The Reactions of Small Molecules with Transition Metal Complexes
Title | The Reactions of Small Molecules with Transition Metal Complexes PDF eBook |
Author | D. Kelly |
Publisher | |
Pages | |
Release | 1990 |
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Reactions of Transition Metal Complexes with Small Molecules
Title | Reactions of Transition Metal Complexes with Small Molecules PDF eBook |
Author | Margaret Norgett |
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Pages | |
Release | 1968 |
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Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells
Title | Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells PDF eBook |
Author | Kenneth Kam-Wing Lo |
Publisher | Academic Press |
Pages | 408 |
Release | 2016-12-30 |
Genre | Science |
ISBN | 012803887X |
Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells Foscuses on the fundamentals and their potential therapeutic and diagnostic applications Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents
Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation
Title | Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation PDF eBook |
Author | Veeranna Yempally |
Publisher | |
Pages | |
Release | 2012 |
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The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Activation of Small Molecules
Title | Activation of Small Molecules PDF eBook |
Author | William B. Tolman |
Publisher | John Wiley & Sons |
Pages | 382 |
Release | 2006-12-13 |
Genre | Science |
ISBN | 3527609377 |
The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
The Activation of Small Molecules by Some Transition Metal Complexes
Title | The Activation of Small Molecules by Some Transition Metal Complexes PDF eBook |
Author | Philip Vasil Yaneff |
Publisher | |
Pages | |
Release | 1976 |
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ISBN |
Activation of Small Molecules by Transition Metal Complexes Via Computational Methods
Title | Activation of Small Molecules by Transition Metal Complexes Via Computational Methods PDF eBook |
Author | Ahmad Najafian |
Publisher | |
Pages | 113 |
Release | 2020 |
Genre | Activation (Chemistry) |
ISBN |