The international Mont Terri rock laboratory in Switzerland plays a central role in the safety and construction of deep geological nuclear repositories in clay formations. The laboratory has developed and refined a range of new measurement and evaluation methods: it has e.g. advanced the determination of rock parameters using innovative borehole geophysics, improved the methodology for characterizing pore-water and microbial activity in claystones, and greatly improved our understanding of diffusion and retention processes of radionuclides in and through claystones. The methods and insights described in this compendium can also be applied to low-permeability rocks at various sites around the globe, and in other fields of application.

Clays are used as barriers for the isolation of landfills and contaminated sites. They are envisioned as long-term storage media for hazardous materials and radioactive wastes, and as seals in the case of geological CO2 sequestration or energy storage. Clay properties greatly influence the integrity, efficiency, and safety of these applications. Natural and Engineered Clay Barriers provides a clear view of the fundamental properties of clay materials and how these properties affect their engineering applications. This volume focuses on how the mass transfer properties (hydraulic permeability, gas fluxes, molecular diffusion, semi-permeable membrane properties), geochemical reactivity (adsorption, dissolution) and mechanical properties of clay barriers at the macroscale are influenced by phenomena that occur at clay mineral - water interfaces. - Examines clay properties from the molecular to the macroscopic scale - Addresses experimental and modeling issues - Authored by experts in the properties of clay barriers

This book is a comprehensive treatment of the elastic volumetric response of sandstones to variations in stress. The theory and data presented apply to the deformations that occur, for example, due to withdrawal of fluid from a reservoir, or due to the redistribution of stresses caused by the drilling of a borehole. Although the emphasis is on reservoir-type sandstones, results and methods discussed are also applicable to other porous rocks.Part One concerns the effect of stress on deformation and discusses porous rock compressibility coefficients. Elasticity theory is used to derive relationships between the porous rock compressibility coefficients, the porosity, and the mineral grain compressibility. Theoretical bounds on the compressibility coefficients are derived. The concept of effective stress coefficients is examined, as is the integrated form of the stress-strain relationships. Undrained compression and induced pore pressures are treated within the same general framework. Part One is concluded with a brief, elementary introduction to Biot's theory of poroelasticity. All the results in Part One are illustrated and verified with extensive references to published compressibility data.Part Two deals with the relationship between pore structure and compressibility, and presents methods that permit quantitative prediction of the compressibility coefficients. Two- and three-dimensional models of tubular pores, spheroidal pores, and crack-like "grain boundary" voids are analyzed. A critical review is made of various methods that have been proposed to relate the effective elastic moduli (bulk and shear) of a porous material to its pore structure. Methods for extracting pore aspect ratio distributions from stress-strain data or from acoustic measurements are presented, along with applications to actual sandstone data.Part Three is a brief summary of experimental techniques that are used to measure porous rock compressibilities in the laboratory.The information contained in this volume is of interest to petroleum engineers, specifically those involved with reservoir modeling, petroleum geologists, geotechnical engineers, hydrologists and geophysicists.

Volume 77 of Reviews in Mineralogy and Geochemistry focuses on important aspects of the geochemistry of geological CO2 sequestration. It is in large part an outgrowth of research conducted by members of the U.S. Department of Energy funded Energy Frontier Research Center (EFRC) known as the Center for Nanoscale Control of Geologic CO2 (NCGC). Eight out of the 15 chapters have been led by team members from the NCGC representing six of the eight partner institutions making up this center - Lawrence Berkeley National Laboratory (lead institution, D. DePaolo - PI), Oak Ridge National Laboratory, The Ohio State University, the University of California Davis, Pacific Northwest National Laboratory, and Washington University, St. Louis.

This Special Publication contains 43 scientific studies presented at the 5th conference on ‘Clays in natural and engineered barriers for radioactive waste confinement’ held in Montpellier, France in 2012. The conference and this resulting volume cover all the aspects of clay characterization and behaviour considered at various temporal and spatial scales relevant to the confinement of radionuclides in clay, from basic phenomenological process descriptions to the global understanding of performance and safety at repository and geological scales. Special emphasis has been given to the modelling of processes occurring at the mineralogical level within the clay barriers. The papers in this Special Publication consider research into argillaceous media under the following topic areas: large-scale geological characterization; clay-based concept/large-scale experiments; hydrodynamical modelling; geochemistry; geomechanics; mass transfer/gas transfer; mass transfer mechanisms. The collection of different topics presented in this Special Publication demonstrates the diversity of geological repository research.

The aim of the book is to provide an understanding of the current science underpinning Carbon Capture and Sequestration (CCS) and to provide students and interested researchers with sufficient background on the basics of Chemical Engineering, Material Science, and Geology that they can understand the current state of the art of the research in the field of CCS. In addition, the book provides a comprehensive discussion of the impact of CCS on the energy landscape, society, and climate as these topics govern the success of the science being done in this field.The book is aimed at undergraduate students, graduate students, scientists, and professionals who would like to gain a broad multidisciplinary view of the research that is being carried out to solve one of greatest challenges of our generation.