Hyperspherical harmonics are extremely useful in nuclear physics and reactive scattering theory. However, their use has been confined to specialists with very strong backgrounds in mathematics. This book aims to change the theory of hyperspherical harmonics from an esoteric field, mastered by specialists, into an easily-used tool with a place in the working kit of all theoretical physicists, theoretical chemists and mathematicians. The theory presented here is accessible without the knowledge of Lie-groups and representation theory, and can be understood with an ordinary knowledge of calculus. The book is accompanied by programs and exercises designed for teaching and practical use.

where d 3 3)2 ( L x - -- i3x j3x j i i>j Thus the Gegenbauer polynomials play a role in the theory of hyper spherical harmonics which is analogous to the role played by Legendre polynomials in the familiar theory of 3-dimensional spherical harmonics; and when d = 3, the Gegenbauer polynomials reduce to Legendre polynomials. The familiar sum rule, in 'lrlhich a sum of spherical harmonics is expressed as a Legendre polynomial, also has a d-dimensional generalization, in which a sum of hyper spherical harmonics is expressed as a Gegenbauer polynomial (equation (3-27»: The hyper spherical harmonics which appear in this sum rule are eigenfunctions of the generalized angular monentum 2 operator A , chosen in such a way as to fulfil the orthonormality relation: VIe are all familiar with the fact that a plane wave can be expanded in terms of spherical Bessel functions and either Legendre polynomials or spherical harmonics in a 3-dimensional space. Similarly, one finds that a d-dimensional plane wave can be expanded in terms of HYPERSPHERICAL HARMONICS xii "hyperspherical Bessel functions" and either Gegenbauer polynomials or else hyperspherical harmonics (equations ( 4 - 27) and ( 4 - 30) ) : 00 ik·x e = (d-4)!!A~oiA(d+2A-2)j~(kr)C~(~k'~) 00 (d-2)!!I(0) 2: iAj~(kr) 2:Y~ (["2k)Y (["2) A A=O ). l). l)J where I(O) is the total solid angle. This expansion of a d-dimensional plane wave is useful when we wish to calculate Fourier transforms in a d-dimensional space.

This book provides a comprehensive presentation of geometric results, primarily from the theory of convex sets, that have been proved by the use of Fourier series or spherical harmonics. An important feature of the book is that all necessary tools from the classical theory of spherical harmonics are presented with full proofs. These tools are used to prove geometric inequalities, stability results, uniqueness results for projections and intersections by hyperplanes or half-spaces and characterisations of rotors in convex polytopes. Again, full proofs are given. To make the treatment as self-contained as possible the book begins with background material in analysis and the geometry of convex sets. This treatise will be welcomed both as an introduction to the subject and as a reference book for pure and applied mathematics.

State of the Art of Molecular Electronic Structure Computations: Correlation Methods, Basis Sets and More, Volume 79 in the Advances in Quantum Chemistry series, presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry and biology. Chapters in this new release include Computing accurate molecular properties in real space using multiresolution analysis, Self-consistent electron-nucleus cusp correction for molecular orbitals, Correlated methods for computational spectroscopy, Potential energy curves for the NaH molecule and its cation with the cock space coupled cluster method, and much more. - Presents surveys of current topics in this rapidly-developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry and biology - Features detailed reviews written by leading international researchers

This book reviews the construction of elementary systems living in de Sitter (dS) spacetime, in both the classical and quantum senses. Field theories on dS spacetime are among the most studied mathematical models of the Universe, whether for its earlier period (inflationary phase) or for its current phase of expansion acceleration (dark energy or cosmological constant). Classical elementary systems are Hamiltonian phase spaces, which are associated with co-adjoint orbits of the relativity group. On the other hand, quantum elementary systems are associated with (projective) unitary irreducible representations of the (possibly extended) relativity group (or one of its covering). This study emphasizes the conceptual issues arising in the formulation of such systems and discusses known results in a mathematically rigorous way. Particular attention is paid to: “smooth” transition from classical to quantum theory; physical content under vanishing curvature, from the point of view of a local (“tangent”) Minkowskian observer; and thermal interpretation (on the quantum level), in the sense of the Gibbons-Hawking temperature. Such a mathematical construction is of paramount importance to the understanding of the early Universe (due to the critical role that the dS metric plays in the inflationary cosmological scenarii) as well as to the construction of possible models for late-time cosmology (since a small positive cosmological constant or dark energy seems to be required by recent data). In this sense, this book uniquely blends mathematical physics (spacetime symmetry on classical and quantum levels) and theoretical physics (quantization, quantum field theory, and cosmology). Moreover, the level of exposition varies in different parts of the book so that both experts and beginners alike can utilize the book.

This text explores the connections between the theory of hyperspherical harmonics, momentum-space quantum theory and generalized Sturmian basis functions. It also introduces methods which may be used to solve many-particle problems directly, without the use of the self-consistent-field approximation.; The method of many-electron Sturmians offers an interesting alternative to the usual SCF-CI methods for calculating atomic and molecular structure. When many-electron Sturmians are used, and when the basis potential is chosen to be the attractive potential of the nuclei in the system, the following advantages are offered: the matrix representation of the nuclear attraction potential is diagonal; the kinetic energy term vanishes from the secular equation; the Slater exponents of the atomic orbitals are automatically optimized; convergence is rapid; a correlated solution to the many-electron problem can be obtained directly, without the use of the SCF approximation; and excited states can be obtained with good accuracy.; The text should be of interest to advanced students and research workers in theoretical chemistry, physics and mathematics.