High Resolution Photoelectron Spectroscopy Using Synchrotron Radiation [microform] : Ligand Field and Vibrational Splitting and Chemical Effects on Linewidths
Title | High Resolution Photoelectron Spectroscopy Using Synchrotron Radiation [microform] : Ligand Field and Vibrational Splitting and Chemical Effects on Linewidths PDF eBook |
Author | Jeffrey N. Cutler |
Publisher | National Library of Canada = Bibliothèque nationale du Canada |
Pages | 0 |
Release | 1993 |
Genre | High resolution spectroscopy |
ISBN | 9780315812918 |
High resolution spectra of the Ge 3d and Sn 4d levels of several compounds are reported. The spectra of GeH$\sb4$ and AsH$\sb3$ demonstrate that the observed vibrational intensity is related to the metal's position on the Periodic Table. The spectra of GeF$\sb4$ and SnCl$\sb4$ prove that orbital interaction is possible between atomic levels thereby creating pseudo-bonding orbitals.
High Resolution Photoelectron Spectroscopy Using Synchrotron Radiation
Title | High Resolution Photoelectron Spectroscopy Using Synchrotron Radiation PDF eBook |
Author | Jeffrey N. Cutler |
Publisher | |
Pages | 422 |
Release | 1992 |
Genre | High resolution spectroscopy |
ISBN |
Physics Briefs
Title | Physics Briefs PDF eBook |
Author | |
Publisher | |
Pages | 1416 |
Release | 1992 |
Genre | Physics |
ISBN |
Photoelectron Spectroscopy
Title | Photoelectron Spectroscopy PDF eBook |
Author | Shigemasa Suga |
Publisher | Springer Nature |
Pages | 511 |
Release | 2021-08-01 |
Genre | Science |
ISBN | 3030640736 |
This book presents photoelectron spectroscopy as a valuable method for studying the electronic structures of various solid materials in the bulk state, on surfaces, and at buried interfaces. This second edition introduces the advanced technique of high-resolution and high-efficiency spin- and momentum-resolved photoelectron spectroscopy using a novel momentum microscope, enabling high-precision measurements down to a length scale of some tens of nanometers. The book also deals with fundamental concepts and approaches to applying this and other complementary techniques, such as inverse photoemission, photoelectron diffraction, scanning tunneling spectroscopy, as well as photon spectroscopy based on (soft) x-ray absorption and resonance inelastic (soft) x-ray scattering. This book is the ideal tool to expand readers’ understanding of this marvelously versatile experimental method, as well as the electronic structures of metals and insulators.
Photoelectron Spectroscopy of Organometallic Compounds [microform]
Title | Photoelectron Spectroscopy of Organometallic Compounds [microform] PDF eBook |
Author | Jingcun Wu |
Publisher | National Library of Canada = Bibliothèque nationale du Canada |
Pages | 228 |
Release | 1997 |
Genre | Organometallic compounds |
ISBN | 9780612286917 |
High resolution gas phase photoelectron spectra are reported for a series of trimethylphosphine substituted tungsten carbonyls and cyclopentadienyl derivatives of indium (CpIn) and thallium (CpTl). The advantages of using monochromatic synchrotron radiation PES for studying the electronic structure of organometallic molecules are demonstrated.
High-resolution Pulsed-field Ionization Photoelectron Spectroscopy Using Multi-bunch Synchrotron Radiation
Title | High-resolution Pulsed-field Ionization Photoelectron Spectroscopy Using Multi-bunch Synchrotron Radiation PDF eBook |
Author | |
Publisher | |
Pages | 3 |
Release | 1997 |
Genre | |
ISBN |
BL9.0.2.2 is the newly constructed experimental End Station 2 at the Chemical Dynamics Beamline 9.0.2 of the Advanced Light Source (ALS). It is dedicated to the high resolution photoionization study of molecules of interest to atmospheric and combustion chemistry. This End Station is equipped with a high resolution scanning monochromator, which has been demonstrated to have a world record resolution of E/[delta]E=70,000. Taking the advantage of the high resolution ALS light, the authors have improved the energy resolution in threshold photoelectron spectroscopy (TPES) to 0.8 meV. The TPES is a popular technique for photoionization experiments at all synchrotron radiation facilities due to its high energy resolution as compared to that of traditional photoelectron spectroscopy (PES). TPES achieves higher energy resolution by preferentially detecting near zero kinetic energy photoelectrons resulting from threshold photoionization. However, the spectra obtained from the TPES technique generally are complicated by the simultaneous detection of electrons with nonzero kinetic energy, which are not fully discriminated against. On the other hand, the spectra obtained from pulsed field ionization photoelectron spectroscopy (PFI-PES) are completely free of the contamination from kinetic electrons. The PFI-PE technique basically involves the detection of the photoelectrons from field ionization of the very high-n Rydberg states, a few cm{sup -1} below the ionization energy (IE), by applying a delayed pulsed electric field. Within a delay of a few microseconds, all the prompt electrons formed from direct ionization will escape from the photoionization region and will not be collected. The authors have recently overcome problems with energy resolution of an electron time-of-flight technique, and incorporated the PFI-PE technique with multi-bunch VUV synchrotron radiation.
Very High Resolution Photoelectron Spectroscopy
Title | Very High Resolution Photoelectron Spectroscopy PDF eBook |
Author | Stephan Hüfner |
Publisher | Springer Science & Business Media |
Pages | 411 |
Release | 2007-02-09 |
Genre | Science |
ISBN | 3540681302 |
Photoemission spectroscopy is one of the most extensively used methods to study the electronic structure of atoms, molecules, and solids and their surfaces. This volume introduces and surveys the field at highest energy and momentum resolutions allowing for a new range of applications, in particular for studies of high temperature superconductors.