I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions
Title | I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions PDF eBook |
Author | Susan Deborah Toto |
Publisher | |
Pages | 504 |
Release | 1989 |
Genre | |
ISBN |
Dissertation Abstracts International
Title | Dissertation Abstracts International PDF eBook |
Author | |
Publisher | |
Pages | 770 |
Release | 1989 |
Genre | Dissertations, Academic |
ISBN |
Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities
Title | Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities PDF eBook |
Author | American Chemical Society. Committee on Professional Training |
Publisher | |
Pages | 1646 |
Release | 1991 |
Genre | Chemical engineering |
ISBN |
Chiral Transition Metal Complexes Containing Phosphines
Title | Chiral Transition Metal Complexes Containing Phosphines PDF eBook |
Author | Darlene Grace D'Alliessi |
Publisher | |
Pages | 314 |
Release | 2003 |
Genre | |
ISBN |
Development of Bifunctional Phosphines, Metal Complexes and Catalysts for Various Organic Transformations
Title | Development of Bifunctional Phosphines, Metal Complexes and Catalysts for Various Organic Transformations PDF eBook |
Author | |
Publisher | |
Pages | 424 |
Release | 2011 |
Genre | |
ISBN | 9781124696287 |
A series of phosphines with different heterocycles (pyridine and imidazole) possessing different substituents (alkyl and aryl) were synthesized. The phosphine ligands were reacted with different metal precursors to from organometallic complexes which were applied to catalysis. This dissertation describes, part of the discovery process of a uniquely active and selective catalyst for alkene isomerization and the importance of heterocyclic ring in the ligand, enhancing the acceleration of the reaction to almost 11,000 times faster than a non-heterocyclic analog. Further investigation of the isomerization catalyst, as a catalyst for cycloisomerization of alkynols led to discovery of the fact that a related alkyne hydration catalyst, reported by Dan Lev in 2004, was broadly useful in cycloisomerization reactions leading to synthesis of both indoles and benzofurans. A series of allylpalladium(II) chloride bifunctional phosphine complexes were also synthesized and characterized and eventually applied as catalysts for aryl amination reactions. Finally, two mechanistically distinct approaches to anti-Markovnikov alkene hydration using bifunctional ligands are described, which show promise for further development.
Transition-metal Complexes Containing Phosphorus Ligands
Title | Transition-metal Complexes Containing Phosphorus Ligands PDF eBook |
Author | Naseer Ahmad |
Publisher | |
Pages | 6 |
Release | 1973 |
Genre | Chemistry |
ISBN |
Synthesis, Characterization and Reactivity of Platinum(0)-tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands
Title | Synthesis, Characterization and Reactivity of Platinum(0)-tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands PDF eBook |
Author | Lisa Marie Green |
Publisher | |
Pages | 502 |
Release | 1987 |
Genre | Ligands |
ISBN |