Sonochemistry and cavitation are rapidly increasing in importance in modern chemistry as a result of many significant achievements made in recent years. In this current and comprehensive text, the author clearly details and illustrates these developments as well as the fundamental concepts. Much attention is given to the fundamental problems, such as the general kinetics of sonochemical reactions: energetic yields; the principles of the cavitation diffusion theory; the place of acoustic energy among other physical methods of action on matter; and the new electrical theory of cavitation phenomena, sonochemical reactions and sonoluminescence initiation (the theory developed by Professor Margulis). Results of low-frequency acoustic fields investigations are also observed. Special attention is given to the influence of acoustic fields on chemical reactions in nonaqueous systems, catalytic processes and the initiation of oscillating reactions. This publication is designed to broaden the application of ultrasound in chemical technology and improve the efficiency of existing production processes. Its comprehensiveness makes it a practical handbook which will prove invaluable to a broad readership amongst chemistry, engineering and physics undergraduates, graduates, researchers, and industrialists working in the fields of sonochemistry, ultrasonic and chemical technology, high energy chemistry, acoustics and biology.

Energy Aspects of Acoustic Cavitation and Sonochemistry: Fundamentals and Engineering covers topics ranging from fundamental modeling to up-scaled experiments. The book relates acoustic cavitation and its intrinsic energy balance to macroscopic physical and chemical events that are analyzed from an energetic perspective. Outcomes are directly projected into practical applications and technological assessments covering energy consumption, thermal dissipation, and energy efficiency of a diverse set of applications in mixed phase synthesis, environmental remediation and materials chemistry. Special interest is dedicated to the sonochemical production of hydrogen and its energetic dimensions. Due to the sensitive energy balance that governs this process, this is seen as a "green process" for the production of future energy carriers. - Provides a concise and detailed description of energy conversion and exchange within the single acoustic cavitation bubble and bubble population, accompanying physical and chemical effects - Features a comprehensive approach that is supported by experiments and the modeling of energy concentration within the sonochemical reactor, jointly with energy dissipation and damping phenomenon - Gives a clear definition of energy efficiency metrics of industrial sono-processes and their application to the main emergent industrial fields harnessing acoustic cavitation and sonochemistry, notably for the production of hydrogen

Sonochemistry is studied primarily by chemists and sonoluminescence mainly by physicists, but a single physical phenomenon - acoustic cavitation - unites the two areas. The physics of cavitation bubble collapse, is relatively well understood by acoustical physicists but remains practically unknown to the chemists. By contrast, the chemistry that gives rise to electromagnetic emissions and the acceleration of chemical reactions is familiar to chemists, but practically unknown to acoustical physicists. It is just this knowledge gap that the present volume addresses. The first section of the book addresses the fundamentals of cavitation, leading to a more extensive discussion of the fundamentals of cavitation bubble dynamics in section two. A section on single bubble sonoluminescence follows. The two following sections address the new scientific discipline of sonochemistry, and the volume concludes with a section giving detailed descriptions of the applications of sonochemistry. The mixture of tutorial lectures and detailed research articles means that the book can serve as an introduction as well as a comprehensive and detailed review of these two interesting and topical subjects.

This book provides an introduction to the fundamental and applied aspects of sonochemistry, discussing a number of basic concepts in sonochemistry, such as how ultrasonic waves interact with gas bubbles in liquids to generate cavitation, and how the high temperatures generated within cavitation bubbles could be estimated. It explains how redox radicals are produced and how to make use of both the physical and chemical forces generated during cavitation for various applications. Intended for academic researchers, industry professionals as well as undergraduate and graduate students, especially those starting on a new research topic or those new to the field, it provides a clear understanding of the concepts and methodologies involved in ultrasonic and sonochemistry.

Sonochemistry and the Acoustic Bubble provides an introduction to the way ultrasound acts on bubbles in a liquid to cause bubbles to collapse violently, leading to localized 'hot spots' in the liquid with temperatures of 5000° celcius and under pressures of several hundred atmospheres. These extreme conditions produce events such as the emission of light, sonoluminescence, with a lifetime of less than a nanosecond, and free radicals that can initiate a host of varied chemical reactions (sonochemistry) in the liquid, all at room temperature. The physics and chemistry behind the phenomena are simply, but comprehensively presented. In addition, potential industrial and medical applications of acoustic cavitation and its chemical effects are described and reviewed. The book is suitable for graduate students working with ultrasound, and for potential chemists and chemical engineers wanting to understand the basics of how ultrasound acts in a liquid to cause chemical and physical effects.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.