The phases of matter between isotropic liquid and well-ordered crystalline solid phases are known as liquid crystal phases. The molecular architecture, which includes structure, polarity, and topology, influences the liquid crystal phases formed by mesomorphic materials. The most common and widely studied liquid crystal phase is the nematic phase formed by rod-like molecules. The molecules in this phase have only orientational order, which means they prefer to align along a single axis while their positions are random addition they do not have polarity. Flexible bent-shape molecules where an odd number of methylene groups connect two rigid arms exhibit twist-bend nematic (N_TB)" phase. In the N_TB phase, the molecules have a heliconical structure with a 10 nm range pich. Rigid achiral bent-shape materials typically show polar and chiral smectic structures because tilted and polar packing makes each smectic layer chiral. Lastly, rod-shaped molecules with large (about 10 Debye) dipole moments form the ferroelectric nematic phase predicted by Max Born in 1916 but experimentally observed only a few years ago. In my dissertation, I will describe various studies of the nanostructure of different flexibly bent-core liquid crystal materials exhibiting the N_TB Phase, structures of ferroelectric and antiferroelectric smectic phases of rigid bent-shape materials, and multiple ferroelectric nematic phases of a highly polar rod-shape substance.

Bent-Shaped Liquid Crystals: Structures and Physical Properties provides insight into the latest developments in the research on liquid crystals formed by bent-shaped mesogens. After a historical introduction, the expert authors discuss different kinds of mesophase structures formed by bent-shaped molecules. This book devotes the majority of its pages to physical properties such as polar switching, optics and non-linear optics, and behavior in restricted geometries. However, as chemistry is often highly relevant to the emergence of new phases, particularly with reflection symmetry breaking, it also involves a broad spectrum of interesting chemistry viewpoints.

Fluorinated Liquid Crystals: Design of Soft Nanostructures and Increased Complexity of Self-Assembly by Perfluorinated Segments, by Carsten Tschierske Liquid Crystalline Crown Ethers, by Martin Kaller and Sabine Laschat Star-Shaped Mesogens – Hekates: The Most Basic Star Structure with Three Branches, by Matthias Lehmann DNA-Based Soft Phases, by Tommaso Bellini, Roberto Cerbino and Giuliano Zanchetta Polar and Apolar Columnar Phases Made of Bent-Core Mesogens, by N. Vaupotič, D. Pociecha and E. Gorecka Spontaneous Achiral Symmetry Breaking in Liquid Crystalline Phases, by H. Takezoe Nanoparticles in Liquid Crystals and Liquid Crystalline Nanoparticles, by Oana Stamatoiu, Javad Mirzaei, Xiang Feng and Torsten Hegmann Stimuli-Responsive Photoluminescent Liquid Crystals, by Shogo Yamane, Kana Tanabe, Yoshimitsu Sagara and Takashi Kato

Bent-Shaped Liquid Crystals: Structures and Physical Properties provides insight into the latest developments in the research on liquid crystals formed by bent-shaped mesogens. After a historical introduction, the expert authors discuss different kinds of mesophase structures formed by bent-shaped molecules. This book devotes the majority of its pages to physical properties such as polar switching, optics and non-linear optics, and behavior in restricted geometries. However, as chemistry is often highly relevant to the emergence of new phases, particularly with reflection symmetry breaking, it also involves a broad spectrum of interesting chemistry viewpoints.

This book focuses on the exciting topic of nanoscience with liquid crystals: from self-organized nanostructures to applications. The elegant self-organized liquid crystalline nanostructures, the synergetic characteristics of liquid crystals and nanoparticles, liquid crystalline nanomaterials, synthesis of nanomaterials using liquid crystals as templates, nanoconfinement and nanoparticles of liquid crystals are covered and discussed, and the prospect of fabricating functional materials is highlighted. Contributions, collecting the scattered literature of the field from leading and active players, are compiled to make the book a reference book. Readers will find the book useful and of benefit both as summaries for works in this field and as tutorials and explanations of concepts for those just entering the field. Additionally, the book helps to stimulate future developments.

This book is a printed edition of the Special Issue "Nanomaterials in Liquid Crystals" that was published in Nanomaterials

LCs are self-organized anisotropic fluids that are thermodynamically located between the isotropic liquid and the crystalline phase, exhibiting the fluidity of liquids as well as the long-range lattice order that can only be found in crystalline solids. The addition of nanomaterials to a LC material produces a composite or colloidal dispersion and results into a revolutionary change in their applications. This book will discuss the remarkable performances of nano-particle aided liquid crystals in metamaterials, photonics, functionalized polymer fibres, sensing, and medical diagnostics.