Metal Interactions of Borane, Carborane and Thiaborane Clusters
Title | Metal Interactions of Borane, Carborane and Thiaborane Clusters PDF eBook |
Author | Kelley Jean Donaghy |
Publisher | |
Pages | 566 |
Release | 1996 |
Genre | |
ISBN |
Metal Interactions with Boron Clusters
Title | Metal Interactions with Boron Clusters PDF eBook |
Author | Russell N. Grimes |
Publisher | Springer Science & Business Media |
Pages | 335 |
Release | 2013-11-11 |
Genre | Science |
ISBN | 1489921540 |
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.
Metal Interactions with Boron Clusters
Title | Metal Interactions with Boron Clusters PDF eBook |
Author | Springer |
Publisher | |
Pages | 344 |
Release | 2014-01-15 |
Genre | |
ISBN | 9781489921550 |
Boranes and Metalloboranes
Title | Boranes and Metalloboranes PDF eBook |
Author | Catherine E. Housecroft |
Publisher | Ellis Horwood |
Pages | 174 |
Release | 1990 |
Genre | Borane |
ISBN |
Metal Interactions with Boron Clusters
Title | Metal Interactions with Boron Clusters PDF eBook |
Author | Grimes RN. |
Publisher | |
Pages | |
Release | 1982 |
Genre | |
ISBN |
Boranes and Metallaboranes
Title | Boranes and Metallaboranes PDF eBook |
Author | Catherine E. Housecroft |
Publisher | |
Pages | 180 |
Release | 1994 |
Genre | Science |
ISBN |
This concise introduction to boranes and metalloboranes employs an informal and straightforward style. The author establishes facts first, and rationalization and theories follow. Ideas of cluster bonding are presented, and the author surveys different approaches to the bonding in clusters, emphasizing the use of frontier molecule orbitals and the construction of clusters from fragments. The application of spectroscopic techniques to the elucidation of cluster structure is discussed, with an emphasis on multinuclear NMR spectroscopy. The second edition includes an update on structural data for boranes and their anions. Sections on spectroscopy and the reactivity of metalloboranes have been slightly expanded and references have been updated.
Electron Deficient Boron and Carbon Clusters
Title | Electron Deficient Boron and Carbon Clusters PDF eBook |
Author | George Andrew Olah |
Publisher | Wiley-Interscience |
Pages | 408 |
Release | 1991-02-07 |
Genre | Science |
ISBN |
Compares and contrasts the structure and chemistry of boron clusters, carbon clusters, and carboranes and their derivatives. Honors the pioneering works of William Lipscomb.