Studies in nucleophilic aromatic substitution
Title | Studies in nucleophilic aromatic substitution PDF eBook |
Author | |
Publisher | |
Pages | 19 |
Release | 1966 |
Genre | |
ISBN |
Studies in nucleophilic aromatic substitution
Title | Studies in nucleophilic aromatic substitution PDF eBook |
Author | Bo Lamm |
Publisher | |
Pages | 19 |
Release | 1966 |
Genre | |
ISBN |
Studies on Nucleophilic Aromatic Substitution Reactions and the Smiles Rearrangement
Title | Studies on Nucleophilic Aromatic Substitution Reactions and the Smiles Rearrangement PDF eBook |
Author | Philip Reginald Williams |
Publisher | |
Pages | |
Release | 1978 |
Genre | |
ISBN |
Modern Nucleophilic Aromatic Substitution
Title | Modern Nucleophilic Aromatic Substitution PDF eBook |
Author | Francois Terrier |
Publisher | John Wiley & Sons |
Pages | 488 |
Release | 2013-05-20 |
Genre | Science |
ISBN | 3527656162 |
This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the reactivity of strongly electron-deficient aromatic and heteroaromatic structures. The numerous synthetic applications are considered in depth in the chapters 4 and 5 that follow on intermolecular and intramolecular nucleophilic aromatic substitutions. Then, chapter 6 focuses on substitutions proceeding formally through displacement of a hydride ion, a hot topic in the field. The final chapter brings together concise yet comprehensive discussions surrounding SNAr photosubstitutions, radical substitutions, and ANRORC substitutions. Authored by a highly respected chemist who has contributed greatly to the field over the past two decades, this is a valuable information source for all organic chemists working in academia or the pharmaceutical and agrochemical industries.
Nucleophilic Aromatic Substitution of Hydrogen
Title | Nucleophilic Aromatic Substitution of Hydrogen PDF eBook |
Author | Oleg N. Chupakhin |
Publisher | Academic Press |
Pages | 378 |
Release | 2012-12-02 |
Genre | Science |
ISBN | 0323140599 |
Nucleophilic aromatic substitution in carbo- and heteroaromatic systems is a subject of considerable interest to chemists. This book uniquely addresses the systematic analysis of a vast range of nucleophilic substitutions of aromatic hydrogen. - Nucleophilic displacement of hydrogen (the S N/H reactions) in pi-deficient aromatics, such as nitroarenes, arene-metal complexes, and the like - Nucleophilic displacement of hydrogen in heterocyclic substrates such as pyridines, their aza and benzo analogs, pyrylium and thiapyrylium cations, and other heterocycles - Mechanisms for the S N/H reactions (S N/H(AE), vicarious nucleophilic substitutions, and radical S N/H substitutions
Studies on Chemistry of Aromatic Nucleophilic Substitution Reaction in Solvents of Low Relative Permittivity
Title | Studies on Chemistry of Aromatic Nucleophilic Substitution Reaction in Solvents of Low Relative Permittivity PDF eBook |
Author | Sun Li-Quan |
Publisher | |
Pages | 0 |
Release | 2023-03 |
Genre | |
ISBN | 9781649975348 |
Studies on Chemistry of Aromatic Nucleophilic Substitution Reaction in Solvents of Low Relative Permittivity
Title | Studies on Chemistry of Aromatic Nucleophilic Substitution Reaction in Solvents of Low Relative Permittivity PDF eBook |
Author | Li-Quan Sun |
Publisher | Scientific Research Publishing, Inc. USA |
Pages | 214 |
Release | 2023-03-02 |
Genre | Antiques & Collectibles |
ISBN | 164997535X |
This book is based on a partial fulfillment of my doctoral thesis, which was finished about 20 years ago. This book is composed of 7 chapters. In the present work, the author is trying to describe his contribution to the chemistry of a fundamental unit reaction, bimolecular aromatic nucleophilic substitution (SNAr) reaction, with the hope of leaving something for the welfare of the human being.