Impact of Accelerated Hydrothermal Aging on Structure and Performance of Cu-SSZ-13 SCR Catalysts

Impact of Accelerated Hydrothermal Aging on Structure and Performance of Cu-SSZ-13 SCR Catalysts
Title Impact of Accelerated Hydrothermal Aging on Structure and Performance of Cu-SSZ-13 SCR Catalysts PDF eBook
Author
Publisher
Pages
Release 2015
Genre
ISBN

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Atomic-level Insights Into the Hydrothermal Stability of CU/SSZ-13 SCR Catalysts for the Abatement of Diesel Vehicle Nox Emissions

Atomic-level Insights Into the Hydrothermal Stability of CU/SSZ-13 SCR Catalysts for the Abatement of Diesel Vehicle Nox Emissions
Title Atomic-level Insights Into the Hydrothermal Stability of CU/SSZ-13 SCR Catalysts for the Abatement of Diesel Vehicle Nox Emissions PDF eBook
Author James Song
Publisher
Pages
Release 2017
Genre
ISBN

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Road and Off-Road Vehicle Dynamics

Road and Off-Road Vehicle Dynamics
Title Road and Off-Road Vehicle Dynamics PDF eBook
Author Moustafa El-Gindy
Publisher Springer Nature
Pages 469
Release 2023-07-10
Genre Technology & Engineering
ISBN 3031362160

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This book introduces and provides a detailed understanding of on- and off-road vehicle dynamics. It discusses classical on-road tyre mechanics, including finite element tyre modelling and validation, using a combination of theoretical and experimental data sets. Chapters explore new computational techniques that describe terrain models and combined to develop better off-road vehicle models, and focus is placed on terrain characterization and modelling, using two popular modelling techniques, as well as performance characteristics of off-road vehicles - including rolling and driven combinations, traction, and steering. The effect of multi-pass and soil compaction on tyre performance is described as well. The book presents a unique neuro-tyre model for both on-road and off-road situations, capable of computing the steering, braking characteristics, and soil compaction. Road vehicle characteristics are described, including the stability and control, roll centre and roll axis, and rollover mechanics. The road vehicle braking performance is also described, including the brake components, choice of brake, and the transient load transfer. Finally, the dynamics and control of multi-wheel combat vehicles are presented and described extensively. The book is dedicated to undergraduate and graduate engineering students, in addition to researchers, and the automotive industry. As well as provide the readers with a better understanding of vehicle dynamics and soil mechanics. The book is also beneficial for automotive industries looking for a quick and reliable model to be implemented in their main software.

Selective Catalytic Reduction of NOx

Selective Catalytic Reduction of NOx
Title Selective Catalytic Reduction of NOx PDF eBook
Author Oliver Kröcher
Publisher MDPI
Pages 281
Release 2018-12-14
Genre Science
ISBN 3038973645

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This book is a printed edition of the Special Issue "Selective Catalytic Reduction of NOx" that was published in Catalysts

Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts

Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts
Title Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts PDF eBook
Author Isabella Nova
Publisher Springer Science & Business Media
Pages 715
Release 2014-03-14
Genre Science
ISBN 1489980717

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Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts presents a complete overview of the selective catalytic reduction of NOx by ammonia/urea. The book starts with an illustration of the technology in the framework of the current context (legislation, market, system configurations), covers the fundamental aspects of the SCR process (catalysts, chemistry, mechanism, kinetics) and analyzes its application to useful topics such as modeling of full scale monolith catalysts, control aspects, ammonia injections systems and integration with other devices for combined removal of pollutants.

