This comprehensive book presents a detailed account of research and recent developments in the field of green energetic materials, including pyrotechnics, explosives and propellants. This area is attracting increasing interest in the community as it undergoes a transition from using traditional processes, to more environmentally-friendly procedures. The book covers the entire line of research from the initial theoretical modelling and design of new materials, to the development of sustainable manufacturing processes. It also addresses materials that have already reached the production line, as well as considering future developments in this evolving field.

Advanced energetic materialsâ€"explosive fill and propellantsâ€"are a critical technology for national security. While several new promising concepts and formulations have emerged in recent years, the Department of Defense is concerned about the nation's ability to maintain and improve the knowledge base in this area. To assist in addressing these concerns, two offices within DOD asked the NRC to investigate and assess the scope and health of the U.S. R&D efforts in energetic materials. This report provides that assessment. It presents several findings about the current R&D effort and recommendations aimed at improving U.S. capabilities in developing new energetic materials technology. This study reviewed U.S. research and development in advanced energetics being conducted by DoD, the DoE national laboratories, industries, and academia, from a list provided by the sponsors. It also: (a) reviewed papers and technology assessments of non-U.S. work in advanced energetics, assessed important parameters, such as validity, viability, and the likelihood that each of these materials can be produced in quantity; (b) identified barriers to scale-up and production, and suggested technical approaches for addressing potential problems; and (c) suggested specific opportunities, strategies, and priorities for government sponsorship of technologies and manufacturing process development.

Nitrogen-Rich Energetic Materials Provides in-depth and comprehensive knowledge on both the chemistry and practical applications of nitrogen-rich energetic materials Energetic materials, a class of material with high amounts of stored chemical energy, include explosives, pyrotechnics, and propellants. Initially used for military applications, nitrogen-rich energetic materials have become important in the civil engineering and aerospace sectors, they are increasingly used in commercial mining and construction as well as in rocket propulsion. Making these nitrogen-rich energetic materials safer, more powerful, and more cost-effective requires a thorough understanding of their chemistry, physics, synthesis, properties, and applications. Nitrogen-Rich Energetic Materials presents a detailed summary of the development of nitrogen-rich energetic materials over the past decade and provides up-to-date knowledge on their applications in various areas of advanced engineering. Edited by a panel of international experts in the field, this book examines the chemistry of pentazoles, fused ring and laser ignitable nitrogen-rich compounds, polynitrogen and tetrazole-based energetic compounds, and more. The text also introduces applications of nitrogen-rich energetic materials in energetic polymers and metal-organic frameworks, as pyrotechnics materials for light and smoke, and in oxadiazoles from precursor molecules. This authoritative volume: Presents in-depth chapters written by leading experts in each sub-field covered Offers a systematic introduction to new and emerging applications of nitrogen-rich energetic materials such as in computational chemistry Discusses recent advances in nitrate ester chemistry with focus on propellant applications Discusses green and eco-friendly approaches to nitrogen-rich compounds Nitrogen-Rich Energetic Materials is an important resource for researchers, academics, and industry professionals across fields, including explosives specialists, pyrotechnicians, materials scientists, polymer chemists, laser specialists, physical chemists, environmental chemists, chemical engineers, and safety officers.

This is the first comprehensive overview of this topic. It serves as a single source for information about the properties, preparation, and uses of all relevant primary explosives. The first chapter provides background such as the basics of initiation and differences between requirements on primary explosives used in detonators and igniters. The authors then clarify the influence of physical characteristics on explosive properties, focusing on those properties required for primary explosives. Furthermore, the issue of sensitivity is discussed. All the chapters on particular groups of primary explosives are structured in the same way, including introduction, physical and chemical properties, explosive properties, preparation and documented use. The authors thoroughly verified all data and information. A unique feature of this book are original microscopic images of some explosives.