Antennas are used across a wide range of frequencies in the electromagnetic spectrum to concentrate wave energy into electronic circuits. The principles that govern the operation of conventional radio-frequency antennas can be extended to much higher frequencies and be applied to produce nano-metallic (i.e. plasmonic) antennas that act as "receivers" and "transmitters" for visible light. These traits make them excellent candidates for light trapping in solar cells, light concentration in sub-wavelength photodetectors, or even localized heating for cancer therapies. The unique optical properties of metals at visible frequencies make it difficult to apply traditional antenna design rules. Using full-field electromagnetic simulations and analytical antenna models, we developed new design rules for producing optical antennas with a desired set of optical properties. We then applied these design rules to create antennas that resonantly enhance absorption on thin silicon detectors as well as enhance emission of cathodoluminescence (CL). Through spatial and spectral mapping of both photocurrent and CL we clearly show the fundamental and higher-order resonant modes of these antennas. With CL we are also able to map the spatial distribution of these resonant modes with nanometer resolution. In addition to these specific demonstrated applications, the results of this work enable optical engineers to more easily design a myriad of plasmonic devices that employ optical antenna structures, including nanoscale photodetectors, light sources, sensors, and modulators.

Antennas are used across a wide range of frequencies in the electromagnetic spectrum to concentrate wave energy into electronic circuits. The principles that govern the operation of conventional radio-frequency antennas can be extended to much higher frequencies and be applied to produce nano-metallic (i.e. plasmonic) antennas that act as "receivers" and "transmitters" for visible light. These traits make them excellent candidates for light trapping in solar cells, light concentration in sub-wavelength photodetectors, or even localized heating for cancer therapies. The unique optical properties of metals at visible frequencies make it difficult to apply traditional antenna design rules. Using full-field electromagnetic simulations and analytical antenna models, we developed new design rules for producing optical antennas with a desired set of optical properties. We then applied these design rules to create antennas that resonantly enhance absorption on thin silicon detectors as well as enhance emission of cathodoluminescence (CL). Through spatial and spectral mapping of both photocurrent and CL we clearly show the fundamental and higher-order resonant modes of these antennas. With CL we are also able to map the spatial distribution of these resonant modes with nanometer resolution. In addition to these specific demonstrated applications, the results of this work enable optical engineers to more easily design a myriad of plasmonic devices that employ optical antenna structures, including nanoscale photodetectors, light sources, sensors, and modulators.

This consistent and systematic review of recent advances in optical antenna theory and practice brings together leading experts in the fields of electrical engineering, nano-optics and nano-photonics, physical chemistry and nanofabrication. Fundamental concepts and functionalities relevant to optical antennas are explained, together with key principles for optical antenna modelling, design and characterisation. Recognising the tremendous potential of this technology, practical applications are also outlined. Presenting a clear translation of the concepts of radio antenna design, near-field optics and field-enhanced spectroscopy into optical antennas, this interdisciplinary book is an indispensable resource for researchers and graduate students in engineering, optics and photonics, physics and chemistry.

The interaction of light with matter is a central topic in both fundamental science and applied technology. At the heart of this interaction lies the absorption or emission of a photon by an electronic transition in for example an atom, molecule or semiconductor. Because such quantum emitters are generally much smaller than the wavelength of light, they interact slowly and omnidirectionally with light, limiting their absorption and emission. At radio frequencies similar issues were encountered and addressed long ago. Electrical circuits radiate little because they are much smaller than the corresponding wavelength. To enable wireless communication, they are connected to antennas that have dimensions in the order of the wavelength. These antennas are designed to effectively convert electrical signals into radiation and vice versa. The same concept can be applied in optics. The central idea of this thesis is that the interaction of a quantum emitter with light can be improved by near-field coupling it to the resonant plasmon modes of a metal nano-particle, which then acts as an optical antenna. In this way, excitation and emission rates can be enhanced, and the angular, polarization, and spectral dependence controlled. Chapter 1 of this thesis outlines these concepts and introduces optical antennas for single emitters. The experimental demonstration of optical antennas requires the near-field coupling of a single emitter to a resonant optical antenna. We fabricated optical monopole antennas on scanning probes, so that they can be precisely positioned near single fluorescent molecules. In this way we directly mapped the changes in the excitation and emission of a single quantum emitter as it is scanned near the antenna. Chapter 2 presents the results for the excitation part of the interaction. The enhanced excitation field at the antenna is highly confined (within 25 nm); the emitter only interacts with the antenna mode over this short distance. The antenna resonances were probed directly in the near-field and show that the antenna is indeed an optical analog of a monopole antenna. The experiments in Chapter 3 demonstrate how the antenna controls the emission. If the emitter is placed at the right position and if the antenna is tuned to resonance, the angular emission of the coupled system is determined by the antenna mode, regardless of the orientation of the emitter. In Chapter 4, we exploit that fact. We demonstrate, theoretically and experimentally, that the radiation from a single emitter coupled to a multi-element optical Yagi-Uda antenna is highly directed. We show that by reciprocity such a high directivity both enhances the excitation field and the collection efficiency. An intuitive way to understand optical antennas is as cavities for surface plasmon polaritons. In chapter 5, I present an extended description of the interaction of dipolar emitters with radiation through nano-rod antenna modes, by treating the antenna as a cavity. The results demonstrate how the properties of the antenna modes evolve from macroscopic perfectly conducting antennas to nanoscale plasmonic antennas, and highlight the similarities and differences between optical and conventional antennas. The results presented in this thesis show that optical antennas provide a new way to link single emitters to light. By designing the antenna the absorption and emission properties of the emitter can be tailored. More generally, optical antennas enhance and control light-matter interaction on the nano-scale, making them promising tools for applications in topics as diverse as high resolution near-field scanning optical microscopy, non-linear optics and spectroscopy, and photovoltaic devices.

This volume presents a considerable number of interrelated contributions dealing with the new scientific ability to shape and control matter and electromagnetic fields on a sub-wavelength scale. The topics range from the fundamental ones, such as photonic metamateriials, plasmonics and sub-wavelength resolution to the more applicative, such as detection of single molecules, tomography on a micro-chip, fluorescence spectroscopy of biological systems, coherent control of biomolecules, biosensing of single proteins, terahertz spectroscopy of nanoparticles, rare earth ion-doped nanoparticles, random lasing, and nanocoax array architecture. The various subjects bridge over the disciplines of physics, biology and chemistry, making this volume of interest to people working in these fields. The emphasis is on the principles behind each technique and on examining the full potential of each technique. The contributions that appear in this volume were presented at a NATO Advanced Study Institute that was held in Erice, Italy, 3-18 July, 2011. The pedagogical aspect of the Institute is reflected in the topics presented in this volume.

The linear and nonlinear resonance behaviour of optical antennas (metallic nanostructures showing resonance behaviour at optical frequencies) made of gold and aluminum using electron-beam lithography is investigated. Specifically, it is of interest how the emission behaviour is changed by the coupling of two antenna arms via a small gap. Experimental techniques applied include dark-field spectroscopy and two-photon luminescence.