During the last three decades, it has become increasingly clear that atmospheric modelling and remote sounding of the atmosphere from space, to name just two important application areas, are affected by non-equilibrium processes which have not been incorporated into traditional radiative transfer calculations. These processes, dubbed “non-LTE”, are therefore the subject of growing interest among scholars and researchers dealing with the upper atmosphere. This important book provides the first comprehensive and “global” description of non-LTE infrared emissions in the atmosphere of the Earth and other planets, starting with the theoretical foundations and progressing to the most important applications. Besides giving an introduction to this complex subject, it is a guide to the state-of-the-art in incorporating non-LTE processes into radiative transfer algorithms and computer models of the atmosphere. Numerous examples are presented of the application of these methods to (a) atmospheric remote sensing, (b) atmospheric energy budget (cooling and heating rate) calculations, and (c) atmospheres other than the Earth's.

Ch. 1. Introduction and overview. 1.1. General introduction. 1.2. Basic properties of the Earth's atmosphere. 1.3. What is LTE? 1.4. Non-LTE situations. 1.5. The importance of non-LTE. 1.6. Some historical background. 1.7. Non-LTE models. 1.8. Experimental studies of non-LTE. 1.9. Non-LTE in planetary atmospheres. 1.10. References and further reading -- ch. 2. Molecular spectra. 2.1. Introduction. 2.2. Energy levels in diatomic molecules. 2.3. Energy levels in polyatomic molecules. 2.4. Transitions and spectral bands. 2.5. Properties of individual vibration-rotation lines. 2.6. Interactions between energy levels. 2.7. References and further reading -- ch. 3. Basic atmospheric radiative transfer. 3.1. Introduction. 3.2. Properties of radiation. 3.3. The radiative transfer equation. 3.4. The formal solution of the radiative transfer equation. 3.5. Thermodynamic equilibrium and local thermodynamic equilibrium. 3.6. The source function in non-LTE. 3.7. Non-LTE situations. 3.8. References and further reading -- ch. 4. Solutions to the radiative transfer equation in LTE. 4.1. Introduction. 4.2. Integration of the radiative transfer equation over height. 4.3. Integration of the radiative transfer equation over frequency. 4.4. Integration of the radiative transfer equation over solid angle. 4.5. References and further reading -- ch. 5. Solutions to the radiative transfer equation in non-LTE. 5.1. Introduction. 5.2. Simple solutions for radiative transfer under non-LTE. 5.3. The full solution of the radiative transfer equation in non-LTE. 5.4. Integration of the RTE in non-LTE. 5.5. Intercomparison of non-LTE codes. 5.6. Parameterizations of the non-LTE cooling rate. 5.7. The Curtis matrix method. 5.8. References and further reading -- ch. 6. Non-LTE modelling of the Earth's atmosphere I: CO2. 6.1. Introduction. 6.2. Useful approximations. 6.3. Carbon dioxide, CO2. 6.4. References and further reading -- ch. 7. Non-LTE modelling of the Earth's atmosphere II: Other infrared emitters. 7.1. Introduction. 7.2. Carbon monoxide, CO. 7.3. Ozone, O3. 7.4. Water vapour, H2O. 7.5. Methane, CH4. 7.6. Nitric oxide, NO. 7.7. Nitrogen dioxide, NO2. 7.8. Nitrous oxide, N2O. 7.9. Nitric acid, HNO3. 7.10. Hydroxyl radical, OH. 7.11. Molecular oxygen atmospheric infrared bands. 7.12. Hydrogen chloride, HC1, and hydrogen fluoride, HF. 7.13. NO+. 7.14. Atomic Oxygen, O (3P), at 63[symbol]m. 7.15. References and further reading -- ch. 8. Remote sensing of the non-LTE atmosphere. 8.1. Introduction. 8.2. The analysis of emission measurements. 8.3. Observations of carbon dioxide in emission. 8.4. Observations of ozone in emission. 8.5. Observations of water vapour in emission. 8.6. Observations of carbon monoxide in emission. 8.7. Observations of nitric oxide in emission. 8.8. Observations of other infrared emissions. 8.9. Rotational non-LTE. 8.10. Absorption measurements. 8.11. Simulated limb emission spectra at high resolution. 8.12. Simulated Nadir emission spectra at high resolution. 8.13. Non-LTE retrieval schemes. 8.14. References and further reading -- ch. 9. Cooling and heating rates. 9.1. Introduction. 9.2. CO2 15 f[symbol]m cooling. 9.3. O3 9.6[symbol]xm cooling. 9.4. H2O 6.3[symbol]m cooling. 9.5. NO 5.3[symbol]m cooling. 9.6. O(3Pi) 63[symbol]m cooling. 9.7. Summary of cooling rates. 9.8. CO2 solar heating. 9.9. References and further reading -- ch. 10. Non-LTE in planetary atmospheres. 10.1. Introduction. 10.2. The terrestrial planets: Mars and Venus. 10.3. A non-LTE model for the Martian and Venusian atmospheres. 10.4. Mars. 10.5. Venus. 10.6. Outer planets. 10.7. Titan. 10.8. Comets. 10.9. References and further reading.

