This practical, concise guide showcases the sustainable methods offered by green free radical chemistry and summarizes the fundamental science involved.

Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.

The present monograph presents 17 in-depths reviews from eminent professors, scientists, chemists and engineers from educational institutions, research organizations and chemical industries introducing a new emerging green face of multidimensional chemistry. It addresses different topics under the domain of 'Green Chemistry' like Introductory aspects, alternate approaches to solvent chemistry, Environment friendly Green techniques, Alternative wastewater treatment technologies and Step change technologies for exploiting Green Chemistry.

Green Chemical Synthesis with Microwaves and Ultrasound A guide to the efficient and sustainable synthesis of organic compounds Chemical processes and the synthesis of compounds are essential aspects of numerous industries, and particularly central to the creation of drug-like structures. Their often significant environmental biproducts, however, have driven substantial innovations in the areas of green and organic synthesis, which have the potential to drive efficient, solvent-free synthesis and create more sustainable chemical processes. The use of microwaves and ultrasounds in chemical synthesis has proven an especially fruitful area of research, with the potential to produce a more sustainable industrial future. Green Chemical Synthesis with Microwaves and Ultrasound provides a comprehensive overview of recent advances in microwave- and ultrasound-driven synthesis and their cutting-edge applications. Green Chemical Synthesis with Microwaves and Ultrasound readers will also find: Introduction to the key equipment and tools of green chemical synthesis Detailed discussion of methods including ultrasound irradiation, metal-catalyzed reactions, enzymatic reactions, and many more An authorial team with immense experience in environmentally friendly organic chemical production Green Chemical Synthesis with Microwaves and Ultrasound is ideal for chemists, organic chemists, chemical engineers, biochemists, and any researchers or industry professionals working on the synthesis of chemicals and/or organic compounds.

Discussing the broad impact of alternative energy transfer technologies on reactions, separations and materials synthesis, for industrialists, academics and postgraduates in alternative-energy based processing.

Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.

This second edition Encyclopedia supplies nearly 350 gold standard articles on the methods, practices, products, and standards influencing the chemical industries. It offers expertly written articles on technologies at the forefront of the field to maximize and enhance the research and production phases of current and emerging chemical manufacturing practices and techniques. This collecting of information is of vital interest to chemical, polymer, electrical, mechanical, and civil engineers, as well as chemists and chemical researchers. A complete reconceptualization of the classic reference series the Encyclopedia of Chemical Processing and Design, whose first volume published in 1976, this resource offers extensive A-Z treatment of the subject in five simultaneously published volumes, with comprehensive indexing of all five volumes in the back matter of each tome. It includes material on the design of key unit operations involved with chemical processes; the design, unit operation, and integration of reactors and separation systems; process system peripherals such as pumps, valves, and controllers; analytical techniques and equipment; and pilot plant design and scale-up criteria. This reference contains well-researched sections on automation, equipment, design and simulation, reliability and maintenance, separations technologies, and energy and environmental issues. Authoritative contributions cover chemical processing equipment, engineered systems, and laboratory apparatus currently utilized in the field. It also presents expert overviews on key engineering science topics in property predictions, measurements and analysis, novel materials and devices, and emerging chemical fields. ALSO AVAILABLE ONLINE This Taylor & Francis encyclopedia is also available through online subscription, offering a variety of extra benefits for both researchers, students, and librarians, including: Citation tracking and alerts Active reference linking Saved searches and marked lists HTML and PDF format options Contact Taylor and Francis for more information or to inquire about subscription options and print/online combination packages. US: (Tel) 1.888.318.2367; (E-mail) [email protected] International: (Tel) +44 (0) 20 7017 6062; (E-mail) [email protected]