Physical Chemistry: An Advanced Treatise, Volume IV: Molecular Properties provides the aspects of the properties of single molecules and physical methods available for their determination. This book discusses linear polyatomic molecules, quantum-mechanical theory of vibrations, spectra of organic molecules, production and detection of free radicals, and force constants and molecular structure. The Hund's coupling cases for diatomic molecules, methods of measuring dipole moments, NMR spectra, and ESR spectra of organic species are also elaborated. This publication likewise covers the applications of the Mössbauer effect, electric deflection experiments, and effects of intramolecular motions on diffraction patterns. This volume is intended for graduate and physical chemistry students interested in molecular properties.

Textbook on modern theoretical chemistry suitable for advanced undergraduate or graduate students.

This book is an introduction to statistical mechanics, intended for advanced undergraduate or beginning graduate students.

Physical Chemistry: An Advanced Treatise, Volume I: Thermodynamics deals with the applications of thermodynamics to mixtures, fluids, and solid systems at high pressures and temperatures, critical phenomena, practical handling of coupled gas equilibriums, and matter in electric, magnetic, and gravitational fields. This book begins with a survey of basic laws, followed by discussions on questions of stability, irreversible processes, surfaces, the third law, and a short introduction to Caratheodory's axiomatic foundation. The zeroth law of thermodynamics, gaseous mixtures, internal equilibrium in solids, thermodynamic properties of the mixture, and theory of linear differential forms are also elaborated. This publication presents a comprehensive treatment of physical chemistry for advanced students and researchers.