzien können auch für die Einführung anderer Funktionalisierungen verwendet werden. Dieser Band ist der erste in der Reihe, die die Eigenschaften und das chemische Verhalten von hypervalentem Jod und Brom, deren Einsatz in der organischen Synthese sowie deren industrielle Anwendung untersucht. Wie bei allen neuen Bänden, werden die Kapitel zunächst online in Patai's Chemistry of Functional Groups veröffentlicht. Wenn ein Band online vervollständigt ist, erfolgt die Herausgabe als Printversion. Die Printfassung entspricht der Qualität, die man von der Patai-Reihe kennt, und bietet auch einen umfassenden Index.

Das führende Referenzwerk für die bororganische Chemie Professor Mark Gandelman und seine Kollegen tauchen tief in die Theorie, Struktur, Analyse, Synthese und Reaktionen der bororganischen Chemie ein. Bororganische Verbindungen kommen als hocheffiziente Reagenzien bei vielen Reaktionen zum Einsatz, darunter bei Kreuzkupplungen und Radikal-Reaktionen. Die renommierten Autoren führen ihr Wissen der organischen und physikalischen Chemie in einem Werk zusammen. In der Regel stammen diese Informationen aus unterschiedlichen Quellen. Dieses Buch konzentriert sich auf vollständig biologisch abbaubare Reagenzien als Gegenpart zu umweltschädlichen Schwermetallkatalysatoren. The Chemistry of Organoboron Compounds bietet umfassende und ausführliche Informationen zu - dem Verhalten bororganischer Verbindungen, - dem Einsatz bororganischer Verbindungen in der organischen Synthese, - kommerziellen Anwendungen bororganischer Verbindungen. The Chemistry of Organoboron Compounds aus der gefeierten Reihe Patai's Chemistry of Functional Groups bietet alle Merkmale, die Leser von der Reihe gewohnt sind, auch ein ausführliches Stichwortverzeichnis.

The Chemistry of Organocobalt Compounds R–Co PATAI’s Chemistry of Functional Groups The Chemistry of Organocobalt Compounds A series of advanced treatises founded by Professor Saul Patai and now under the general editorship of Professors Ilan Marek and Joel F. Liebman PATAI’s Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical, and environmental aspects. To date, over 150 volumes have been published in the series. Recently Published Titles The Chemistry of Cyclobutanes (2 parts) The Chemistry of Peroxides (Volume 2, 2 parts) The Chemistry of Organozinc Compounds (2 parts) The Chemistry of Anilines (2 parts) The Chemistry of Organomagnesium Compounds (2 parts) The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids (2 volumes, 4 parts) The Chemistry of Metal Enolates (2 parts) The Chemistry of Organocopper Compounds (2 parts) The Chemistry of Organomanganese Compounds The Chemistry of Organic Selenium and Tellurium Compounds (Volume 3, 2 parts) The Chemistry of Organic Selenium and Tellurium Compounds (Volume 4, 2 parts) The Chemistry of Organoiron Compounds The Chemistry of Metal Phenolates The Chemistry of Peroxides (Volume 3, 2 parts) The Chemistry of Organogold Compounds (2 parts) The Chemistry of Organoaluminum Compounds The Chemistry of Metal Enolates (Volume 2) The Chemistry of Metal Phenolates (Volume 2) The Chemistry of Hypervalent Halogen Compounds (2 parts) The Chemistry of Nitrogen-rich Functional Groups The Chemistry of Organoboron Compounds (2 parts) Forthcoming Titles The Chemistry of Nitrogen-rich Functional Groups (Volume 2) The Chemistry of Organofluorine Compounds PATAI Online PATAI’s Chemistry of Functional Groups is available in electronic format on Wiley Online Library.

Nitrogen is unique among the non-carbon atoms in its ability to form single, double, and triple bonds with itself, giving rise to a wide range of organic-chemical groups containing several nitrogen atoms in different states and geometries. The present volume surveys the properties and chemical behaviour of all important nitrogen-rich organic-chemical groups, including azides, azimines, aziridines, diazo compounds, nitramines, nitrenes, nitrosamines, polyazine N-oxides, tetrazoles, triazanes, triazenes, and triazoles. A special focus lies on commercially important species which are used, e. g., as powerful explosives. PATAI's Chemistry of Functional Groups publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopic methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, almost 150 volumes have been published in the series.

T. Wirth: Introduction and General Aspects.- M. Ochiai: Reactivities, Properties and Structures.- A. Varvoglis: Preparation of Hypervalent Iodine Compounds.- V.V. Zhdankin: C-C-Bond Forming Reactions.- G.F. Koser: C- Heteroatom-Bond Forming Reactions.- G.F. Koser: Heteroatom- Heteroatom-Bond Forming Reactions.- T. Wirth: Oxidations and Rearrangements.- H. Tohma, Y. Kita: Synthetic Applications (Total Synthesis and Natural Product Synthesis).

Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.

This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. - Features up-to-date coverage of a wide range of topics - Includes many tables featuring a diversity of reactivity, and a comprehensive index - Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry - Contains a section on unusual efficiency of hypervalent iodine reactions