The first concern of scientists who are interested in synthetic polymers has always been, and still is: How are they synthesized? But right after this comes the question: What have I made, and for what is it good? This leads to the important topic of the structure-property relations to which this book is devoted. Polymers are very large and very complicated systems; their character ization has to begin with the chemical composition, configuration, and con formation of the individual molecule. The first chapter is devoted to this broad objective. The immediate physical consequences, discussed in the second chapter, form the basis for the physical nature of polymers: the supermolecular interactions and arrangements of the individual macromolecules. The third chapter deals with the important question: How are these chemical and physical structures experimentally determined? The existing methods for polymer characterization are enumerated and discussed in this chapter. The following chapters go into more detail. For most applications-textiles, films, molded or extruded objects of all kinds-the mechanical and the thermal behaviors of polymers are of pre ponderant importance, followed by optical and electric properties. Chapters 4 through 9 describe how such properties are rooted in and dependent on the chemical structure. More-detailed considerations are given to certain particularly important and critical properties such as the solubility and permeability of polymeric systems. Macromolecules are not always the final goal of the chemist-they may act as intermediates, reactants, or catalysts. This topic is presented in Chapters 10 and 11.

Featuring contributions from experts at some of the world's leading academic and industrial institutions, Advanced Polymeric Materials: Structure Property Relationships brings into book form a wealth of information previously available primarily only within computer programs. In a welcome narrative treatment, it provides comprehensive coverage of p

This collection of research and review papers is aimed at depicting the state of the art on the possible correlations between processing variables, obtained structure and special properties which this structure induces on the plastic part. The extraordinary capacity of plastics to modify their properties according to a particular structure is evidenced for several transformation processes and for many applications. The final common goal is to take profit of this peculiar capacity of plastics by inducing, through a suitable processing, a specific spatial organization.

Polymeric Foams Structure–Property–Performance: A Design Guide is a response to the design challenges faced by engineers in a growing market with evolving standards, new regulations, and an ever-increasing variety of application types for polymeric foam. Bernard Obi, an author with wide experience in testing, characterizing, and applying polymer foams, approaches this emerging complexity with a practical design methodology that focuses on understanding the relationship between structure–properties of polymeric foams and their performance attributes. The book not only introduces the fundamentals of polymer and foam science and engineering, but also goes more in-depth, covering foam processing, properties, and uses for a variety of applications. By connecting the diverse technologies of polymer science to those from foam science, and by linking both micro- and macrostructure–property relationships to key performance attributes, the book gives engineers the information required to solve pressing design problems involving the use of polymeric foams and to optimize foam performance. With a focus on applications in the automotive and transportation industries, as well as uses of foams in structural composites for lightweight applications, the author provides numerous case studies and design examples of real-life industrial problems from various industries and their solutions. Provides the science and engineering fundamentals relevant for solving polymer foam application problems Offers an exceptionally practical methodology to tackle the increasing complexity of real-world design challenges faced by engineers working with foams Discusses numerous case studies and design examples, with a focus on automotive and transportation Utilizes a practical design methodology focused on understanding the relationship between structure-properties of polymeric foams and their performance attributes

Explores relationships between spectroscopic findings and physical properties of polymers. Thirty-five chapters are divided into six sections covering fundamental concepts in FT-IR, FT-Raman, fluorescence spectroscopy and FT-Mass Spectrometry of polymers; crystalline polymers and copolymers; surfaces and interfaces of polymers; spectroscopic approaches to polymers in solutions and polymer networks; spectroscopy combined with thermally induced processes in polymers; and polymer analysis and surface modifications using non-conventional energy sources. Includes tutorial chapters designed to assist newcomers to the field.

Featuring contributions from experts at some of the world's leading academic and industrial institutions, Advanced Polymeric Materials: Structure Property Relationships brings into book form a wealth of information previously available primarily only within computer programs. In a welcome narrative treatment, it provides comprehensive coverage of p