There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and do-decane which are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For the cycloalkanes, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multidimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real diesel, the inclusion of higher molecular weight components is needed in models and experimental investigations.

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. - Details thermochemical properties and "ab initio" calculations of elementary reaction rates - Details kinetic mechanisms of pyrolysis and combustion processes - Explains experimental data for improving reaction models and for kinetic mechanisms assessment - Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures - Describes pollutant formation in combustion systems - Solves and validates the kinetic mechanisms using numerical and statistical methods - Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces - Outlines large eddy simulation of turbulent reacting flows

The primary objectives of this work were to formulate, blend, and characterize a set of four ultra-low-sulfur diesel surrogate fuels in quantities sufficient to enable their study in single-cylinderengine and combustion-vessel experiments. The surrogate fuels feature increasing levels of compositional accuracy (i.e., increasing exactness in matching hydrocarbon structural characteristics) relative to the single target diesel fuel upon which the surrogate fuels are based. This approach was taken to assist in determining the minimum level of surrogate-fuel compositional accuracy that is required to adequately emulate the performance characteristics of the target fuel under different combustion modes. For each of the four surrogate fuels, an approximately 30-liter batch was blended, and a number of the physical and chemical properties were measured. Lastly, this publication documents the surrogate fuel creation process and the results of the property measurements.

This book is intended to serve as a compendium on the state-of-the-art research in the field of biofuels. The book includes chapters on different aspects of biofuels from renowned international experts in the field. The book looks at current research on all aspects of biofuels from raw materials to production techniques. It also includes chapters on analysis of performance of biofuels, particularly biodiesel, in engines. The book incorporates case studies that provide insights into the performance of biofuels in applications such as automotive engines and diesel generators. The contents of the book will be useful to graduate students and researchers working on all aspects of biofuels. The book will also be of use to professionals and policymakers interested in biofuels.

This book presents the proceedings of the International Conference on Aerospace System Science and Engineering (ICASSE 2019), held in Toronto, Canada, on July 30–August 1, 2019, and jointly organized by the University of Toronto Institute for Aerospace Studies (UTIAS) and the Shanghai Jiao Tong University School of Aeronautics and Astronautics. ICASSE 2019 provided a forum that brought together experts on aeronautics and astronautics to share new ideas and findings. These proceedings present high-quality contributions in the areas of aerospace system science and engineering, including topics such as trans-space vehicle system design and integration, air vehicle systems, space vehicle systems, near-space vehicle systems, aerospace robotics and unmanned systems, communication, navigation and surveillance, aerodynamics and aircraft design, dynamics and control, aerospace propulsion, avionics systems, optoelectronic systems, and air traffic management.

Combustion Engineering, Third Edition introduces the analysis, design, and building of combustion energy systems. It discusses current global energy, climate, and air pollution challenges and considers the increasing importance of renewable energy sources, such as biomass fuels. Mathematical methods are presented, along with qualitative descriptions of their use, which are supported by numerous tables with practical data and formulae, worked examples, chapter-end problems, and updated references. The new edition features new and updated sections on solid biofuels, spark-ignition, compression-ignition, soot and black carbon formation, and current energy policies. Features include: Builds a strong foundation for design and engineering of combustion systems. Provides fully updated coverage of alternative and renewable fuel topics throughout the text. Features new and updated sections on solid biofuels, spark-ignition, compression-ignition, soot and black carbon formation, and current energy policies. Includes updated data and formulae, worked examples, and additional chapter-end problems. Includes a Solutions Manual and figures slides for adopting instructors. This text is intended for undergraduate and first-year graduate mechanical engineering students taking introductory courses in combustion. Practicing heating engineers, utility engineers, and engineers consulting in energy and environmental areas will find this book a useful reference.