Within the realm of the newly evolving discipline of environmental sciences, the stable-isotope methodology is being used to an ever-increasing extent, especially in the study of the water cycle and of paleo-climatology. This book introduces the rules of the game, by reviewing the natural variability of stable isotopes in the hydrosphere, describing the physico-chemical basis of isotope fractionation, and applying this knowledge to natural waters as they move through the hydrologic cycle from the ocean to the atmosphere, the biosphere and the lithosphere. There is a special focus on the processes at the surface-atmosphere and land-biosphere-atmosphere interfaces, since these are the sites of major changes in isotope composition. In response to the increasing awareness of our changing climate, a discussion on the global view of the changing water cycle, in the past and future, winds up the presentation./a

Environmental isotope and nuclear techniques provide unmatched insights into the processes governing the water cycle and its variability. This monograph presents state of the art applications and new developments of isotopes in hydrology, environmental disciplines and climate change studies. Coverage ranges from the assessment of groundwater resources in terms of recharge and flow regime to studies of the past and present global environmental and climate changes.

Environmental isotope and nuclear techniques provide unmatched insights into the processes governing the water cycle and its variability. This monograph presents state of the art applications and new developments of isotopes in hydrology, environmental disciplines and climate change studies. Coverage ranges from the assessment of groundwater resources in terms of recharge and flow regime to studies of the past and present global environmental and climate changes.

This volume is devoted to Earth surface environmental reconstructions and environmental changes that may be deciphered and modelled using stable isotopes along with mineralogical/chemical, sedimentological, palaeontological/biological and climatological methodologies. The book is divided into two sections, both using stable isotopes (see www.geolsoc.org.uk/SP507) in various samples and phases as the main research tool. The first section is devoted to studies focusing on the distribution of isotopes in precipitation, groundwater, lakes, rivers, springs, tap water, mine water and their relationship with terrestrial environments at regional to continental scale. In relation to this, the second section includes case studies from a range of continental settings, investigating cave deposits (stalagmites, bat guano), animal skeletons (dinosaurs, alligators, turtles, bivalves), present and past soils (palaeosols) and limestones. The sections focus on the interaction between the surficial water cycle and underground water storage with deposits acting as archives of short- to long-term climatic and environmental changes. Examples from the Early Cretaceous to present time come from Europe, Asia, Africa, North and South America.

Table of Contents Ch. 1 Introduction 1 Ch. 2 Basic concepts of nuclear physics 8 Ch. 3 Nuclear instrumentation techniques 25 Ch. 4 Environmental isotopes of water molecule and the applications 37 Ch. 5 Tritium, radio carbon and chlorine-36 dating 69 Ch. 6 Chlorofluorocarbons (C Cl[subscript 3]F, CFC - 11, and C Cl[subscript 2]F[subscript 2]) CFC-12 as dating tools and hydrologic tracers 93 Ch. 7 Artificial radioactive isotopes as tracers in surface, subsurface and ground water resources 99 Ch. 8 Application of sealed sources 122 Ch. 9 Sediment studies 149.

The 'detective' power of stable isotopes for processes that occurred in the past, and for elucidating mechanisms at the molecular level, has impressed researchers over the past 100 years, since the time when isotopes of elements were first discovered. While most are interested in the normalized abundance ratios of two isotopes of an element, further power was unleashed when researchers investigated the relationship of three or more isotopes of the same element, e.g. 16O, 17O, and 18O for oxygen. This Element focuses on the history of discovery of triple isotope effects, the conceptual framework behind these effects, and major lines of development in the past few years of triple oxygen isotope research.