This volume reviews all aspects of Mars atmospheric science from the surface to space, and from now and into the past.

The most authoritative synthesis of the quantitative spectroscopic analysis of stellar atmospheres This book provides an in-depth and self-contained treatment of the latest advances achieved in quantitative spectroscopic analyses of the observable outer layers of stars and similar objects. Written by two leading researchers in the field, it presents a comprehensive account of both the physical foundations and numerical methods of such analyses. The book is ideal for astronomers who want to acquire deeper insight into the physical foundations of the theory of stellar atmospheres, or who want to learn about modern computational techniques for treating radiative transfer in non-equilibrium situations. It can also serve as a rigorous yet accessible introduction to the discipline for graduate students. Provides a comprehensive, up-to-date account of the field Covers computational methods as well as the underlying physics Serves as an ideal reference book for researchers and a rigorous yet accessible textbook for graduate students An online illustration package is available to professors at press.princeton.edu

Radiative Processes in Astrophysics: This clear, straightforward, and fundamental introduction is designed to present-from a physicist's point of view-radiation processes and their applications to astrophysical phenomena and space science. It covers such topics as radiative transfer theory, relativistic covariance and kinematics, bremsstrahlung radiation, synchrotron radiation, Compton scattering, some plasma effects, and radiative transitions in atoms. Discussion begins with first principles, physically motivating and deriving all results rather than merely presenting finished formulae. However, a reasonably good physics background (introductory quantum mechanics, intermediate electromagnetic theory, special relativity, and some statistical mechanics) is required. Much of this prerequisite material is provided by brief reviews, making the book a self-contained reference for workers in the field as well as the ideal text for senior or first-year graduate students of astronomy, astrophysics, and related physics courses. Radiative Processes in Astrophysics also contains about 75 problems, with solutions, illustrating applications of the material and methods for calculating results. This important and integral section emphasizes physical intuition by presenting important results that are used throughout the main text; it is here that most of the practical astrophysical applications become apparent.

Humanity has long been fascinated by the planet Mars. Was its climate ever conducive to life? What is the atmosphere like today and why did it change so dramatically over time? Eleven spacecraft have successfully flown to Mars since the Viking mission of the 1970s and early 1980s. These orbiters, landers and rovers have generated vast amounts of data that now span a Martian decade (roughly eighteen years). This new volume brings together the many new ideas about the atmosphere and climate system that have emerged, including the complex interplay of the volatile and dust cycles, the atmosphere-surface interactions that connect them over time, and the diversity of the planet's environment and its complex history. Including tutorials and explanations of complicated ideas, students, researchers and non-specialists alike are able to use this resource to gain a thorough and up-to-date understanding of this most Earth-like of planetary neighbours.

Encyclopedia of Atmospheric Sciences, Second Edition, Six Volume Set is an authoritative resource covering all aspects of atmospheric sciences, including both theory and applications. With more than 320 articles and 1,600 figures and photographs, this revised version of the award-winning first edition offers comprehensive coverage of this important field. The six volumes in this set contain broad-ranging articles on topics such as atmospheric chemistry, biogeochemical cycles, boundary layers, clouds, general circulation, global change, mesoscale meteorology, ozone, radar, satellite remote sensing, and weather prediction. The Encyclopedia is an ideal resource for academia, government, and industry in the fields of atmospheric, ocean, and environmental sciences. It is written at a level that allows undergraduate students to understand the material, while providing active researchers with the latest information in the field. Covers all aspects of atmospheric sciences—including both theory and applications Presents more than 320 articles and more than 1,600 figures and photographs Broad-ranging articles include topics such as atmospheric chemistry, biogeochemical cycles, boundary layers, clouds, general circulation, global change, mesoscale meteorology, ozone, radar, satellite remote sensing, and weather prediction An ideal resource for academia, government, and industry in the fields of atmospheric, ocean, and environmental sciences