The difficult struggle to protect our valuable ground-water resources necessarily involves scientists and engineers from many disciplines. To prevail in this effort, these practitioners—including microbiologists, hydrogeologists, geoscientists, and environmental engineers—must have a common understanding of essential ground-water quality issues and problems. That includes a basic grasp of how microorganisms and microbial processes affect the chemistry of ground water in both pristine and chemically stressed aquifer systems. Ground-Water Microbiology and Geochemistry marks the first attempt to bridge the historical lack of communication among these disciplines by detailing—in language that cuts across specialties—the impact of microorganisms and microbial processes on ground-water systems. To bring these diverse practitioners together, the book has been organized in three parts, with each section addressing the information needs of specific disciplines. The first six chapters of Ground-Water Microbiology and Geochemistry provide an overview of microbiology that’s geared to geoscientists who may lack formal training in the field. Here, the book systematically covers the kinds of microorganisms found in subsurface environments, focusing on their growth, metabolism, genetics, and ecology. The second part of the book, which covers four chapters, speaks both to geoscientists and to microbiologists. It offers a hydrologic perspective on how microbial processes affect groundwater geochemistry in pristine systems—an important topic for geochemists since most ground-water reservoirs have not been chemically affected by human activities, and naturally occurring microbial processes have major impacts on water quality. At the same time, Part Two introduces microbiologists to the different classes of ground-water systems, and gives an overview of techniques for sampling subsurface environments. In addition, microbiologists gain an understanding of biogeochemical cycling in ground-water systems—in coverage that’s unique to this book—and of the classic geochemical modeling techniques that are used to study microbial processes. The final three chapters of Ground-Water Microbiology and Geochemistry focus in on microbial processes in contaminated ground-water systems—a topic of central concern to environmental scientists. In this concluding section, microbiologists see how degradation processes depend upon the hydrologic and geochemical environments within which they operate. Having achieved a basic knowledge of microbiological and biochemical concepts from the earlier chapters, geoscientists are fully prepared for this treatment of microbial acclimation and the biodegradation of petroleum hydrocarbons and halogenated compounds. Ground-Water Microbiology and Geochemistry is as graphically impressive as it is far reaching. High-quality, computer-generated illustrations, of particular appeal to visually oriented geoscientists, can be found throughout the book. Equally important is the book’s unusually comprehensive bibliography, which, like the text itself, spans the relevant science and engineering disciplines. The importance of Ground-Water Microbiology and Geochemistry to geoscientists, hydrologists, and environmental scientists has been amply documented. The book should also be required reading for water planners and lawyers involved in environmental issues. It will also serve as a compelling text in upper undergraduate and graduate courses in ground-water chemistry.

Ein zeitgemäßer Beitrag zum Schutz unserer wertvollen Grundwasservorräte! In drei Teilen beschreibt dieser Band alle Aspekte der Mikrobiologie und Geochemie des Grundwassers. Teil 1 ist einem allgemeinen Überblick über die vorhandenen Mikroorganismen (Arten, Wachstum, Metabolismus, Genetik, Ökologie) gewidmet. Teil 2 befaßt sich mit Verteilung dieser Organismen im Grundwasser, Probennahme und geochemischen Modellen. Im Mittelpunkt des 3. Teils stehen mikrobiologische Prozesse in wasserführenden Schichten, die mit Chemikalien verunreinigt wurden. (10/00)

Groundwater Geochemistry: Fundamentals and Applications to Contamination examines the integral role geochemistry play s in groundwater monitoring and remediation programs, and presents it at a level understandable to a wide audience. Readers of all backgrounds can gain a better understanding of geochemical processes and how they apply to groundwater systems. The text begins with an explanation of fundamental geochemical processes, followed by a description of the methods and tools used to understand and simulate them. The book then explains how geochemistry applies to contaminant mobility, discusses remediation system design, sampling program development, and the modeling of geochemical interactions. This clearly written guide concludes with specific applications of geochemistry to contaminated sites. This is an ideal choice for readers who do not have an extensive technical background in aqueous chemistry, geochemistry, or geochemical modeling. The only prerequisite is a desire to better understand natural processes through groundwater geochemistry.

