This thesis sheds new light on the worldwide first electrical manipulation of a single nuclear spin. Over the last four decades, the size of a bit, the smallest logical unit in a computer, has decreased by more than two orders of magnitude and will soon reach a limit where quantum phenomena become important. Inspired by the power of quantum mechanics, researchers have already identified pure quantum systems, having, analog to a classical bit, two controllable and readable states. In this regard, the inherent spin of electrons or nuclei with its two eigenstates, spin up and spin down, is a promising candidate. Using expertise in the field of single-molecule magnets, the author developed a molecular transistor, which allows quantum information to be written onto a single nuclear spin by means of an electric field only, and, in addition, enables the electronic read-out of this quantum state. This novel approach opens a path to addressing and manipulating individual nuclear spins within a very confined space (a single molecule), at high speed. Thus, the author was able to show that single molecule magnets are promising candidates for quantum information processing, which is triggering a new field of research towards molecular quantum electronics.

The application of quantum physics to the information theory turns out to be full of promises for our information society. Aware of this potential, groups of scientists all around the world have this common goal to create the quantum version of the computer. The first step of this ambitious project is the realization of the basic block that encodes the quantum information, the qubit. Among all existing qubits, spin based devices are very attractive since they reveal electrical read-out and coherent manipulation. Beyond this, the more isolated a system is, the longer its quantum behaviour remains, making of the nuclear spin a serious candidate for exhibiting long coherence time and consequently high numbers of quantum operation.In this context I worked on a molecular spin transistor consisting of a TbPc2 singlemolecule magnet coupled to electrodes (source, drain and gate) and a microwave antenna. This setup enabled us to read-out electrically both the electronic and the nuclear spin states and to coherently manipulate the nuclear spin of the Terbium ion. I focus during my Ph.D. on the study of the spins dynamic and mainly the 3/2 nuclear spin under the influence of a microwave pulse. The first step was to measure the energy difference between these statesleading in a second time to the coherent manipulation of the three nuclear spin transitions using only a microwave electric field. To further characterize the decoherence processes that break the phase of the nuclear spin states, I performed Ramsey and Hahn-echo measurements. These preliminary results show that we were in presence of three qubits with figure of merit higher than two thousands, thus meeting the expectations aroused by the use of a nuclearspin as the basic block of quantum information.More than demonstrating the qubit dynamic, I demonstrated that a nuclear spin embedded in the molecular magnet transistor is a four quantum states system that can be fully controlled, a qudit. Theoretical proposal demonstrated that quantum information processing such as quantum gates and algorithms could be implemented using a 3/2 spin. I focused on a research algorithm which is a succession of an Hadamard gate, that creates a coherent superposition of all the nuclear spin sates, and an unitary evolution, that amplified the amplitude of a desired state. It allows a quadratic speed-up to find an element in an unordered list compared to classical algorithm. During my Ph.D., I demonstrated the experimental proof of feasibility of this Grover like algorithm applied to a multi-levels system. The first step was to experimentally create coherent superposition of 2, 3 and 4 states. Then I measured coherent oscillations inbetween a 3 state superposition and a selected state which is the signature of the research algorithm implementation.In summary, this Ph.D. exposed the first quantum search algorithm on a single-molecule magnet based qudit. These results combined to the great versatility of molecular magnet holds a lot of promises for the next challenge: building up a scalable molecular based quantum computer.

The book allows the reader to have a basic understanding of the structure and properties of nanoscale materials routinely used in nanotechnology-based research and industries. To add, the book describes the operation of nanoscale transistors and the processes used to fabricate the devices. Additionally, it presents research involving the use of carbon nanotubes, graphene, and molecules to create non-silicon based electronic devices. It aims to provide an understanding of the operation of the most frequently used fabrication and characterization procedures, such as scanning electron microscopy, atomic force microscopy, etch, e-beam lithography, and photolithography. Provides explanations of the common techniques used in nanofabrication. Focuses on nanomaterials that are almost exclusively used in academic research and incorporated in consumer materials, such as carbon nanotubes, graphene, metal nanoparticles, quantum dots, and conductive polymers. Each chapter begins with a list of key objectives describing major content covered. Includes end-of-chapter questions to reinforce chapter content.

This is the first comprehensive book on the engineering of diamond optical devices. Written by 39 experts in the field, it gives readers an up-to-date review of the properties of optical quality synthetic diamond (single crystal and nanodiamond) and the nascent field of diamond optical device engineering. Application areas covered in detail in this book include quantum information processing, high performance lasers and light sources, and bioimaging. It provides scientists, engineers and physicists with a valuable and practical resource for the design and development of diamond-based optical devices.

During the last few years cavity-optomechanics has emerged as a new field of research. This highly interdisciplinary field studies the interaction between micro and nano mechanical systems and light. Possible applications range from novel high-bandwidth mechanical sensing devices through the generation of squeezed optical or mechanical states to even tests of quantum theory itself. This is one of the first books in this relatively young field. It is aimed at scientists, engineers and students who want to obtain a concise introduction to the state of the art in the field of cavity optomechanics. It is valuable to researchers in nano science, quantum optics, quantum information, gravitational wave detection and other cutting edge fields. Possible applications include biological sensing, frequency comb applications, silicon photonics etc. The technical content will be accessible to those who have familiarity with basic undergraduate physics.

The book presents invited reviews and original short notes with recent results obtained in fabrication study and application of nanostructures, which are promising for new generations of electronic and optoelectronic devices.Recent developments in nanotechnology, nanoelectronics, spintronics, nanophotonics, nanosensorics and nanobiology are presented.

The book presents invited reviews and original short notes with recent results obtained in fabrication study and application of nanostructures, which are promising for new generations of electronic and optoelectronic devices.