Infrared Matrix Isolation Studies of Reactive Boron Intermediates from Pyrolytic Reactions of B2H6 with Lewis Bases
Title | Infrared Matrix Isolation Studies of Reactive Boron Intermediates from Pyrolytic Reactions of B2H6 with Lewis Bases PDF eBook |
Author | John David Carpenter |
Publisher | |
Pages | 404 |
Release | 1993 |
Genre | |
ISBN |
Dissertation Abstracts International
Title | Dissertation Abstracts International PDF eBook |
Author | |
Publisher | |
Pages | 788 |
Release | 1993 |
Genre | Dissertations, Academic |
ISBN |
Infrared Matrix Isolation Studies Of: I) Ion Pairing Effects: the M+BF4- Ion Pair and Its Chlorine-fluorine Analogs II) Boron Halide-Lewis Base Adducts III) the Cs+CF3 COF2- Ion Pair
Title | Infrared Matrix Isolation Studies Of: I) Ion Pairing Effects: the M+BF4- Ion Pair and Its Chlorine-fluorine Analogs II) Boron Halide-Lewis Base Adducts III) the Cs+CF3 COF2- Ion Pair PDF eBook |
Author | Robin Hunt |
Publisher | |
Pages | 294 |
Release | 1981 |
Genre | Boron compounds |
ISBN |
Matrix Isolation IR and EPR Studies of Reaction Intermediates: Lithium Atom Reactions with H2O, CH3OH, and NH3
Title | Matrix Isolation IR and EPR Studies of Reaction Intermediates: Lithium Atom Reactions with H2O, CH3OH, and NH3 PDF eBook |
Author | R. H. Hauge |
Publisher | |
Pages | 2 |
Release | 1978 |
Genre | |
ISBN |
Matrix-isolation Infrared Studies of Selected Oxidation Reactions of P, As and Sb Clusters
Title | Matrix-isolation Infrared Studies of Selected Oxidation Reactions of P, As and Sb Clusters PDF eBook |
Author | Matthew Clair McCluskey |
Publisher | |
Pages | 344 |
Release | 1990 |
Genre | Antimony |
ISBN |
Orbital Interaction Theory of Organic Chemistry
Title | Orbital Interaction Theory of Organic Chemistry PDF eBook |
Author | Arvi Rauk |
Publisher | John Wiley & Sons |
Pages | 360 |
Release | 2004-04-07 |
Genre | Science |
ISBN | 0471461849 |
A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive computer program that displays orbitals graphically and is available through a link to a Web site. Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced-level undergraduate and graduate students in organic chemistry. It is also a valuable working resource for professional chemists seeking guidance on interpreting the quantitative data produced by modern computational chemists.
Metal Interactions with Boron Clusters
Title | Metal Interactions with Boron Clusters PDF eBook |
Author | Russell N. Grimes |
Publisher | Springer Science & Business Media |
Pages | 335 |
Release | 2013-11-11 |
Genre | Science |
ISBN | 1489921540 |
Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.