The oceans and atmosphere interact through various processes, including the transfer of momentum, heat, gases and particles. In this book leading international experts come together to provide a state-of-the-art account of these exchanges and their role in the Earth-system, with particular focus on gases and particles. Chapters in the book cover: i) the ocean-atmosphere exchange of short-lived trace gases; ii) mechanisms and models of interfacial exchange (including transfer velocity parameterisations); iii) ocean-atmosphere exchange of the greenhouse gases carbon dioxide, methane and nitrous oxide; iv) ocean atmosphere exchange of particles and v) current and future data collection and synthesis efforts. The scope of the book extends to the biogeochemical responses to emitted / deposited material and interactions and feedbacks in the wider Earth-system context. This work constitutes a highly detailed synthesis and reference; of interest to higher-level university students (Masters, PhD) and researchers in ocean-atmosphere interactions and related fields (Earth-system science, marine / atmospheric biogeochemistry / climate). Production of this book was supported and funded by the EU COST Action 735 and coordinated by the International SOLAS (Surface Ocean- Lower Atmosphere Study) project office.

This book arises from a NATO-sponsored Advanced Study Institute on 'The Role of Air-Sea Exchange in Geochemical Cycling' held at Bombann@§. near Bordeaux, France. from 16 to 27 September 1985. The chapters of the book are the written versions of the lectures given at the Institute. The aim of the book is to give a comprehensive up-to-date coverage of the subject. presented in a teaching mode. The chapters contain much recent research material and attempt to give the reader an understanding of how the role of air-sea exchange in geochemical cycling can be quantitatively assessed. In the last decade, major advances in the fields of marine and atmospheric chemistry have underlined the role of physical, chemical and biological processes at and near the air-sea interface in a number of geochemical cycles (C. S, N, metals etc ... ). Further, there is strong concern over the anthropogenic perturbation of these cycles on both regional and global scales. The first part of the book (Chapters 1 to 8) provides a review of topics fundamental to such studies. These topics include concepts in geochemical modelling, assessment of atmospheric transport from sources to the oceans. description of mixing and transport processes within the ocean for both dissolved and particulate materials, quantification of air-sea fluxes for both gases and particles, photochemical transformations in the atmospheric and oceanic boundary layers.

At a time when the polar regions are undergoing rapid and unprecedented change, understanding exchanges of momentum, heat and salt at the ice-ocean interface is critical for realistically predicting the future state of sea ice. By offering a measurement platform largely unaffected by surface waves, drifting sea ice provides a unique laboratory for studying aspects of geophysical boundary layer flows that are extremely difficult to measure elsewhere. This book draws on both extensive observations and theoretical principles to develop a concise description of the impact of stress, rotation, and buoyancy on the turbulence scales that control exchanges between the atmosphere and underlying ocean when sea ice is present. Several interesting and unique observational data sets are used to illustrate different aspects of ice-ocean interaction ranging from the impact of salt on melting in the Greenland Sea marginal ice zone, to how nonlinearities in the equation of state for seawater affect mixing in the Weddell Sea. The book’s content, developed from a series of lectures, may be appropriate additional material for upper-level undergraduates and first-year graduate students studying the geophysics of sea ice and planetary boundary layers.

During the 1980's a wealth of information was reported from field and laboratory experiments in order to validate andlor modify various aspects of the surface layer Monin-Obukhov (M-O) similarity theory for use over the sea, and to introduce and test new concepts related to high resolution flux magnitudes and variabilities. For example, data from various field experiments conducted on the North Sea, Lake Ontario, and the Atlantic experiments, among others, yielded information on the dependence of the flux coefficients on wave state. In all field projects, the usual criteria for satisfying M-O similarity were applied. The assumptions of stationarity and homogeneity was assumed to be relevant over both small and large scales. In addition, the properties of the outer layer were assumed to be "correlated" with properties of the surface layer. These assumptions generally required that data were averaged for spatial footprints representing scales greater than 25 km (or typically 30 minutes or longer for typical windspeeds). While more and more data became available over the years, and the technology applied was more reliable, robust, and durable, the flux coefficients and other turbulent parameters still exhibited significant unexplained scatter. Since the scatter did not show sufficient reduction over the years to meet customer needs, in spite of improved technology and heavy financial investments, one could only conclude that perhaps the use of similarity theory contained too many simplifications when applied to environments which were more complicated than previously thought.

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