Sythesis and Thermal Decomposition of Nitrate Esters
Title | Sythesis and Thermal Decomposition of Nitrate Esters PDF eBook |
Author | Michael A. Hiskey |
Publisher | |
Pages | 414 |
Release | 1990 |
Genre | Nitrates |
ISBN |
An Analysis of the Pressure Dependence of Nitrate Ester Thermal Decomposition
Title | An Analysis of the Pressure Dependence of Nitrate Ester Thermal Decomposition PDF eBook |
Author | George F. Adams |
Publisher | |
Pages | 34 |
Release | 1978 |
Genre | |
ISBN |
An analytical study of the effect of pressure on the rate constant for the unimolecular decomposition of n-propyl nitrate is given. The Rice- Ramsperger-Kassel-Marcus theory is reviewed, and the present application is discussed in detail. Limitations on application of this model are also discussed. It is concluded that the initial decomposition reaction of nitrate esters cannot be the rate determining step for the observed variation of burning rate with pressure.
Nitrate Esters Chemistry and Technology
Title | Nitrate Esters Chemistry and Technology PDF eBook |
Author | Jiping Liu |
Publisher | Springer |
Pages | 694 |
Release | 2019-03-06 |
Genre | Science |
ISBN | 9811366470 |
The idea of this book is to present the up-to-date research results on Nitrate Esters as explosive materials. It covers many aspects including the material structures, nitrating agent, chemical synthesis devices, preparation technology, and applications etc. In particular, this work sheds light on the comprehensive utilization and thorough destruction of the used Nitrate Easters which is crucial for preventing repeated pollution. This is a highly informative and instructive book providing insight for the researchers working on nitrating theory, energetic materials and chemical equipments.
Synthesis of a New Energetic Nitrate Ester
Title | Synthesis of a New Energetic Nitrate Ester PDF eBook |
Author | |
Publisher | |
Pages | |
Release | 2008 |
Genre | |
ISBN |
Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.
The Synthesis and Thermal Decomposition of the Sodium Salts of Some N-(p-tosyl) Hydrazimidocarboxylate Esters
Title | The Synthesis and Thermal Decomposition of the Sodium Salts of Some N-(p-tosyl) Hydrazimidocarboxylate Esters PDF eBook |
Author | Richard N. McDonald |
Publisher | |
Pages | 7 |
Release | 1965 |
Genre | |
ISBN |
A convenient synthesis of N'-(p-tosyl)hydrazimido carboxylate esters (CH3PhSO2NHN=C(R)2) is described and results of studies on the thermal decomposition of the sodium salts of three of these esters are given. The compounds are of possible value for the generation of carbenes.
Thermal Decomposition and Combustion of Explosives and Propellants
Title | Thermal Decomposition and Combustion of Explosives and Propellants PDF eBook |
Author | G.B. Manelis |
Publisher | CRC Press |
Pages | 373 |
Release | 2003-01-30 |
Genre | Science |
ISBN | 1482288265 |
This unique book investigates the synthesis, kinetics, and thermal decomposition properties and processing of energy-producing materials used in propellants, explosives, pyrotechnic, and gas-generating compositions. Thermal Decomposition and Combustion of Explosives and Propellants provides several mechanisms and stages for the thermal deco
The Thermal Decomposition of Simple Nitrite Esters
Title | The Thermal Decomposition of Simple Nitrite Esters PDF eBook |
Author | JOSEPH B. LEVY |
Publisher | |
Pages | 22 |
Release | 1954 |
Genre | |
ISBN |