Large-scale infilling of the wetlands in the Lake Calumet region of Chicago, Illinois with steel slag has created an aquifer with extremely alkaline ground water, the pH of which can range up to 12.8. To understand the geochemistry of this aquifer, we examined samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH, which form a temperature-sensitive pH buffering system. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides. Fe and Mn in the slag, as well as steel additives such as Ni and Mo, react to form insoluble phases; these metals did not accumulate in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that the metals moved through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline waters. Microbiologists have long believed that highly alkaline conditions are poorly supportive of microbial life, in part because an environment lacking in hydrogen ions (H+) is likely to interfere with the proton motive force needed by most respiring organisms to synthesize ATP, and with the need to maintain a circum-neutral intracellular pH (Horikoshi and Akiba, 1982). Here I describe a diverse microbial community that inhabits extremely alkaline (pH ~ 12-13) ground water from the Lake Calumet region. Using microbial culturing, genetic sequencing, and microcosm experiments, I confiimed the presence and growth of a variety of alkaliphilic ß-Proteobacteria, Bacillus, and Clostridium species at pH up to 13.2. Many of the bacterial sequences most closely matched other alkaliphiles found more moderately alkaline waters around the world. Oxidation of dihydrogen produced by reaction of water with steel slag is likely a primary energy source to the community. These results extend upward the known range of pH tolerance for a microbial community by as much as two pH units. The microbial community may provide a source of novel microbes and enzymes that can be exploited under alkaline conditions.

This book contains both practical and theoretical aspects of groundwater resources relating to geochemistry. Focusing on recent research in groundwater resources, this book helps readers to understand the hydrogeochemistry of groundwater resources. Dealing primarily with the sources of ions in groundwater, the book describes geogenic and anthropogenic input of ions into water. Different organic, inorganic and emerging contamination and salinity problems are described, along with pollution-related issues affecting groundwater. New trends in groundwater contamination remediation measures are included, which will be particularly useful to researchers working in the field of water conservation. The book also contains diverse groundwater modelling examples, enabling a better understanding of water-related issues and their management. Groundwater Geochemistry: Pollution and Remediation offers the reader: An understanding of the quantitative and qualitative challenges of groundwater resources An introduction to the environmental geochemistry of groundwater resources A survey of groundwater pollution-related issues Recent trends in groundwater conservation and remediation Mathematical and statistical modeling related to groundwater resources Students, lecturers and researchers working in the fields of hydrogeochemistry, water pollution and groundwater will find Groundwater Geochemistry an essential companion.

In the late 1970s and early 1980s, our nation began to grapple with the legacy of past disposal practices for toxic chemicals. With the passage in 1980 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), commonly known as Superfund, it became the law of the land to remediate these sites. The U. S. Department of Defense (DoD), the nation’s largest industrial organization, also recognized that it too had a legacy of contaminated sites. Historic operations at Army, Navy, Air Force, and Marine Corps facilities, ranges, manufacturing sites, shipyards, and depots had resulted in widespread contamination of soil, groundwater, and sediment. While Superfund began in 1980 to focus on remediation of heavily contaminated sites largely abandoned or neglected by the private sector, the DoD had already initiated its Installation Restoration Program in the mid 1970s. In 1984, the DoD began the Defense Environmental Restoration Program (DERP) for contaminated site assessment and remediation. Two years later, the U. S. Congress codified the DERP and directed the Secretary of Defense to carry out a concurrent program of research, development, and demonstration of innovative remediation technologies. As chronicled in the 1994 National Research Council report, “Ranking Hazardous-Waste Sites for Remedial Action”, our early estimates on the cost and suitability of existing technologies for cleaning up contaminated sites were wildly optimistic. Original estimates, in 1980, projected an average Superfund cleanup cost of a mere $3.