1. 1. Greenhouse gas emissions and climate change . . . . . . . . . . . . . . 3 1. 1. 1. Emissions and concentrations of greenhouse gases 3 1. 1. 2. Impact of increasing greenhouse gases concentration 4 1. 2. Options to reduce carbon dioxide emissions 5 1. 2. 1. Carbon dioxide removal 8 1. 3. Scope of the thesis 10 1. 4. Outline of the thesis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 1. 4. 1. General evaluation method. . . . . . . . . . . . . . . . . . . . . . . 12 1. 4. 2. Some notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 II. Simulation and optimization of carbon dioxide recovery from the flue gases of a coal-fired power plant using amines 14 Abstract 19 2. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 2. 2. The chemical absorption process. . . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 1. General process description. . . . . . . . . . . . . . . . . . . . . . . 22 2. 2. 2. Types of absorbent 23 2. 2. 3. Effects of flue gas contaminants 24 2. 3. Simulation of the scrubber in ASPEN PLUS . . . . . . . . . . . . . . . . . 25 2. 3. 1. ASPEN PLUS for flow sheet simulation 26 2. 3. 2. Simulation of the performance for the base-case design . . 26 the scrubber . . . . . . . . . . . . . . . . . . . . . . 29 2. 3. 3. Optimization of 2. 3. 4. Design and results 32 2. 3. 5. Discussion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 2. 4. Integration of the scrubber in the power plant 35 2. 4. 1. Power loss caused by steam extraction 36 2. 4. 2. Power saved by avoiding preheating boiler feed water . . . 38 2. 4. 3. Power consumption by the carbon dioxide scrubber . . . . . 38 2. 4. 4. Power consumption for carbon dioxide compression . . . . . 38 2. 4. 5. Calculation of plant efficiency losses " . . . . . . . . . . . . . . 39 2. 5.

Coal-Fired Generation is a concise, up-to-date and readable guide providing an introduction to this traditional power generation technology. It includes detailed descriptions of coal fired generation systems, demystifies the coal fired technology functions in practice as well as exploring the economic and environmental risk factors. Engineers, managers, policymakers and those involved in planning and delivering energy resources will find this reference a valuable guide, to help establish a reliable power supply address social and economic objectives. - Focuses on the evolution of the traditional coal-fired generation - Evaluates the economic and environmental viability of the system with concise diagrams and accessible explanations

Coal will continue to provide a major portion of energy requirements in the United States for at least the next several decades. It is imperative that accurate information describing the amount, location, and quality of the coal resources and reserves be available to fulfill energy needs. It is also important that the United States extract its coal resources efficiently, safely, and in an environmentally responsible manner. A renewed focus on federal support for coal-related research, coordinated across agencies and with the active participation of the states and industrial sector, is a critical element for each of these requirements. Coal focuses on the research and development needs and priorities in the areas of coal resource and reserve assessments, coal mining and processing, transportation of coal and coal products, and coal utilization.

Coal accounts for approximately one quarter of world energy consumption and of the coal produced worldwide approximately 65% is shipped to electricity producers and 33% to industrial consumers, with most of the remainder going to consumers in the residential and commercial sectors. The total share of total world energy consumption by coal is expected to increase to almost 30% in 2035. This book describes the challenges and steps by which electricity is produced form coal and deals with the challenges for removing the environmental objections to the use of coal in future power plants. New technologies are described that could virtually eliminate the sulfur, nitrogen, and mercury pollutants that are released when coal is burned for electricity generation. In addition, technologies for the capture greenhouse gases emitted from coal-fired power plants are described and the means of preventing such emissions from contributing to global warming concerns. Written by one of the world’s leading energy experts, this volume is a must-have for any engineer, scientist, or student working in this field, providing a valuable reference and guide in a quickly changing field.

Dry Syngas Purification Processes for Coal Gasification Systems illustrates the promising development status of dry syngas purification for various power generation systems based on coal gasification. The core advantages of dry syngas purification, methodologies for impurity measurement, sorbents development, and evaluation of process performance are described in-depth, and from a practical perspective that is based on current research and development. Reviewing key findings from process integration, the book encompasses scale-up strategies from pilot processes to achieve dry syngas processing for new build plants. The book provides researchers and engineers with practical information to realize dry syngas purification processes for each context. - Delivers pathways to realize dry syngas purification processes customized to specific power plant contexts - Provides analytical tools to facilitate plant operators in examining and interpreting the relevant impurities of coal gasification and gas treatment processes - Illustrates rational strategies for developing capable and durable dry removal sorbent for syngas impurities - Describes process design and integration through key engineering evaluation - Describes scale-up strategies of dry syngas processing for their deployment in new plants - Provides prospects on the development of future coal energy conversion system adopting dry syngas purification processes