The rheological, chemical and microstructural properties of asphalt binders change with oxidative aging which is accelerated at elevated temperatures. Aging stiffens asphalt binders and increases the embrittlement of asphalt mixtures which would lead to fatigue cracking and eventually pavement failure under repetitive traffic loading. This study explored the feasibility of using antioxidant additives and copolymers with antioxidant agents to retard oxidative aging of asphalt binders. The performance of the additives was evaluated at the binder and mastic levels. The laboratory experiments included two unmodified binders, various antioxidant additives and copolymers, and three aggregate types. The fatigue characteristics of asphalt binders and mastic were determined before and after aging and an aging index was defined to evaluate the effect of the additives on aging. The results demonstrated that certain antioxidants and copolymers such as Redicote AP, Solprene, and Calprene may retard the aging and improve the rheological properties of the asphalt binders. In addition, the results of mastic testing confirmed the favorable effect of certain antioxidants on improving the resistance to fatigue cracking. Furthermore, the type of aggregate was found to influence the rate of aging of asphalt mixtures. Based on the rheological and fracture test results on asphalt binders and mastic, the effect of antioxidants was further investigated and validated at spectroscopic, chemical and microstructural level using Fourier-transform infrared spectroscopy (FTIR), Gel-permeation chromatography (GPC) and Atomic Force Microscopy (AFM), respectively. The spectroscopic analysis with FTIR supported the efficacy of the additives in retarding aging by reducing the carbonyl growth in aged binders. The chemical analysis with GPC confirmed that both Redicote and Solprene were capable of reducing the large molecular size fraction in binders subjected to long-term aging. The image analysis with AFM provided insight on the spatial distribution, surface roughness parameters and micromechanical properties (i.e., adhesion, stiffness) of various phases and the effect of aging on the micro-rheology of antioxidant-modified binders. The last part of this study examined the effect of aging on the viscoelastic response of asphalt mixture using the Prony series representation and a newly developed parameter called aging state variable 'A'. The dynamic modulus test data was used for the analysis. The aging state variable 'A' was found to capture the effect of aging temperature and duration of aging on the viscoelastic properties of asphalt mixtures.

Climate change, energy production and consumption, and the need to improve the sustainability of all aspects of human activity are key inter-related issues for which solutions must be found and implemented quickly and efficiently. To be successfully implemented, solutions must recognize the rapidly changing socio-techno-political environment and multi-dimensional constraints presented by today’s interconnected world. As part of this global effort, considerations of climate change impacts, energy demands, and incorporation of sustainability concepts have increasing importance in the design, construction, and maintenance of highway and airport pavement systems. To prepare the human capacity to develop and implement these solutions, many educators, policy-makers and practitioners have stressed the paramount importance of formally incorporating sustainability concepts in the civil engineering curriculum to educate and train future civil engineers well-equipped to address our current and future sustainability challenges. This book will prove a valuable resource in the hands of researchers, educators and future engineering leaders, most of whom will be working in multidisciplinary environments to address a host of next-generation sustainable transportation infrastructure challenges. "This book proposes a broad detailed overview of the actual scientific knowledge about pavements linked to climate change, energy and sustainability at the international level in an original multidimensional/multi-effects way. By the end, the reader will be aware of the whole global issues to care about for various pavement technical features around the world, among which the implications of modelling including data collection, challenging resources saving and infrastructures services optimisation. This is a complete and varied work, rare in the domain." Dr. Agnes Jullien Research Director Director of Environmental, Development, Safety and Eco-Design Laboratory (EASE) Department of Development, Mobility and Environment Ifsttar Centre de Nantes Cedex- France “An excellent compilation of latest developments in the field of sustainable pavements. The chapter topics have been carefully chosen and are very well-organized with the intention of equipping the reader with the state-of-the-art knowledge on all aspects of pavement sustainability. Topics covered include pavement Life Cycle Analysis (LCA), pervious pavements, cool pavements, photocatalytic pavements, energy harvesting pavements, etc. which will all be of significant interest to students, researchers, and practitioners of pavement engineering. This book will no doubt serve as an excellent reference on the topic of sustainable pavements.” Dr. Wei-Hsing Huang Editor-in-Chief of International Journal of Pavement Research and Technology (IJPRT) and Professor of Civil Engineering National Central University Taiwan

A dozen papers from a December 1993 symposium in Dallas/Fort Worth, Texas. Among the topics are why the new proposed rheological properties of asphalt binders are required and how they compare to conventional properties, the development and use of the SHRP direct tension specification test, oxidatio