The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.

High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings

Metals and alloys rely for their application at high temperature on the formation and retention of oxide scales, which act as a barrier between the metallic substrate and the reactive species in the environment such as 0, S, N, C, Cl, etc. This protection concept requires that the oxide grows slowly, develops a dense, uniform layer, is well adherent, has sufficient ductility to accom modate plastic deformation of the substrate and is resistant to thermal cycling. For many years it has been known that small concentrations of certain "active elements" such as Y and the rare earths, as well as carbon and sulphur, can exercise a significant influence upon the oxidation! corrosion behaviour of high temperature metals and alloys. An increasing number of experimental studies on this topic have been published recently. However no generally accepted understanding with regard to the detailed mechanisms and the way in which alloy composition and structure, temperature and environmental conditions, etc., are interacting has yet been achieved, although many - often controversial - theories and ideas have been presented. It therefore seemed to be an appropriate time to bring together a group of experts to review and evaluate the current state-of-the-art and to discuss various aspects of this important topic.

High Temperature Oxides: Refractory Glasses, Glass-Ceramics, and Ceramics is the fourth part of a series of four books on high temperature oxides. This book is divided into nine chapters that cover refractory glasses and glass-ceramics, alumina-containing compounds, zinc oxide, tungsten oxide compounds, and slip-casting of ceramics. The first chapters of the book deal with the fabrication, characterization, and application of refractory glasses and glass-ceramics. These topics are followed by considerable chapters on the preparation, properties, and application of mullite, oxide spinels, oxides containing tungsten, and zinc oxide. A chapter on slip-cast ceramics and refractories approaches slip-casting from a scientific point of view of this complex process. Included also in this text are the advances in sintered and fusion-cast glass-contact refractories, such as zirconium oxide-silica-alumina. The concluding chapter deals with the quantitative calculations of the magnitudes of the physical properties of glasses and the variation of these properties with temperature. This book is of great value to ceramic and glass researchers and scientists.

Refractory Materials: A Series of Monographs Volume 5 is a collection of works from different scientists who have made important discoveries in fields related to chemistry. The text covers topics such as thoria and yttria, and the refractory oxides of the lanthanide and actinide elements; single-crystal titanates and zirconates; some binary systems of zirconium dioxide; and zircon and zirconates. Also covered are topics such as halfnium oxide – its occurrence, purification, and physical and thermodynamic properties; and the structure and physical properties of Nb2O5 and Ta2O5. The book is recommended for chemists and materials scientists who would like to know more about the studies of other experts in the field and their applications.

A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.