A response to increasingly stringent regulation of pollution and toxicity levels in industrial waste discharge, Micellar Enhanced Ultrafiltration: Fundamentals & Applications offers the most complete book available on the benefits and use of micellar-enhanced ultrafiltration (MEUF) to achieve continuous removal of organic and inorganic pollutants. An Unparalleled Book That Addresses Both Academic and Industrial Points of View Several membrane-based techniques, such as microfiltration, ultrafiltration, nanofiltration, and reverse osmosis, are currently used in a wide range of applications throughout the textile, pulp and paper, sugar, chemical, pharmaceutical, biomedical, biotechnological, and food industries. However, although reverse osmosis is an effective means of removing contaminants, this book explains why MEUF is a better substitute, as it less expensive, less energy-intensive, and more efficient and practical for a wider range of applications. Topics covered include: Effects of pollution in water and its consequences Various treatment processes and membrane technologies Fundamentals of ultrafiltration Outline of various membrane modules and modeling approaches Principles of colloid chemistry Theories of micelle formation Stability and dynamics of micelles Phenomena of counterion binding Solubilization of organic pollutants Selection criteria for surfactants Various flux enhancement techniques Recovery of precious metals This book conveys how, with proper selection of surfactant and membrane, MEUF can be used to efficiently remove almost all metal ions (heavy metals, lanthanides, radioactive materials, etc.) with reasonably high efficiency and throughput. It also details the MEUF process for removal of inorganic (cations, anions, and their mixture) and organic pollutants. The authors explain how the economy of the overall process makes recovery and reuse of surfactants essential, and they address various influencing factors on the increase in throughput and the resulting operating problems. Elaborating on technologies involving precipitation and other methods, they also illustrate additional potential applications for MEUF technology.

Complete with bibliographic citations and illustrations, this volume focuses on novel techniques and reviews established methods for surfactant-based separation processes that can be widely applied in industry. Describes new extraction techniques, and introduces micellar-enhanced ultrafiltration and admicellar chromatography, discusses protein extraction using reverse micelles, surfactant-enhanced carbon regeneration, and demonstrates new methods of turning waste streams containing dilute concentrations of valuable materials into product streams and examines such traditional surfactant-based methods as froth flotation and foam fractionation.

This book is a record of a symposium, "Ultrafiltration Membranes and Applications," which was held at the l78th National Meeting of the American Chemical Society in Washington, D.C., September 11-13, 1979. In organlzlng these sessions, I hoped to provide a comprehensive survey of the current state of ultrafiltration theory, the most recent advances in membrane technology, and a thorough treatment of existing applications and future directions for ultrafiltration. For me, the symposium was an outstanding success. It was a truly international forum with stimulating presentations and an enthusiastic audience. I hope that some of this spirit has spilled over into this volume, which is intended to reach a much wider audience. I am indebted to the Division of Colloid and Surface Chemistry of the American Chemical Society for their sponsorship. ANTHONY R. COOPER Palo Alto, California }larch, 1980 vii CONTENTS PART I. FUNDMfENTALS Fifteen Years of Ultrafiltration: Problems and Future Promises of an Adolescent Technology . . 1 Alan S. Michaels Production, Specification, and Some Transport Characteristics of Cellulose Acetate Ultrafil tration Membranes for Aqueous Feed Solutions 21 S. Sourirajan, Takeshi Matsuura Fu-Hung Hsieh and Gary R. Gildert Chemical and Morphological Effects of Solute Diffusion Through Block Copolymer Membranes 45 Yatin B. Thakore, Dien-Feng Shieh and Donald J. Lyman Practical Aspects in the Development of a Polymer Matrix for Ultrafiltration. 57 Israel Cabasso Permeability Parameters of a Novel Polyamide Membrane. ... - ...

Separation and purification processes play a critical role in biorefineries and their optimal selection, design and operation to maximise product yields and improve overall process efficiency. Separations and purifications are necessary for upstream processes as well as in maximising and improving product recovery in downstream processes. These processes account for a significant fraction of the total capital and operating costs and also are highly energy intensive. Consequently, a better understanding of separation and purification processes, current and possible alternative and novel advanced methods is essential for achieving the overall techno-economic feasibility and commercial success of sustainable biorefineries. This book presents a comprehensive overview focused specifically on the present state, future challenges and opportunities for separation and purification methods and technologies in biorefineries. Topics covered include: Equilibrium Separations: Distillation, liquid-liquid extraction and supercritical fluid extraction. Affinity-Based Separations: Adsorption, ion exchange, and simulated moving bed technologies. Membrane Based Separations: Microfiltration, ultrafiltration and diafiltration, nanofiltration, membrane pervaporation, and membrane distillation. Solid-liquid Separations: Conventional filtration and solid-liquid extraction. Hybrid/Integrated Reaction-Separation Systems: Membrane bioreactors, extractive fermentation, reactive distillation and reactive absorption. For each of these processes, the fundamental principles and design aspects are presented, followed by a detailed discussion and specific examples of applications in biorefineries. Each chapter also considers the market needs, industrial challenges, future opportunities, and economic importance of the separation and purification methods. The book concludes with a series of detailed case studies including cellulosic bioethanol production, extraction of algae oil from microalgae, and production of biopolymers. Separation and Purification Technologies in Biorefineries is an essential resource for scientists and engineers, as well as researchers and academics working in the broader conventional and emerging bio-based products industry, including biomaterials, biochemicals, biofuels and bioenergy.

Soon after its publication in 1987, the first edition of Ultrafiltration Handbook became recognized as the leading handbook on ultrafiltration technology. Reviews in professional journals praised it as an authoritative and substantive information resource on this technology. Now a completely, updated and expanded edition is available under the titl

This book is based on the proceedings of the conference "The role of surfactants in new and emerging technology". It examines the position of surfactants in the new growth areas, and describes the needs for surfactant research to facilitate advances in those areas.

The impending crisis posed by water stress and poor sanitation represents one of greatest human challenges for the 21st century, and membrane technology has emerged as a serious contender to confront the crisis. Yet, whilst there are countless texts on wastewater treatment and on membrane technologies, none address the boron problem and separation processes for boron elimination. Boron Separation Processes fills this gap and provides a unique and single source that highlights the growing and competitive importance of these processes. For the first time, the reader is able to see in one reference work the state-of-the-art research in this rapidly growing field. The book focuses on four main areas: - Effect of boron on humans and plants - Separation of boron by ion exchange and adsorption processes - Separation of boron by membrane processes - Simulation and optimization studies for boron separation - Provides in one source a state-of-the-art overview of this compelling area - Reviews the environmental impact of boron before introducing emerging boron separation processes - Includes simulation and optimization studies for boron separation processes - Describes boron separation processes applicable to specific sources, such as seawater, geothermal water and wastewater