Accelerated Thermal Aging of Iron-zeolite SCR Catalyst on an Engine Bench

Accelerated Thermal Aging of Iron-zeolite SCR Catalyst on an Engine Bench
Title Accelerated Thermal Aging of Iron-zeolite SCR Catalyst on an Engine Bench PDF eBook
Author Adam Lamar Foster
Publisher
Pages 173
Release 2008
Genre
ISBN

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Selective catalytic reduction (SCR) of NO[Subscript x] with urea/NH[Subscript 3] is a leading candidate to the impending more stringent emissions regulations for diesel engines. Currently, there is no consensus on the durability and the deactivation mechanisms associated with zeolite-based SCR catalysts, nor is there an established protocol for rapidly aging zeolite-based SCR catalysts that replicates the catalyst deactivation associated with field service. A 517 cc single-cylinder, naturally-aspirated direct injection (NA/DI) diesel engine is used to perform accelerated thermal aging on Fe-zeolite SCR catalysts. The engine is fitted with an exhaust aftertreatment system consisting of a DOC, a SCR catalyst and a DPF. Accelerated aging protocol established for the SCR catalyst utilizes high temperature exhaust gases during the active regeneration of the DPF. Accelerated aging is carried out at exhaust gas temperatures of 650, 750 and 850°C at the SCR inlet and at a gas hourly space velocity (GHSV) of approximately 40,000 h−1. The engine is maintained at 1500 rpm and supplemental fuel is injected upstream of the DOC to alter the temperature of the aftertreatment system. The aged Fe-zeolite SCR catalysts are evaluated for NO[Subscript x] performance in a bench-flow reactor and characterized by multiple surface characterization techniques for materials changes. The NO[Subscript x] performance of the front sections of the engine-aged catalysts is severely degraded. BET surface area measurements of the engine-aged catalyst indicate a severe reduction of catalyst surface area in the front sections of the catalysts aged at 750 and 850°C. However, the catalyst aged at 650°C has a catalyst surface area similar to that of a fresh catalyst; thereby ruling out reduction of catalyst surface area as the sole cause of the catalyst deactivation seen in the front sections of the engine-aged catalysts. The similar shape of the NO[Subscript x] conversion profiles observed with these catalyst sections even at different aging temperatures indicates some type of catalyst poisoning; however, the cause of catalyst degradation in these catalyst sections is not identified in this investigation. There is a good relationship between the NO[Subscript x] performance and catalyst aging temperature for the rear sections of the engine-aged catalysts - NO[Subscript x] performance decreases with increasing aging temperature. XRD patterns and NO oxidation experiments reveal evidence of zeolite dealumination in the engine-aged catalysts. BET surface area measurements show that catalyst surface area decreases with increasing aging temperature, which further supports the suggestion of zeolite dealumination as the cause of catalyst deactivation in the rear sections of the engine-aged catalysts. A comparison between the engine-aged and field-aged catalysts is conducted to assess the validity of the implemented accelerated thermal aging protocol in replicating the aging conditions observed in the field-aged catalyst. Bench-flow reactor evaluation is used to determine the NO[Subscript x] performance of the engine-aged and field-aged catalysts, and in depth surface studies are used to determine the deactivation mechanisms associated with each type of catalyst aging. SEM micrographs and BET surface area measurements of the aged catalysts show that the deactivation mechanism associated with catalyst aging is primarily physical damage to the zeolite washcoat for both the field-aged and engine-aged catalysts. Furthermore, X-ray diffraction and NO oxidation experiments identify zeolite dealumination as the underlying cause of the washcoat degradation. Finally, BFR evaluation shows that the NO[Subscript x] performance of the catalyst aged at 750°C for approximately 50 hours compares very well to that of the field-aged catalyst with a service life of 3 years. It is concluded that accelerated thermal aging on the engine bench is successful in bringing about similar catalyst changes to those seen with the field-aged catalyst.

Zeolites in Industrial Separation and Catalysis

Zeolites in Industrial Separation and Catalysis
Title Zeolites in Industrial Separation and Catalysis PDF eBook
Author Santi Kulprathipanja
Publisher John Wiley & Sons
Pages 618
Release 2010-01-26
Genre Science
ISBN 9783527629572

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This first book to offer a practical overview of zeolites and their commercial applications provides a practical examination of zeolites in three capacities. Edited by a globally recognized and acclaimed leader in the field with contributions from major industry experts, this handbook and ready reference introduces such novel separators as zeolite membranes and mixed matrix membranes. The first part of the book discusses the history and chemistry of zeolites, while the second section focuses on separation processes. The third and final section treats zeolites in the field of catalysis. The three sections are unified by an examination of how the unique properties of zeolites allow them to function in different capacities as an adsorbent, a membrane and as a catalyst, while also discussing their impact within the industry.