Volume 70 of Reviews in Mineralogy and Geochemistry represents an extensive review of the material presented by the invited speakers at a short course on Thermodynamics and Kinetics of Water-Rock Interaction held prior to the 19th annual V. M. Goldschmidt Conference in Davos, Switzerland (June 19-21, 2009). Contents: Thermodynamic Databases for Water-Rock Interaction Thermodynamics of Solid Solution-Aqueous Solution Systems Mineral Replacement Reactions Thermodynamic Concepts in Modeling Sorption at the Mineral-Water Interface Surface Complexation Modeling: Mineral Fluid Equilbria at the Molecular Scale The Link Between Mineral Dissolution/Precipitation Kinetics and Solution Chemistry Organics in Water-Rock Interactions Mineral Precipitation Kinetics Towards an Integrated Model of Weathering, Climate, and Biospheric Processes Approaches to Modeling Weathered Regolith Fluid-Rock Interaction: A Reactive Transport Approach Geochemical Modeling of Reaction Paths and Geochemical Reaction Networks

Geochemical kinetics as a topic is now of importance to a wide range of geochemists in academia, industry, and government, and all geochemists need a rudimentary knowledge of the field. This book summarizes the fundamentals of geochemical kinetics with examples drawn especially from mineral dissolution and precipitation. It also encompasses discussion of high temperature processes and global geochemical cycle modeling. Analysis of textures of rocks, sediments, and mineral surfaces are incorporated throughout and provide a sub-theme of the book.

The chemical interaction of water and rock is one of the most fascinating an d multifaceted process in geology. The composition of surface water and groundwater is largely controlled by the reaction of water with rocks and minerals. At elevated temperature, hydrothermal features, hydrothermal 0 re deposits and geothermal fields are associated with chemical effects of water-rock interaction. Surface outcrops of rocks from deeper levels in the crust, including exposures of lower crustal and mantle rocks, often display structures that formed by interaction of the rocks with a supercritical aqueous fluid at very high pT conditions. Understanding water-rock interaction is also of great importance to applied geology and geochemistry, particularly in areas such as geothermal energy, nuclear waste repositories and applied hydrogeology. The extremely wide-ranging research efforts on the universal water-rock interaction process is reflected in the wide diversity of themes presented at the regular International Symposia on Water-Rock Interaction (WRI). Because of the large and widespread interest in water-rock interaction, the European Union of Geosciences organized a special symposium on "water-rock interaction" at EUGI0, the biannual meeting in Strasbourg 1999 convened by the editors of this volume. In contrast to the regular WRI symposia addressed to the specialists, the EUG 10 "water-rock interaction" symposium brought the subject to a general platform This very successful symposium showed the way to the future of water-rock reaction research.

Water-rock interactions play an important role in nearly all physical and chemical processes operating on the Earth's surface and subsurface. This work contains the proceedings of the Eighth International Symposium on Water-Rock Interaction (WRI-8), held in Russia in 1995.

The interaction of the lithosphere and hydrosphere sets the boundary conditions for life, as water and the nutrients extracted from rocks are essential to all known life-forms. Water-rock interaction also affects the fate and transport of pollutants, mediates the long-term cycling of fluids and metals in the earth's crust, impacts the migration and