Phase Diagrams and Thermodynamic Modeling of Solutions

Phase Diagrams and Thermodynamic Modeling of Solutions
Title Phase Diagrams and Thermodynamic Modeling of Solutions PDF eBook
Author Arthur D. Pelton
Publisher Academic Press
Pages 404
Release 2018-09-19
Genre Science
ISBN 0128016698

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Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. - Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics - Provides an in-depth understanding of phase equilibria - Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling - Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more

Phase Diagrams

Phase Diagrams
Title Phase Diagrams PDF eBook
Author Flake C. Campbell
Publisher ASM International
Pages 471
Release 2012-01-01
Genre Science
ISBN 1615039864

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This well-written text is for non-metallurgists and anyone seeking a quick refresher on an essential tool of modern metallurgy. The basic principles, construction, interpretation, and use of alloy phase diagrams are clearly described with ample illustrations for all important liquid and solid reactions. Gas-metal reactions, important in metals processing and in-service corrosion, also are discussed. Get the basics on how phase diagrams help predict and interpret the changes in the structure of alloys.

Phase Diagrams for Geoscientists

Phase Diagrams for Geoscientists
Title Phase Diagrams for Geoscientists PDF eBook
Author Tibor Gasparik
Publisher Springer Science & Business Media
Pages 467
Release 2013-08-13
Genre Science
ISBN 1461457769

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The book summarizes the results of the experimental studies of phase relations in the chemical systems relevant to Earth, carried out by the author in a time period of over 20 years between 1979 and 2001. It is based on 1000 piston-cylinder experiments at pressures up to 4 GPa, and close to 700 experiments carried out with a multi-anvil apparatus at pressures up to 24 GPA. This is the largest published collection of calculated phase diagrams for the chemical systems relevant to Earth. This is also the first time that the phase relations at the relatively low pressures of the lithospheric mantle, mainly applicable to the experimental thermobarometry of metamorphic rocks and mantle xenoliths, are seamlessly integrated with the phase relations of the sublithospheric upper mantle and the uppermost lower mantle, primarily applicable to inclusions in diamond and schocked meteorites. "Tibor Gasparik has devoted his career to determining the high-pressure, high-temperature phase relations of the geologically important Sodium-Calcium-Magnesium-Aluminium-Silicon (NCMAS) oxide system. This book is his opus magnum, summarizing more than 1700 experiments in over 120 figures. ... I have found Phase Diagrams for Geoscientists to be a useful first port-of-call for finding the P-T stability fields ... and I can recommend the book as a reference for geoscientists requiring an overview of the stable phase assemblages in the top 700 km of the Earth." (David Dobson, Geological Magazine, Vol. 142 (2), 2005)

Phase Diagrams and Heterogeneous Equilibria

Phase Diagrams and Heterogeneous Equilibria
Title Phase Diagrams and Heterogeneous Equilibria PDF eBook
Author Bruno Predel
Publisher Springer Science & Business Media
Pages 357
Release 2013-03-09
Genre Science
ISBN 366209276X

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This advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.

Phase Equilibria, Phase Diagrams and Phase Transformations

Phase Equilibria, Phase Diagrams and Phase Transformations
Title Phase Equilibria, Phase Diagrams and Phase Transformations PDF eBook
Author Mats Hillert
Publisher Cambridge University Press
Pages 525
Release 2007-11-22
Genre Technology & Engineering
ISBN 1139465864

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Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.

Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys

Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys
Title Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys PDF eBook
Author Nikolay A. Belov
Publisher Elsevier
Pages 428
Release 2005-07-01
Genre Technology & Engineering
ISBN 0080456960

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Despite decades of extensive research and application, commercial aluminum alloys are still poorly understood in terms of the phase composition and phase transformations occurring during solidification, cooling, and heating. Multicomponent Phase Diagrams: Applications for Commercial Aluminum Alloys aims to apply multi-component phase diagrams to commercial aluminum alloys, and give a comprehensive coverage of available and assessed phase diagrams for aluminum-based alloy systems of different dimensionality. - Features data on non-equilibrium phase diagrams, which can rarely be obtained from other publications - Extensive coverage of all groups of commercially important alloys and materials

Methods for Phase Diagram Determination

Methods for Phase Diagram Determination
Title Methods for Phase Diagram Determination PDF eBook
Author Ji-Cheng Zhao
Publisher Elsevier
Pages 522
Release 2011-05-05
Genre Technology & Engineering
ISBN 0080549969

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Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides.* Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies* A must-read for experimental measurements of phase diagrams