Synthetic Membranes and Membrane Separation Processes addresses both fundamental and practical aspects of the subject. Topics discussed in the book cover major industrial membrane separation processes, including reverse osmosis, ultrafiltration, microfiltration, membrane gas and vapor separation, and pervaporation. Membrane materials, membrane preparation, membrane structure, membrane transport, membrane module and separation design, and applications are discussed for each separation process. Many problem-solving examples are included to help readers understand the fundamental concepts of the theory behind the processes. The book will benefit practitioners and students in chemical engineering, environmental engineering, and materials science.

Synthetic Membranes and Membrane Separation Processes addresses both fundamental and practical aspects of the subject. Topics discussed in the book cover major industrial membrane separation processes, including reverse osmosis, ultrafiltration, microfiltration, membrane gas and vapor separation, and pervaporation. Membrane materials, membrane preparation, membrane structure, membrane transport, membrane module and separation design, and applications are discussed for each separation process. Many problem-solving examples are included to help readers understand the fundamental concepts of the theory behind the processes. The book will benefit practitioners and students in chemical engineering, environmental engineering, and materials science.

The chapters in this book are based upon lectures given at the NATO Advanced Study Institute on Synthetic Membranes (June 26-July 8, 1983, Alcabideche, Portugal), which provided an integrated presentation of syn thetic membrane science and technology in three broad areas. Currently available membrane formation mechanisms are reviewed, as well as the manner in which synthesis conditions can be controlled to achieve desired membrane structures. Membrane performance in a specific separa tionprocess involves complex phenomena, the understanding of which re quires a multidisciplinary approach encompassing polymer chemistry, phys ical chemistry, and chemical engineering. Progress toward a global understanding of membrane phenomena is described in chapters on the principles of membrane transport. The chapters on membrane processes and applications highlight both established and emerging membrane processes, and elucidate their myriad applications. It is our hope that this book will be an enduring, comprehensive compen dium of the state of knowledge in the field of synthetic membranes. We have been encouraged in that hope by numerous expressions of interest in the book, coming from a variety of potential users.

Membrane science and technology is an expanding field and has become a prominent part of many activities within the process industries. It is relatively easy to identify the success stories of membranes such as desali nation and microfiltration and to refer to others as developing areas. This, however, does not do justice to the wide field of separations in which membranes are used. No other 'single' process offers the same potential and versatility as that of membranes. The word separation classically conjures up a model of removing one component or species from a second component, for example a mass transfer process such as distillation. In the field of synthetic membranes, the terminology 'separation' is used in a wider context. A range of separations of the chemical/mass transfer type have developed around the use of membranes including distillation, extraction, absorption, adsorption and stripping, as well as separations of the physical type such as filtration. Synthetic membranes are an integral part of devices for analysis, energy generation and reactors (cells) in the electrochemical industry.

Researchers in polymeric membranes as well as R&D professionals will find this work an essential addition to the literature. It concentrates on the method recently developed to study the surfaces of synthetic polymeric membranes using an Atomic Force Microscope (AFM), which is fast becoming a very important tool. Each chapter includes information on basic principles, commercial applications, an overview of current research and guidelines for future research.

The chapters of this book are based upon lectures presented at the NATO Advanced Study Institute on Membrane Processes in Separation and Purification (March 21 - April 2, 1993, Curia, Portugal), organized as a successor and update to a similar Institute that took place 10 years ago (p.M.Bungay, H.K. Lonsdale, M.N. de Pinho (Eds.): Synthetic Membranes: Science, Engineering and Applications, NATO ASI Series, Reidel, Dordrecht, 1986). The decade between the two NATO Institutes witnesses the transition from individually researched membrane processes to an applied and established membrane separation technology, as is reflected by the contents of the corresponding proceeding volumes. By and large, the first volume presents itself as a textbook on membrane processes, still valid, while the present volume focuses on areas of separation need as amenable to membrane processing: Biotechnology and Environmental Technology. Accordingly, the contributions to this volume are grouped into "Membranes in Biotechnology" (11 papers), "Membranes in Environmental Technology" (6 papers), and "New Concepts" (4 papers). This is followed by one contribution each on "Energy Requirements" and "Education", i.e., membrane processes within an academic curriculum. The book thus amounts to a state of the art of applied membrane processing and may well augment the more fundamental approach of its predecessor.

III . 2 Preparation of synthetic membranes 72 III . 3 Phase inversion membranes 75 III. 3. 1 Preparation by evaporation 76 III . 3. 2 Precipitation. from the vapour phase 76 III . 3. 3 Precipitation by controlled evaporation 76 Thermal precipitation 76 III . 3. 4 III . 3. 5 Immersion precipitation 77 Preparation techniques for immersion precipitation 77 III . 4 Flat membranes 77 III . 4. 1 78 III . 4. 2 Tubular membranes 81 III . 5 Preparation techniques for composite membranes 82 III. 5. 1 Interfacial polymerisation Dip-coating 83 III . 5. 2 III . 5. 3 Plasma polymerisation 86 III . 5. 4 Modification of homogeneous dense membranes 87 III . 6 Phase separation in polymer systems 89 III . 6. 1 Introduction 89 III . 6. 1. 1 Thermodynamics 89 III . 6. 2 Demixing processes 99 III . 6. 2. 1 Binary mixtures 99 III . 6. 2. 2 Ternary systems 102 III . 6. 3 Crystallisation 104 III . 6. 4 Gelation 106 III . 6. 5 Vitrification 108 III . 6. 6 Thermal precipitation 109 III . 6. 7 Immersion precipitation 110 III . 6. 8 Diffusional aspects 114 III . 6. 9 Mechanism of membrane formation 117 III. 7 Influence of various parameters on membrane morphology 123 III. 7. 1 Choice of solvent-nonsolvent system 123 III . 7. 2 Choice of the polymer 129 III . 7. 3 Polymer concentration 130 III . 7. 4 Composition of the coagulation bath 132 III . 7. 5 Composition of the casting solution 133 III . 7.