The Nagra/PSI Chemical Thermodynamic Data Base 01/01 is an encyclopedia of thermodynamic data recommended for environmental studies. The data base focuses on elements commonly found as major solutes in natural waters, and on actinides and fission products relevant for radioactive waste disposal projects. It is the official chemical thermodynamic data base used in Swiss radioactive waste disposal projects. The detailed discussion of every number recommended in this encyclopedia is the result of a multi man-year project of the Paul Scherrer Institut (PSI), a Swiss National Lab. The five authors of this work have many years of experience in research, data base development and the application of thermodynamic data in environmental studies. The data included for many elements are based on their reviews of the basic literature. The data base also includes additional data selected by the authors from recommendations of other experts in ground- water geochemistry and of the international data base project of the Nuclear Energy Agency (NEA).This report is indispensable for every scientist working in the field of environmental studies as the comprehensive source of information on the quality of the thermodynamic data governing particular problems in environmental geochemistry, especially those concerned with the fate of hazardous substances. This enables graduate students, researchers and consultants, as well as regulators and reviewers of scientific papers to assess the scientific basis of environmental modeling studies. The encyclopedia can be used as a stand-alone source of knowledge but amplereferences are provided for readers who wish to go beyond the level of discussion in the book. An electronic version of the data base and a data base management program is available for download at our homepage (http://les.web.psi.ch/TDBbook.htm).

This book provides incentives for further development of sustainable fuel cycles through a novel and interdisciplinary approach to an Earth science-related topic. The main focus is on geochemical concepts in immobilizing, isolating or neutralizing waste derived from energy production and consumption. The book also addresses the issue of using some types of energy-derived waste as alternative raw materials. Moreover, it highlights research on how certain wastes can be used for energy production, an increasingly important aspect of modern integrated waste management strategies. The main objectives are to: (a) identify the most serious environmental problems related to various types of power generation and associated waste accumulation; (b) present strategies, based on natural analogue materials, for the immobilization of toxic and radioactive waste components through mineralogical barriers; (c) discuss modern procedures for reuse of waste or certain waste components; and (d) review the importance of geochemical modelling in describing and predicting the interaction between waste and the environment.

Solubility is fundamental to most areas of chemistry and is one of the most basic of thermodynamic properties. It underlies most industrial processes. Bringing together the latest developments and ideas, Developments and Applications in Solubility covers many varied and disparate topics. The book is a collection of work from leading experts in their fields and covers the theory of solubility, modelling and simulation, industrial applications and new data and recent developments relating to solubility. Of particular interest are sections on: experimental, calculated and predicted solubilities; solubility phenomena in 'green' quaternary mixtures involving ionic liquids; molecular simulation approaches to solubility; solubility impurities in cryogenic liquids and carbon dioxide in chemical processes. The book is a definitive and comprehensive reference to what is new in solubility and is ideal for researcher scientists, industrialists and academics

This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography. * Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.