Containing illustrations, worked examples, graphs and tables, this book deals with periodic precipitation (also known as Liesegang Ring formation) in terms of mathematical models and their logical consequences, and is entirely concerned with microcomputer analysis and software development. Three distinctive periodic precipitation mechanisms are included: binary diffusion-reaction; solubility modulation, and competitive particle growth. The book provides didactic illustrations of a valuable investigational procedure, in the form of hypothetical experimentation by microcomputer. The development of appropriate software is described and the resulting programs are available separately on disk. The software (for IBM compatible microcomputers; 5 1/4 and 3 1/2 inch disks available) will be sold separately by, The Carnation Press, PO Box 101, State College, PA 16804, USA.

This book offers a survey of the historic development of selected areas of chemistry and chemical physics, discussing in detail the European, American and Russian approaches to the development of chemistry. Other key topics include the kinetics and non-linear thermodynamics of chemical reactions and mathematical modeling, which have found new applications in the theory of dynamical systems. The first observations of the periodicity of chemical reactions were lost in the mist of time. In the second half of the 19th century, the phenomenon of chemical periodicity was studied in relation to electrochemistry, solutions and colloids. Discovered in the late 19th century, Liesegang rings are still enigmatic and remain attractive for researchers. However, the discovery of the Belousov–Zhabotinsky reaction marked the successful culmination of the efforts to find a true chemical oscillatory reaction. The book investigates chemical phenomena that were neglected in the past, but have been rediscovered, placing them into a new conceptual framework. For example, it notes that William Bray, who discovered the first oscillatory homogeneous reaction in 1921, was influenced by the first bio-mathematicians who predicted chemical oscillations in homogeneous systems.

Out-of-Equilibrium (Supra)molecular Systems and Materials A must-have resource that covers everything from out-of-equilibrium chemical systems to active materials Out-of-Equilibrium (Supra)molecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use molecular and supramolecular bonds in various out-of-equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative chemical systems that adapt their structures in space and time when fueled by an external source of energy. The contributors also examine molecules, nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores living supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical networks and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of out-of-equilibrium self-assemblies to molecular machines and active materials Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium (Supra)molecular Systems and Materials is an indispensable resource written by top scientists in the field.