Collisions involving Rydberg atoms reveal detailed information on the state of a background medium and can be used as diagnostic probes of temperature and density distributions in a neutral or ionized gas. Spectroscopy of Rydberg atoms in highly excited states reveals the interaction of the Rydberg electron with core electrons, including relativistic effects, and can be used for precise determination of fundamental constants. The advent of ultracold trapping and cooling methods in the last three decades has ushered in a new paradigm in Rydberg physics control and manipulation. The concept of the Rydberg blockade, for instance, al- lows for precise control of long-range dipolar interaction between atoms, creation of correlated many-body wave functions, and realization of macroscopic quantum entanglement and quan- tum logic operations. The formation of a new class of Rydberg molecules arising from ground and Rydberg atom collisions can be used to manipulate electron-atom scattering phase shifts, form and manipulate molecules with enormous permanent electric dipole moments, study Ry- dberg chemistry at the ultracold, and realize macroscopic quantum polaronic systems. In this thesis, I will investigate charge transfer from covalent ground-Rydberg collisions to form heavy ion pair states. In another related study, I explore the formation of spin-mixed ultralong range Rydberg molecules, by accounting for spin-dependent relativistic fine and hyperfine interac- tion. Such studies help to not only explain experimental observations, but also point to how molecular reactions can be controlled using small electric or magnetic fields.

New phenomena have been observed by exciting ultracold ground-state atoms to Rydberg states. Starting with a dense sample of Rb atoms in a magneto-optical trap, we excite them to high Rydberg states (n = 30 - 90) with a single UV excitation pulse. Long-range molecular resonances with interatomic distances exceeding 104 a0 have been discovered. We have also observed the Rydberg excitation blockade, crucial for the implementation of quantum phase gates using neutral atoms. The physics behind these observations is attributed to the strong long-range van der Waals interactions among the Rydberg atoms. In addition, we have seen dipole (E1) forbidden but quadrupole (E2) allowed 5s → nd transitions, allowing us to determine the E2 oscillator strengths to these high Rydberg states. Our narrow-band UV pulsed laser system, with âˆ1⁄4100 MHz bandwidth, also allows us to measure the ratios of j-dependent oscillator strengths to the p and d Rydberg states.

The advent of laser cooling of atoms led to the discovery of ultra-cold matter, with temperatures below liquid Helium, which displays a variety of new physical phenomena. Physics of Ultra-Cold Matter gives an overview of this recent area of science, with a discussion of its main results and a description of its theoretical concepts and methods. Ultra-cold matter can be considered in three distinct phases: ultra-cold gas, Bose Einstein condensate, and Rydberg plasmas. This book gives an integrated view of this new area of science at the frontier between atomic physics, condensed matter, and plasma physics. It describes these three distinct phases while exploring the differences, as well as the sometimes unexpected similarities, of their respective theoretical methods. This book is an informative guide for researchers, and the benefits are a result from an integrated view of a very broad area of research, which is limited in previous books about this subject. The main unifying tool explored in this book is the wave kinetic theory based on Wigner functions. Other theoretical approaches, eventually more familiar to the reader, are also given for extension and comparison. The book considers laser cooling techniques, atom-atom interactions, and focuses on the elementary excitations and collective oscillations in atomic clouds, Bose-Einstein condensates, and Rydberg plasmas. Linear and nonlinear processes are considered, including Landau damping, soliton excitation and vortices. Atomic interferometers and quantum coherence are also included.

Arising from a workshop, this book surveys the physics of ultracold atoms and molecules taking into consideration the latest research on ultracold phenomena, such as Bose Einstein condensation and quantum computing. Several reputed authors provide an introduction to the field, covering recent experimental results on atom and molecule cooling as well as the theoretical treatment.

The aim of this book is to present review articles describing the latest theoretical and experimental developments in the field of cold atoms and molecules. Our hope is that this series will promote research by both highlighting recent breakthroughs and by outlining some of the most promising research directions in the field.

We investigate here the characteristics of energy resonant dipole-dipole interactions between Rydberg atoms in Magneto-Optical Trap. These resonant processes occur in a kinetic energy regime in which the atoms may be considered stationary over the time scale of the experiment. Coupled with the long range of the interactions considered, this leads to multi-atom interactions becoming non-negligible. A simple model is outlined to provide insight into the effects of these multi-atom interactions which lead to some interesting behaviors. Experiments which examine the broadening of the dipole-dipole resonances and observe the time dependence of the interaction signal are discussed. Examination of adiabatic character of population transfer caused by slewing across the resonance is discussed in another experiment, as is the scaling behavior of the resonance linewidths and on-resonant signal growth rates. We end by discussing an experiment which takes advantage of some of the characteristics of these interactions to measure the tensor polarizability of Rydberg states of Rb.