MFI zeolite characterized by uniform pore size, adjustable acidity, and high-temperature resistance has a broad application prospect in catalytic reactions. However, controlling the product distribution of zeolite as a catalyst is still confronting great challenges and applications. It is considered as an effective way to control the product distribution by developing and improving new zeolites to modulate their shape selective effect. In recent years, researchers have achieved remarkable successes in investigating the shape selective modulation of zeolites on catalytic reaction and molecular diffusion. The microporous channels of MFI zeolite are the main places for the entry and exit of reactants or product molecules. This review provides the research progress of the shape-selective modulation of MFI zeolite channels and its influence on a series of catalytic performances in recent years. The shape-selective modulation of microporous channels of zeolite, encapsulation of micropores to metals, catalysis of mesoporous zeolite, and the distribution of framework Al were all systematically discussed. The development of advanced catalysts still faces great challenges and potential applications. Finally, we discussed the problems to be addressed urgently in the field of zeolite catalysts in the future.

This two-volume work contains over 140 papers which, together, reflect the current status of zeolite science and technology encompassing high and low silica zeolites, pillared clays, molecular sieves, microporous metallosilicates, crystalline silica polymorphs, crystalline microporous aluminophosphates and their isomorphically substituted forms.The five plenary invited lectures summarize current knowledge and address a number of topical areas such as the enumeration of theoretically possible frameworks, the use of sophisticated physical methods to unravel and characterise new molecular sieve materials, the potential of molecular sieves as catalysts for chemical intermediate and commodity synthesis and conversion, the role of zeolites in fluid catalytic cracking, and new zeolitic materials.Specific aspects of zeolite science are highlighted in the ten keynote lectures of which three are on synthesis and modification, one on new materials, one on characterization, two on structure and theory, one on metals in zeolites, and two on catalytic topics. All the contributions in this book reflect the high quality of research being carried out throughout the zeolite community.

Catalysis is the acceleration of a chemical reaction by a catalyst, a substance that notably affects the rate of a chemical reaction without itself being consumed or altered. Since 1948, Advances in Catalysis has filled the gap between the papers that report on and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area.* Provides a comprehensive review of all aspects of catalytic research * Contains in-depth, critical, state-of-the-art reports