The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (radical, cationic, anionic) * Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies * Graft and block copolymers * High-temperature polymers * Inorganic and organometallic polymers * Conducting polymers * Ring-opening polymer ization * In vivo and in vitro polymerization Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. A thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, Principles of Polymerization, Fourth Edition provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas.

Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.

Three-Dimensional Microfabrication Using Two-Photon Polymerization, Second Edition offers a comprehensive guide to TPP microfabrication and a unified description of TPP microfabrication across disciplines. It offers in-depth discussion and analysis of all aspects of TPP, including the necessary background, pros and cons of TPP microfabrication, material selection, equipment, processes and characterization. Current and future applications are covered, along with case studies that illustrate the book's concepts. This new edition includes updated chapters on metrology, synthesis and the characterization of photoinitiators used in TPP, negative- and positive-tone photoresists, and nonlinear optical characterization of polymers. This is an important resource that will be useful for scientists involved in microfabrication, generation of micro- and nano-patterns and micromachining. - Discusses the major types of nanomaterials used in the agriculture and forestry sectors, exploring how their properties make them effective for specific applications - Explores the design, fabrication, characterization and applications of nanomaterials for new Agri-products - Offers an overview of regulatory aspects regarding the use of nanomaterials for agriculture and forestry

Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.

Plasma Polymerization aims to bridge the conceptual gap between the academic and practical approaches to plasma polymerization and highlights the significance of plasma polymerization in materials science and technology. The major topics covered are gas-phase kinetics, ionization of gases, fundamentals of polymerization, mechanism of polymer formation in plasma, competitive aspects of polymer formation and ablation, mechanism of polymer deposition, operational factors of plasma polymerization, and electrical properties of plasma polymers. This book is comprised of 11 chapters and begins with a brief overview of plasma polymerization and its growing importance for the formation of entirely new kinds of materials. The discussion then shifts to a comparison between plasma-state polymerization and plasma-induced polymerization, between plasma polymerization and graft polymerization, and between plasma polymerization and radiation polymerization. The reader is also introduced to fundamental aspects of gas-phase reactions, paying particular attention to the classical kinetic theory of gas, as well as the mechanisms of formation of polymeric materials in plasma, competitive ablation and polymer formation in plasma, and polymer deposition in plasma polymerization. The operational parameters of plasma polymerization are described and a chapter devoted to the electrical properties of plasma-polymerized thin organic films concludes the book. This book will be of interest to students and researchers of material science.

This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.

This book has been written in a concise manner to include all fundamental aspects of polymer science including recent inventions in polymerisation's and polymers. It covers atom transfer radical polymerisation (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide-mediated polymerisation (NMP), click chemistry as well as stereopolymerisation, ring opening metathesis polymerisation (ROMP), group transfer polymerisation (GTP), plasma polymerisation etc. in addition to the usual polymerisation mechanisms such as radical, ionic and step polymerisations. It also includes new developments of polymer science which are considered as hot topics of functional polymers like smart or intelligent polymers, light emitting polymers, conducting polymers, magnetic polymers, optically active and/or chiral polymers, liquid crystalline polymers, self-healing polymers, polymers for biomedical applications, dendrimers and/or dendritic polymers and polymer nanocomposites etc.