This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.

In this completely revised edition, all the chapters have been updated to reflect the current state of crystal growth kinetics. At the same time, fifteen percent additional content now allows coverage of computer-assisted modeling of second-order phase changes, microstructure development, novel data and images of coarsening mechanisms, with the most significant single addition being breakthrough results on spinodal decomposition -- published here for the first time in book form. The refined didactical approach with a streamlined presentation now allows readers to grasp the kinetic concepts even more easily, coherently introducing the field of kinetic processes, especially those involved in crystal growth, and explaining such phenomena as diffusion, nucleation, segregation and phase transitions at a level accessible to graduate students. In addition to the basic kinetic concepts, the textbook presents modern applications where these processes play a major role, including ion implantation, plasma deposition and rapid thermal processing.

Kinetic Processes in Gases and Plasmas provides a survey of studies on transport and chemical kinetic processes in high temperature gases and plasmas. The book is concerned with conditions produced by the interaction of an object with the atmosphere at hypersonic velocities. The text also provides a foundation for the flow field equations which include chemical reactions and other transport processes, and to present in some detail the microscopic considerations underlying these calculations. Chapters are devoted to the discussion of topics such as the molecular theory of transport equations; transport processes in ionized gases; and inelastic energy transfer processes and chemical kinetics. Aerospace engineers, physicists, chemists, and astrophysicists will find the book a good reference material.

The formation of solids is governed by kinetic processes, which are closely related to the macroscopic behaviour of the resulting materials. With the main focus on ease of understanding, the author begins with the basic processes at the atomic level to illustrate their connections to material properties. Diffusion processes during crystal growth and phase transformations are examined in detail. Since the underlying mathematics are very complex, approximation methods typically used in practice are the prime choice of approach. Apart from metals and alloys, the book places special emphasis on the growth of thin films and bulk crystals, which are the two main pillars of modern device and semiconductor technology. All the presented phenomena are tied back to the basic thermodynamic properties of the materials and to the underlying physical processes for clarity.

The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.

A classroom-tested textbook providing a fundamental understandingof basic kinetic processes in materials This textbook, reflecting the hands-on teaching experience of itsthree authors, evolved from Massachusetts Institute of Technology'sfirst-year graduate curriculum in the Department of MaterialsScience and Engineering. It discusses key topics collectivelyrepresenting the basic kinetic processes that cause changes in thesize, shape, composition, and atomistic structure of materials.Readers gain a deeper understanding of these kinetic processes andof the properties and applications of materials. Topics are introduced in a logical order, enabling students todevelop a solid foundation before advancing to more sophisticatedtopics. Kinetics of Materials begins with diffusion, offering adescription of the elementary manner in which atoms and moleculesmove around in solids and liquids. Next, the more complex motion ofdislocations and interfaces is addressed. Finally, still morecomplex kinetic phenomena, such as morphological evolution andphase transformations, are treated. Throughout the textbook, readers are instilled with an appreciationof the subject's analytic foundations and, in many cases, theapproximations commonly used in the field. The authors offer manyextensive derivations of important results to help illuminate theirorigins. While the principal focus is on kinetic phenomena incrystalline materials, select phenomena in noncrystalline materialsare also discussed. In many cases, the principles involved apply toall materials. Exercises with accompanying solutions are provided throughoutKinetics of Materials, enabling readers to put their newfoundknowledge into practice. In addition, bibliographies are offeredwith each chapter, helping readers to investigate specializedtopics in greater detail. Several appendices presenting importantbackground material are also included. With its unique range of topics, progressive structure, andextensive exercises, this classroom-tested textbook provides anenriching learning experience for first-year graduate students.

Kinetics of Chemical Processes details the concepts associated with the kinetic study of the chemical processes. The book is comprised of 10 chapters that present information relevant to applied research. The text first covers the elementary chemical kinetics of elementary steps, and then proceeds to discussing catalysis. The next chapter tackles simplified kinetics of sequences at the steady state. Chapter 5 deals with coupled sequences in reaction networks, while Chapter 6 talks about autocatalysis and inhibition. The seventh chapter describes the irreducible transport phenomena in chemical kinetics. The next two chapters discuss the correlations in homogenous kinetics and heterogeneous catalysis, respectively. The last chapter covers the analysis of reaction networks. The book will be of great use to students, researchers, and practitioners of scientific disciplines that deal with chemical reaction, particularly chemistry and chemical engineering.