This book fills the gap for concise but comprehensive literature on this interdisciplinary topic, involving chemical, physical, biological and engineering challenges. It provides broad coverage of the most important fields of modern hydrogen technology: hydrogen properties, production, storage, conversion to power, and applications in materials science. In so doing, the book covers all the pertinent materials classes: metal hydrides, inorganic porous solids, organic materials, and nanotubes. The authors present the entire view from fundamental research to viable devices and systems, including the latest scientific results and discoveries, practical approaches to design and engineering, as well as functioning prototypes and advanced systems.

The technologies of hydrogen's energetic utilization have been known for a long time. But aspects of system analysis, energy economics, and ecology that would come into play in introducing it into energy systems nave received much less attention. For those reasons, this book attempts to show the development path of a hydrogen economy, based on assured technological knowledge. One special concern has been to demonstrate, on one hand, how these developments would fit into existing energy supply structures, and, on the other, how they would contribute to further development of the energy system as a whole. With that goal in mind it is necessary to contrast the obvious advantages of hydrogen with the large efforts that would be required for its introduction. This total-systems approach led to a three-part organization of the book that also aids the reader in quickly identifying those parts that are of special interest to him. Section A essentially explains why it is necessary today to think about a new synthetic energy carrier. It also describes the irreplacable and growing role of hydrogen as a chemical raw material, and it explains technologies that al ready exist for its energetic use or that need further development. An attempt has also been made to prove that hydrogen's safety characteristics indeed per mit its handling and use as an energy carrier. Hopefully, all this will show that hydrogen, together with electricity, could be the universally employable energy carrier of a future non-fossil energy supply system.

Owing to the limited resources of fossil fuels, hydrogen is proposed as an alternative and environment-friendly energy carrier. However, its potential is limited by storage problems, especially for mobile applications. Current technologies, as compressed gas or liquefied hydrogen, comprise severe disadvantages and the storage of hydrogen in lightweight solids could be the solution to this problem. Since the optimal storage mechanism and optimal material have yet to be identified, this first handbook on the topic provides an excellent overview of the most probable candidates, highlighting both their advantages as well as drawbacks. From the contents: ¿ Physisorption ¿ Clathrates ¿ Metal hydrides ¿ Complex hydrides ¿ Amides, imides, and mixtures ¿ Tailoring Reaction Enthalpies ¿ Borazan ¿ Aluminum hydride ¿ Nanoparticles A one-stop reference on all questions concerning hydrogen storage for physical and solid state chemists, materials scientists, chemical engineers, and physicists.

to the German Edition This book is based on published material, oral presentations and lecture courses, as well as the author's personal research in the specific field of space technology and in the general areas of energy storage and transfer, and cryogenics. The science and technology of liquid hydrogen-once essential prere quisites for the rapid development of space technology-are now also proving to be more and more important for the energy production of the future. Hydrogen as an energy carrier can generally mediate the existing disparity between nuclear energy and regenerative energy, both of which are indispensable for the future. Hydrogen, as a secondary energy carrier, can be produced from these primary energy sources with minimal environmental impact and without the detrimental, long-term pollution effects of current fossil fuel technology. Hydrogen, therefore, represents the ultimate in energy technology. The initial, large-scale application of hydrogen as a secondary energy was as a high-energy rocket propellant. The procedures for its large scale liquefaction, storage and employment were generally developed in the U.S. Currently in Europe similar activities are being conducted only in France. The effort in West Germany involves testing hydrogen-oxygen and hydrogen-fluorine rocket engines, studying also the physical and technical characteristics of slush hydrogen-mixture of the solid and liquid phase-and is concentrating currently on R&D applications of liquid hydrogen as an alternate fuel. Similar activities are also being conducted in Japan and Canada.

The announcement of a hydrogen fuel initiative in the President's 2003 State of the Union speech substantially increased interest in the potential for hydrogen to play a major role in the nation's long-term energy future. Prior to that event, DOE asked the National Research Council to examine key technical issues about the hydrogen economy to assist in the development of its hydrogen R&D program. Included in the assessment were the current state of technology; future cost estimates; CO2 emissions; distribution, storage, and end use considerations; and the DOE RD&D program. The report provides an assessment of hydrogen as a fuel in the nation's future energy economy and describes a number of important challenges that must be overcome if it is to make a major energy contribution. Topics covered include the hydrogen end-use technologies, transportation, hydrogen production technologies, and transition issues for hydrogen in vehicles.

This book highlights the opportunities and the challenges of introducing hydrogen as alternative transport fuel from an economic, technical and environmental point of view. Through its multi-disciplinary approach the book provides researchers, decision makers and policy makers with a solid and wide-ranging knowledge base concerning the hydrogen economy.

Proceedings of the 3rd International Seminar, held in Lyon, May 25-27, 1983