Few fields of research in the earth sciences have produced as much data and litera ture as the study of carbonate sediments and rocks. The past 25 years in particular, have seen a significant increase in studies concerning modern marine and fresh water carbonates. With the present worldwide interest in oceanographic research, marine carbonates have received the bulk of the attention, particularly with respect to shallow-water sediments. However, in terms of the variety of environ ments, compositions and modes of formation, non-marine carbonates probably encompass a wider spectrum than do marine types. Our purpose is to present a two-volume treatise on carbonate sediments and rocks, both marine and non-marine. We have confined ourselves to the discussion of modern (Holocene) environments, sediments and components, assuming that the compilation of these data will not only be relevant to those working with modern carbonates but will also serve as a necessary reference source for those interested in ancient analogs. The first volume, by MILLIMAN, deals almost exclu sively with marine environments, while the second volume, by MULLER and FORST NER, will concentrate on the non-marine carbonates.

and their identification obviates individual thermochemical studies on every genus. The stability relations among sedimentary carbonate minerals are now more or less well known. The common rock-forming minerals cal cite and dolomite are indeed stable phases in the pertinent systems. Most other carbonate minerals of similar composition which are known to occur in the younger sediments are metastable with respect to calcite, dolomite, and magnesite. This implies that the sedimentation of carbon ates is determined only in part by stability relations. Kinetic factors, which allow the formation of metastable minerals, appear to be more important. Although the diagenetic transformations leading to stable minerals take place by virtue of thermodynamic requirements, the reac tions themselves are triggered by kinetic factors as well. Some of the reactions leading from metastable to stable carbonate assemblages are susceptible to simulation in the laboratory; others (e. g. dolomitization) appear to be so slow that they can be studied only in analogous systems characterized by reasonable reaction rates. In all attempts to explain the possible mechanisms of such reactions, we must consider the crystal structures of the final products as well as of the starting materials. This is another viewpoint from which mineralogy is important to carbonate petrology, if we regard the crystal chemistry of minerals as a part of mineralogy. A certain parallelism with clay mineralogy suggests itself.

This book covers the more basic aspects of carbonate minerals and their interaction with aqueous solutions; modern marine carbonate formation and sediments; carbonate diagenesis (early marine, meteoric and burial); the global cycle of carbon and human intervention; and the role of sedimentary carbonates as indicators of stability and changes in the Earth's surface environment. The selected subjects are presented with sufficient background information to enable the non-specialist to understand the basic chemistry involved. Tested on classes taught by the authors, and approved by the students, this comprehensive volume will prove itself to be a valuable reference source to students, researchers and professionals in the fields of oceanography, geochemistry, petrology, environmental science and petroleum geology.

This textbook provides an overview of the origin and preservation of carbonate sedimentary rocks. The focus is on limestones and dolostones and the sediments from which they are derived. The approach is general and universal and draws heavily on fundamental discoveries, arresting interpretations, and keystone syntheses that have been developed over the last five decades. The book is designed as a teaching tool for upper level undergraduate classes, a fundamental reference for graduate and research students, and a scholarly source of information for practicing professionals whose expertise lies outside this specialty. The approach is rigorous, with every chapter being designed as a separate lecture on a specific topic that is encased within a larger scheme. The text is profusely illustrated with all colour diagrams and images of rocks, subsurface cores, thin sections, modern sediments, and underwater seascapes. Additional resources for this book can be found at: www.wiley.com/go/james/carbonaterocks

This textbook provides an overview of the origin and preservation of carbonate sedimentary rocks. The focus is on limestones and dolostones and the sediments from which they are derived. The approach is general and universal and draws heavily on fundamental discoveries, arresting interpretations, and keystone syntheses that have been developed over the last five decades. The book is designed as a teaching tool for upper level undergraduate classes, a fundamental reference for graduate and research students, and a scholarly source of information for practicing professionals whose expertise lies outside this specialty. The approach is rigorous, with every chapter being designed as a separate lecture on a specific topic that is encased within a larger scheme. The text is profusely illustrated with all colour diagrams and images of rocks, subsurface cores, thin sections, modern sediments, and underwater seascapes. Additional resources for this book can be found at: www.wiley.com/go/james/carbonaterocks

Hardcover plus Foldouts

Carbonate Sediments and Their Diagenesis